Technical Papers
Sep 22, 2020

Evaluation of the Reuse of Baked-Alum Water Treatment Residual to Adsorb Phosphorous

Publication: Journal of Environmental Engineering
Volume 146, Issue 12

Abstract

Excess phosphorous in waterways is known to be a cause of harmful algal blooms. This research evaluated if baking water treatment residuals (WTRs) would increase the number of adsorption sites, thereby increasing the WTRs ability to adsorb phosphorous. Initial 24-h sorption studies determined optimal baking temperatures of 175°C for alum based-WTR (Al-WTR) and 150°C for Al-WTR amended with power activated carbon (PAC) (PAC-WTR). Adsorption-desorption isotherm studies for baked Al-WTR (175°C) and PAC-WTR (150°C) found that there was a net desorption of phosphorous when distilled water was used as the background solution. When surface water was used, baked Al-WTR adsorbed more phosphorous at 5°C while baked PAC-WTR adsorbed more at 20°C. Continuous flow column tests were also conducted and found a sorption capacity of 7.91  mgPO4g1 WTR for baked Al-WTR that was less than as-is and 16.21  mgPO4 per kg-WTR, which was 83% better than its as-is counterpart. An analysis of all experiments found that as-is WTR performed better (p<0.05) than baked WTR and would be the recommended reuse of the water treatment plant’s WTR for the adsorption of phosphorous.

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Data Availability Statement

All data generated or used during the study appear in the published article.

Acknowledgments

The following grants made this research possible through funding: Ohio EPA 319—Surface Water Quality Improvements, and Ohio Water Development Authority 80-17—Beneficial Reuse of Alum WTR for P Removal for a Tributary Feeding into Drinking Water Supply Reservoir.

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Information

Published In

Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 146Issue 12December 2020

History

Received: May 18, 2020
Accepted: Jul 17, 2020
Published online: Sep 22, 2020
Published in print: Dec 1, 2020
Discussion open until: Feb 22, 2021

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Authors

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Michael Spade [email protected]
M.S. Candidate, Dept. of Civil Engineering, Univ. of Akron, Akron, OH 44325-3905. Email: [email protected]
Emeritus Professor, Biology Dept., Univ. of Akron, Akron, OH 44325. Email: [email protected]
Professor, Dept. of Civil Engineering, Univ. of Akron, Akron, OH 44325-3905 (corresponding author). ORCID: https://orcid.org/0000-0002-6233-2452. Email: [email protected]

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