Technical Papers
Jun 29, 2022

Remediation of Coal Tar–Contaminated Soil by Smoldering Combustion Using Vegetable Oils as Supplemental Fuel

Publication: Journal of Environmental Engineering
Volume 148, Issue 9

Abstract

This study explored the remediation of coal tar–contaminated sand with smoldering combustion using vegetable oil as supplemental fuel. In this work, bench-scale column experiments were conducted one factor at a time to identify the minimum concentration limit of coal tar and the feasibility of vegetable oil as supplemental fuel. A range of key parameters including various concentrations of vegetable oil (10,00050,000  mg/kg), types of vegetable oil (sunflower, soybean, and corn oils), and oil to coal tar mass ratios that affect smoldering combustion were examined in detail. Results demonstrated that exceeding 80,000 mg coal tar in 1 kg sand caused smoldering exceeding 630°C. The posttreatment coal tar concentration in treated sand was 648  mg/kg, indicating more than 99% initial coal tar was destroyed. Further, corn oil was a relative suitable supplemental fuel, which possessed higher average peak temperature and removal efficiency. To be specific, the sum of the concentration of corn oil and coal tar reaching 50,000  mg/kg was found to be a necessary requirement to determine whether smoldering combustion occurred or not; in addition, the content of coal tar was not less than 20,000  mg/kg. Overall, this study indicated that smoldering with injection of vegetable oil has potential to be effective in situ remediation application for low-concentration coal tar–impacted sand (<80,000  mg/kg).

Get full access to this article

View all available purchase options and get full access to this article.

Data Availability Statement

All data generated or analyzed during this study are included in this published article.

Acknowledgments

Major Science and Technology Project of Water Body Pollution Control and Treatment (Project No. 2018ZX07111001).

