Technical Papers
Sep 2, 2020

Nitric Oxide Removal by Combined Ammonia and Fe(II)EDTA in a Packed Tower

Publication: Journal of Environmental Engineering
Volume 146, Issue 11

Abstract

To explore the effects of some operating conditions on NO removal efficiency in a packed tower, the denitration process was simulated in a laboratory-scale packed tower using an ammonia solution containing Fe(II) ethylene diaminetetraacetic [Fe(II)EDTA]. The effects of pH, NO concentration, Fe(II)EDTA concentration, (NH4)2SO3 concentration, and SO2 concentration on denitration efficiency were studied. The experimental conditions to get the best denitration efficiency are as follows: pH of the absorbed solution is 6.5, liquid/gas ratio is 10  L/m3, and the appropriate concentration of Fe(II)EDTA and (NH4)2SO3 is 0.03 and 0.1  mol/L, respectively. When the concentration of SO2 rises from 1,500 to 2,000  mg/m3, the removal efficiency of nitric oxide decreases slightly. The basic data obtained from results are in favor of the application of industrial desulfurization and denitration.

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Data Availability Statement

All data, models, and code generated or used during the study appear in the published article.

Acknowledgments

The financial support from the Talent Introduction Project of Kunming University of Science and Technology (KKSY201305110).