References

Arca-Ramos, A., G. Eibes, M. T. Moreia, G. Feijoo, and J. N. Lema. 2014. “Vegetable oils as NAPLs in two phase partitioning bioreactors for the degradation of anthracene by laccase.” Chem. Eng. J. 240 (Mar): 281–289. https://doi.org/10.1016/j.cej.2013.11.076.
Chen, D., Y. Shen, S. Wang, X. Chen, X. Cao, Z. Wang, and Y. Li. 2021. “Efficient removal of various coexisting organic pollutants in water based on β-cyclodextrin polymer modified flower-like Fe3O4 particles.” J. Colloid Interface Sci. 589 (May): 217–228. https://doi.org/10.1016/j.jcis.2020.12.109.
Christensen, E. G., N. Fernandez-Anez, and G. Rein. 2020. “Influence of soil conditions on the multidimensional spread of smouldering combustion in shallow layers.” Combust. Flame 214 (Apr): 361–370. https://doi.org/10.1016/j.combustflame.2019.11.001.
Ciesińska, W. 2017. “Thermo-rheological properties of coal-tar pitch modified with phenol-formaldehyde resin.” J. Therm. Anal. Calorim. 130 (1): 187–195. https://doi.org/10.1007/s10973-017-6471-5.
Demirbaş, A. 2000. “A direct route to the calculation of heating values of liquid fuels by using their density and viscosity measurements.” Energy Convers. Manage. 41 (15): 1609–1614. https://doi.org/10.1016/S0196-8904(00)00012-1.
Ding, D., X. Song, C. Wei, and J. LaChance. 2019. “A review on the sustainability of thermal treatment for contaminated soils.” Environ. Pollut. 253 (Oct): 449–463. https://doi.org/10.1016/j.envpol.2019.06.118.
Duchesne, A. L., J. K. Brown, D. J. Patch, D. Major, K. P. Weber, and J. I. Gerhard. 2020. “Remediation of PFAS-contaminated soil and granular activated carbon by smoldering combustion.” Environ. Sci. Technol. 54 (19): 12631−12640. https://doi.org/10.1021/acs.est.0c03058.
Gerhard, J. I., G. P. Grant, and J. L. Torero. 2020. “Star: A uniquely sustainable in situ and ex situ remediation process.” In Sustainable remediation of contaminated soil and groundwater, 221–246. Oxford, UK: Butterworth-Heinemann.
Gianfelice, G., M. D. Zassa, A. Biasin, and P. Canu. 2019. “Onset and propagation of smouldering in pine bark controlled by addition of inert solids.” Renewable Energy 132 (Mar): 596–614. https://doi.org/10.1016/j.renene.2018.08.028.
Grant, G. P., D. Major, G. C. Scholes, J. Horst, S. Hill, M. R. Klemmer, and J. N. Couch. 2016. “Smoldering combustion (STAR) for the treatment of contaminated soils: Examining limitations and defining success.” Rem. J. 26 (3): 27–51. https://doi.org/10.1002/rem.21468.
Hagen, B. C., and A. K. Meyer. 2021. “From smoldering to flaming fire: Different modes of transition.” Fire Saf. J. 121 (May): 103292. https://doi.org/10.1016/j.firesaf.2021.103292.
Hasan, T., J. I. Gerhard, R. Hadden, and G. Rein. 2015. “Self-sustaining smouldering combustion of coal tar for the remediation of contaminated sand: Two-dimensional experiments and computational simulations.” Fuel 150 (15): 288–297. https://doi.org/10.1016/j.fuel.2015.02.014.
Huang, R., X. Yuan, L. Yan, L. Han, W. Bao, L. Chang, L. Liu, J. Wang, and Y. S. Ok. 2021. “Carbon precursors in coal tar: Extraction and preparation of carbon materials.” Sci. Total Environ. 788 (Sep): 147697. https://doi.org/10.1016/j.scitotenv.2021.147697.
Jia, T. L., M. Hong, A. Jia, Y. Nie, X. Feng, C. Wang, and S. Xia. 2019. “Effect factors of self-sustaining treatment for active remediation technique in high concentration organic contaminated soil.” [In Chinese.] Sci. Tech. Eng. 19 (25): 379–385.
Lin, Y. C., C. Y. Lai, and C. P. Chu. 2021. “Air pollution diffusion simulation and seasonal spatial risk analysis for industrial areas.” Environ. Res. 194 (Mar): 110693. https://doi.org/10.1016/j.envres.2020.110693.
Ma, Z. H., X. Y. Wei, G. H. Liu, F. J. Liu, and Z. M. Zong. 2021. “Value-added utilization of high-temperature coal tar: A review.” Fuel 292 (15): 119954. https://doi.org/10.1016/j.fuel.2020.119954.
MacPhee, S. L., J. I. Gerhard, and G. Rein. 2012. “A novel method for simulating smoldering propagation and its application to STAR (self-sustaining treatment for active remediation).” Environ. Modell. Software 31 (May): 84–98. https://doi.org/10.1016/j.envsoft.2011.11.004.
Meateas, D. J., G. R. Tick, and K. C. Carroll. 2017. “In situ stabilization of NAPL contaminant source-zones as a remediation technique to reduce mass discharge and flux to groundwater.” J. Contam. Hydrol. 204 (Apr): 40–56. https://doi.org/10.1016/j.jconhyd.2017.07.007.
Pironi, P., C. Switzer, J. I. Gerhard, G. Rein, and J. L. Torero. 2011. “Self-sustaining smoldering combustion for NAPL remediation: Laboratory evaluation of process sensitivity to key parameters.” Environ. Sci. Technol. 45 (7): 2980–2986. https://doi.org/10.1021/es102969z.
Pironi, P., C. Switzer, G. Rein, A. Fuentes, J. I. Gerhard, and J. L. Torero. 2009. “Small-scale forward smouldering experiments for remediation of coal tar in inert media.” Proc. Combust. Inst. 32 (2): 1957–1964. https://doi.org/10.1016/j.combustflame.2020.12.050.
Qian, Z., Y. Chen, Z. Liu, Z. Y. Han, Y. Zhang, Y. Feng, Y. Shang, H. Guo, Q. Li, G. Shen, J. Chen, and S. Tao. 2021. “Intermediate volatile organic compound emissions from residential solid fuel combustion based on field measurements in rural China.” Environ. Sci. Technol. 55 (9): 5689–5700. https://doi.org/10.1021/acs.est.0c07908.
Radelyuk, I., M. Naseri-Rad, H. Hashemi, M. Persson, R. Berndtsson, M. Yelubay, and K. Tussupova. 2021. “Assessing data-scarce contaminated groundwater sites surrounding petrochemical industries.” Environ. Earth Sci. 80 (9): 351. https://doi.org/10.1007/s12665-021-09653-z.
Rashwan, T. L., J. I. Gerhard, and G. P. Grant. 2016. “Application of self-sustaining smouldering combustion for the destruction of wastewater biosolids.” Waste Manage. 50 (Apr): 201–212. https://doi.org/10.1016/j.wasman.2016.01.037.
Rashwan, T. L., J. L. Torero, and J. I. Gerhard. 2021. “Heat losses in a smouldering system: The key role of non-uniform air flux.” Combust. Flame 227 (May): 309–321. https://doi.org/10.1016/j.combustflame.2020.12.050.
Richards, A. P., D. Haycock, J. Frandsen, and T. H. Fletcher. 2021. “A review of coal heating value correlations with application to coal char, tar, and other fuels.” Fuel 283 (Jan): 118942. https://doi.org/10.1016/j.fuel.2020.118942.
Salman, M., J. I. Gerhard, D. W. Major, P. Pironi, and R. Hadden. 2015. “Remediation of trichloroethylene-contaminated soils by star technology using vegetable oil smoldering.” J. Hazard. Mater. 285 (21): 346–355. https://doi.org/10.1016/j.jhazmat.2014.11.042.
Scholes, G. C., J. I. Gerhard, G. P. Grant, D. W. Major, J. E. Vidumsky, C. Switzer, and J. L. Torero. 2015. “Smoldering remediation of coal-tar-contaminated soil: Pilot field tests of STAR.” Environ. Sci. Technol. 49 (24): 14334–14342. https://doi.org/10.1021/acs.est.5b03177.
Solinger, R., G. P. Grant, G. C. Scholes, C. Murray, and J. I. Gerhard. 2020. “STARx Hottpad for smoldering treatment of waste oil sludge: Proof of concept and sensitivity to key design parameters.” Waste Manage Res. 38 (5): 554–566. https://doi.org/10.1177/0734242X20904430.
Sun, S., L. Sun, G. Liu, C. Zou, Y. Wang, L. Wu, and H. Mao. 2021. “Developing a vehicle emission inventory with high temporal-spatial resolution in Tianjin, China.” Sci. Total Environ. 776 (Jul): 145873. https://doi.org/10.1016/j.scitotenv.2021.145873.
Switzer, C., P. Pironi, J. I. Gerhard, G. Rein, and J. L. Torero. 2009. “Self-sustaining smoldering combustion: A novel remediation process for non-aqueous-phase liquids in porous media.” Environ. Sci. Technol. 43 (15): 5871–5877. https://doi.org/10.1021/es803483s.
Switzer, C., P. Pironi, J. I. Gerhard, G. Rein, and J. L. Torero. 2014. “Volumetric scale-up of smouldering remediation of contaminated materials.” J. Hazard. Mater. 268 (15): 51–60. https://doi.org/10.1016/j.jhazmat.2013.11.053.
Wei, T., M. Hong, and L. Liu. 2018. “Study on the removal effect and influencing factors of nitrobenzene reduction by iron carbonate precipitates.” Environ. Sci. Pollut. Res. Int. 25 (27): 27112–27121. https://doi.org/10.1007/s11356-018-2621-y.
Wyn, H. K., M. Konarova, J. Beltramini, G. Perkins, and L. Yermán. 2020. “Self-sustaining smouldering combustion of waste: A review on applications, key parameters and potential resource recovery.” Fuel Process. Technol. 205 (Aug): 106425. https://doi.org/10.1016/j.fuproc.2020.106425.
Yao, M., J. Bai, Y. Chang, C. Qin, F. Li, X. Yang, and Y. Zhao. 2020. “Effects of air flowrate distribution and benzene removal in heterogeneous porous media during air sparging remediation.” J. Hazard. Mater. 398 (Nov): 122866. https://doi.org/10.1016/j.jhazmat.2020.122866.
Zanoni, M. A. B., J. L. Torero, and J. I. Gerhard. 2019. “Delineating and explaining the limits of self-sustained smouldering combustion.” Combust. Flame 201 (Mar): 78–92. https://doi.org/10.1016/j.combustflame.2018.12.004.
Zanoni, M. A. B., J. L. Torero, and J. I. Gerhard. 2020. “Experimental and numerical investigation of weak, self-sustained conditions in engineered smouldering combustion.” Combust. Flame 222 (Dec): 27–35. https://doi.org/10.1016/j.combustflame.2020.08.020.
Zanoni, M. A. B., J. Wang, and J. I. Gerhard. 2021. “Understanding pressure changes in smouldering thermal porous media reactors.” Chem. Eng. J. 412 (May): 128642. https://doi.org/10.1016/j.cej.2021.128642.
Zhang, H., D. Ma, R. Qiu, Y. Tang, and C. Du. 2017. “Non-thermal plasma technology for organic contaminated soil remediation: A review.” Chem. Eng. J. 313 (Dec): 157–170. https://doi.org/10.1016/j.cej.2016.12.067.
Zhao, C., Y. Li, Z. Gan, and M. Nie. 2021. “Method of smoldering combustion for refinery oil sludge treatment.” J. Hazard. Mater. 409 (5): 124995. https://doi.org/10.1016/j.jhazmat.2020.124995.

Information & Authors

Information

Published In

Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 148Issue 9September 2022

History

Received: Jul 22, 2021
Accepted: Mar 26, 2022
Published online: Jun 29, 2022
Published in print: Sep 1, 2022
Discussion open until: Nov 29, 2022

Permissions

Request permissions for this article.

ASCE Technical Topics:

Authors

Affiliations

Aiyuan Jia
Postgraduate, Key Laboratory of Groundwater Resources and Environment, Ministry of Education, Jilin Univ., Changchun 130021, China.
Professor, Key Laboratory of Groundwater Resources and Environment, Ministry of Education, National and Local Joint Engineering Laboratory for Petrochemical Contaminated Site Control and Remediation Technology, Jilin Univ., 2519 Jiefang Rd., Changchun 130021, China (corresponding author). Email: [email protected]
Tao Wei
Assitant Professor, Key Laboratory of Groundwater Resources and Environment, Ministry of Education, Jilin Univ., Changchun 130021, China.
Tianli Jia
Research Scholar, Key Laboratory of Groundwater Resources and Environment, Ministry of Education, Jilin Univ., Changchun 130021, China.
Shuai Zhang
Postgraduate, Key Laboratory of Groundwater Resources and Environment, Ministry of Education, Jilin Univ., Changchun 130021, China.

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share