References

Arcibar-Orozco, J. A., A. A. Acosta-Herrera, and J. R. Rangel-Mendez. 2019. “Simultaneous desulfuration and denitrogenation of model diesel fuel by Fe-Mn microwave modified activated carbon: Iron crystalline habit influence on adsorption capacity.” J. Cleaner Prod. 218 (May): 69–82. https://doi.org/10.1016/j.jclepro.2019.01.202.
Arcibar-Orozco, J. A., J. R. Rangel-Mendez, and T. J. Bandosz. 2013. “Reactive adsorption of SO2 on activated carbons with deposited Iron nanoparticles.” J. Hazard. Mater. 246–247 (Feb): 300–309. https://doi.org/10.1016/j.jhazmat.2012.12.001.
Bandyopadhyay, A., and M. N. Biswas. 2007. “Modeling of SO2 scrubbing in spray towers.” Sci. Total Environ. 383 (1–3): 25–40. https://doi.org/10.1016/j.scitotenv.2007.04.024.
Bao, J., L. Sun, Z. Mo, G. Xie, J. Tang, and H. Yang. 2017. “Investigation on formation characteristics of aerosol particles during wet ammonia desulfurization process.” Energy Fuels 31 (8): 8374–8382. https://doi.org/10.1021/acs.energyfuels.7b00672.
Chen, W., J. Luo, L. Qin, and J. Han. 2015. “Selective autocatalytic reduction of NO from sintering flue gas by the hot sintered ore in the presence of NH3.” J. Environ. Manage. 164 (Dec): 146–150. https://doi.org/10.1016/j.jenvman.2015.09.001.
Chien, T., H. Hsueh, B. Chu, and H. Chu. 2009. “Absorption kinetics of NO from simulated flue gas using Fe(II)EDTA solutions.” Process Saf. Environ. Prot. 87 (5): 300–306. https://doi.org/10.1016/j.psep.2009.06.002.
Ding, Y., X. Liu, and W. Fang. 1986. “Summary of desulphurization experiments by EDTA complex iron method.” [In Chinese.] Henan Chem. Ind. (1): 13–20.
Dong, X., Y. Zhang, J. Zhou, H. Li, X. Wang, and M. Chen. 2013. “Evaluation of simultaneous reduction of Fe(II)EDTANO and Fe(III)EDTA by a bacterial pure culture.” J. Chem. Technol. Biotechnol. 89 (1): 111–116. https://doi.org/10.1002/jctb.4112.
Dou, B., W. Pan, Q. Jin, W. Wang, and Y. Li. 2009. “Prediction of SO2 removal efficiency for wet flue gas desulfurization.” Energy Convers. Manage. 50 (10): 2547–2553. https://doi.org/10.1016/j.enconman.2009.06.012.
Gui, K., H. Liang, F. Wang, X. Wang, and G. Yao. 2015. “Low-temperature selective catalytic reduction of NO on an iron ore catalyst in a magnetically fluidized bed.” Chem. Eng. Technol. 38 (9): 1537–1542. https://doi.org/10.1002/ceat.201400190.
Guo, R., X. Gao, W. Pan, J. Ren, J. Wu, and X. Zhang. 2010. “Absorption of NO into NaClO3/NaOH solutions in a stirred tank reactor.” Fuel 89 (11): 3431–3435. https://doi.org/10.1016/j.fuel.2010.03.020.
Hao, R., Y. Mao, X. Mao, Z. Wang, Y. Gong, Z. Zhang, and Y. Zhao. 2019. “Cooperative removal of SO2 and NO by using a method of UV-heat/H2O2 oxidation combined with NH4OH-(NH4)2SO3 dual-area absorption.” Chem. Eng. J. 365 (Jun): 282–290. https://doi.org/10.1016/j.cej.2019.02.059.
He, F., X. Deng, and M. Chen. 2017. “Evaluation of Fe(II)EDTA-NO reduction by zinc powder in wet flue gas denitrification technology with Fe(II)EDTA.” Fuel 199 (Jul): 523–531. https://doi.org/10.1016/j.fuel.2017.03.015.
Jia, Y., D. Du, X. Zhang, X. Ding, and Q. Zhong. 2013. “Simultaneous removal of SO2 and NOx with ammonia absorbent in a packed column.” Korean J. Chem. Eng. 30 (9): 1735–1740. https://doi.org/10.1007/s11814-013-0091-y.
Jia, Y., Q. Zhong, X. Fan, Q. Chen, and H. Sun. 2011. “Modeling of ammonia-based wet flue gas desulfurization in the spray scrubber.” Korean J. Chem. Eng. 28 (4): 1058–1064. https://doi.org/10.1007/s11814-010-0472-4.
Li, H., and W. Fang. 1988. “Kinetics of absorption of nitric oxide in aqueous Fe(II)-EDTA solution.” Ind. Eng. Chem. Res. 27 (5): 770–774. https://doi.org/10.1021/ie00077a009.
Liu, Q., and Z. Liu. 2013. “Carbon supported vanadia for multi-pollutants removal from flue gas.” Fuel 108 (Jun): 149–158. https://doi.org/10.1016/j.fuel.2011.05.015.
Liu, Y., Q. Wang, Y. Yin, J. Pan, and J. Zhang. 2014. “Advanced oxidation removal of NO and SO2 from flue gas by using ultraviolet/H2O2/NaOH process.” Chem. Eng. Res. Des. 92 (10): 1907–1914. https://doi.org/10.1016/j.cherd.2013.12.015.
Moshiri, H., B. Nasernejad, H. A. Ebrahim, and M. Taheri. 2014. “A comprehensive kinetic study of the reaction of SO2 with CaO by the random pore model.” Chem. Eng. Technol. 37 (12): 2037–2046. https://doi.org/10.1002/ceat.201400285.
Narita, E., T. Sato, T. Shloya, M. Ikarl, and T. Okabe. 1984. “Formation of hydroxylamldoble (sulfate) ion by the absorption of NO in aqueous solutions of Na2SO3 contain FeII-EDTA complex.” Ind. Eng. Chem. Prod. Res. Dev. 23 (2): 262–265. https://doi.org/10.1021/i300014a018.
Pillai, K. C., K. S. Chung, T. Raju, and I. Moon. 2009. “Experimental aspects of combined NOx and SO2 removal from flue-gas mixture in an integrated wet scrubber-electrochemical cell system.” Chemosphere 76 (5): 657–664. https://doi.org/10.1016/j.chemosphere.2009.04.013.
Raghunath, C. V., and M. K. Mondal. 2017. “Experimental scale multi-component absorption of SO2 and NO by NH3/NaClO scrubbing.” Chem. Eng. J. 314 (Apr): 537–547. https://doi.org/10.1016/j.cej.2016.12.011.
Sada, E., H. Kumazawa, and H. Hikosaka. 1986. “A kinetic study of absorption of NO into aqueous solutions of Na2SO3 with added Fe(II)-EDTA chelate.” Ind. Eng. Chem. Fundam. 25 (3): 386–390. https://doi.org/10.1021/i100023a014.
Sada, E., H. Kumazawa, I. Kudo, and T. Kondo. 1980. “Individual and simultaneous absorption of dilute NO and SO2 in aqueous slurries of MgSO3 with Fe(II)-EDTA.” Ind. Eng.Chem. Process Des. Dev. 19 (3): 377–382. https://doi.org/10.1021/i260075a008.
Sousa, J. P. S., M. F. R. Pereira, and J. L. Figueiredo. 2013. “Modified activated carbon as catalyst for NO oxidation.” Fuel Process. Technol. 106 (Feb): 727–733. https://doi.org/10.1016/j.fuproc.2012.10.008.
Wang, L., W. Zhao, and Z. Wu. 2007. “Simultaneous absorption of NO and SO2 by Fe(II)EDTA combined with Na2SO3 solution.” Chem. Eng. J. 132 (1–3): 227–232. https://doi.org/10.1016/j.cej.2006.12.030.
Wang, S., Q. Zhang, G. Zhang, Z. Wang, and P. Zhu. 2017. “Effects of sintering flue gas properties on simultaneous removal of SO2 and NO by ammonia-Fe(II)EDTA absorption.” J. Energy Inst. 90 (4): 522–527. https://doi.org/10.1016/j.joei.2016.05.010.
Wang, X., Y. Zhang, X. Dong, M. Chen, Z. Shi, and J. Zhou. 2013. “Fe(II)EDTA–NO reduction by sulfide in the anaerobic aqueous phase: Stoichiometry and kinetics.” Energy Fuels 27 (10): 6024–6030. https://doi.org/10.1021/ef401095f.
Xiao, Z., D. Li, Q. Zhu, and Z. Sun. 2020. “Simultaneous removal of NO and SO2 through a new wet recycling oxidation-reduction process utilizing micro-nano bubble gas-liquid dispersion system based on Na2SO3.” Fuel 263 (Mar): 116682. https://doi.org/10.1016/j.fuel.2019.116682.
Xiong, Y., Y. Zeng, W. Cai, S. Zhang, J. Ding, and Q. Zhong. 2018. “Experimental study on reaction characteristics of NO in (NH4)2SO3 solution.” J. Ind. Eng. Chem. 65 (Sep): 380–386. https://doi.org/10.1016/j.jiec.2018.05.010.
Yan, B., J. Yang, M. Guo, G. Chen, Z. Li, and S. Ma. 2014. “Study on NO enhanced absorption using FeIIEDTA in (NH4)2SO3 solution.” J. Ind. Eng. Chem. 20 (4): 2528–2534. https://doi.org/10.1016/j.jiec.2013.10.036.
Yanik, J., G. Duman, O. Karlström, and A. Brink. 2018. “NO and SO2 emissions from combustion of raw and torrefied biomasses and their blends with lignite.” J. Environ. Manage. 227 (Dec): 155–161. https://doi.org/10.1016/j.jenvman.2018.08.068.
Yih, S., and C. Lii. 1988. “Absorption of NO and SO2 in Fe(II)-EDTA solutions. I: Absorption in a double stirred vessel.” Chem. Eng. Commun. 73 (1): 43–53. https://doi.org/10.1080/00986448808940432.
Zhang, Q., S. Wang, G. Zhang, Z. Wang, and P. Zhu. 2016. “Effects of slurry properties on simultaneous removal of SO2 and NO by ammonia-Fe(II)EDTA absorption in sintering plants.” J. Environ. Manage. 183 (Dec): 1072–1078. https://doi.org/10.1016/j.jenvman.2016.09.042.
Zhao, Y., T. Guo, F. Liu, and S. Shen. 2011. “Performance of simultaneous desulfurization and denitration in liquid phase with new-style complex absorbent.” Sci. China Technol. Sci. 54 (11): 3009–3016. https://doi.org/10.1007/s11431-011-4529-3.

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Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 146Issue 11November 2020

History

Received: Mar 6, 2020
Accepted: Jun 15, 2020
Published online: Sep 2, 2020
Published in print: Nov 1, 2020
Discussion open until: Feb 2, 2021

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Authors

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Lecturer, Faculty of Chemical Engineering, Kunming Univ. of Science and Technology, 727 South Jingming Rd., Chenggong District, Kunming 650500, China (corresponding author). ORCID: https://orcid.org/0000-0001-6137-3116. Email: [email protected]
M.S. Candidate, Faculty of Chemical Engineering, Kunming Univ. of Science and Technology, 727 South Jingming Rd., Chenggong District, Kunming 650500, China. Email: [email protected]
M.S. Candidate, Faculty of Chemical Engineering, Kunming Univ. of Science and Technology, 727 South Jingming Rd., Chenggong District, Kunming 650500, China. Email: [email protected]

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