Parameter Effects on Dynamic Adsorption of Trichloroethylene on Hypercrosslinked Polymeric Adsorbents
Publication: Journal of Environmental Engineering
Volume 146, Issue 8
Abstract
Fixed-bed column adsorption is an important operation for separation of gas mixtures and recovery of volatile organic compounds (VOCs). In industrial processes, the exothermal characteristic of adsorption could cause increasing of bed temperature, lead to bed combustion incidents and reduce adsorption capacity. In this work, the widely applied hypercrosslinked polymeric adsorbents (HPA) were chosen as adsorbent. The parameters [VOCs concentrations, flow rate, ratio of column height and diameter (), and temperature] that affect adsorption performance were analyzed and investigated in the dynamic adsorption of trichloroethylene (TCE). Under isothermal conditions, breakthrough adsorption capacities decreased with increasing of temperature and inlet flow rate. Ratio of should be set above . Dynamic adsorption rate increases with increase of TCE concentration and temperature, and decreases with the increase of flow rate and . Under near-adiabatic conditions, temperature in the column naturally increased, resulting in lower adsorption capacity and higher adsorption rate; in addition, the maximum temperature, which increased with TCE concentration, was approximate for different height measurements at central axial, but decreased for higher detected height at peripheral axial. Because of the thermal conductivity, the temperature was lower at peripheral axial than central axial. Finally, water vapor, used to regenerate the saturated bed, could help reduce the bed temperature and then slow the adsorption rate. However, water vapor was only advantageous for TCE adsorption at relative humidity lower than 50%. At higher relative humidity (80%), water molecules could occupy adsorption volume of TCE and reduce the adsorption capacity of TCE.
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Data Availability Statement
All data, models, and code generated or used during the study appear in the published article.
Acknowledgments
This research was funded by the National Science Foundation for Young Scientists of China (Grant No. 51808485), Department of Education in Shanxi Province (Grant No.2019L0853), and Shanxi Science and Technology Department (Grant No. 201901D211459).
References
Ahmad, M., S. S. Lee, A. U. Rajapaksha, M. Vithanage, M. Zhang, J. S. Cho, S. E. Lee, and Y. S. Ok. 2013. “Trichloroethylene adsorption by pine needle biochars produced at various pyrolysis temperatures.” Bioresour. Technol. 143 (Sep): 615–622. https://doi.org/10.1016/j.biortech.2013.06.033.
Akubuiro, E. C. 1993. “Potential mechanistic routes for the oxidative disintegration of ketones on carbon adsorbents.” Ind. Eng. Chem. Res. 32 (12): 2960–2968. https://doi.org/10.1021/ie00024a002.
Albayati, T. M., A. A. Sabri, and R. A. Alazawi. 2016. “Separation of methylene blue as pollutant of water by SBA-15 in a fixed-bed column.” Arab. J. Sci. Eng. 41: 2409–2415. https://doi.org/10.1007/s13369-015-1867-7.
Crini, G. 2006. “Non-conventional low-cost adsorbents for dye removal: A review.” Bioresour. Technol. 97 (9): 1061–1085. https://doi.org/10.1016/j.biortech.2005.05.001.
Dawson, R., A. I. Cooper, and D. J. Adams. 2012. “Nanoporous organic polymer networks.” Prog. Polym. Sci. 37 (4): 530–563. https://doi.org/10.1016/j.progpolymsci.2011.09.002.
Delage, F., P. Pré, and P. Le Cloirec. 2000. “Mass transfer and warming during adsorption of high concentrations of VOCs on an activated carbon bed: Experimental and theoretical analysis.” Environ. Sci. Technol. 34 (22): 4816–4821. https://doi.org/10.1021/es001187x.
Donahuea, N. M., et al. 2012. “Aging of biogenic secondary organic aerosol via gas-phase OH radical reactions.” Proc. Natl. Acad. Sci. U.S.A. 109 (34): 13503–13508. https://doi.org/10.1073/pnas.1115186109.
Downarowicz, D., and T. Aleksandrzak. 2017. “Isobutanol vapor adsorption on activated carbons: Equilibrium and kinetic studies.” J. Chem. Eng. Data. 62: 3518–3524. https://doi.org/10.1021/acs.jced.7b00528.
Furuya, E. G., H. T. Chang, Y. Miura, and K. E. Noll. 1997. “A fundamental analysis of the isotherm for the adsorption of phenolic compounds on activated carbon.” Sep. Purif. Technol. 11 (2): 69–78. https://doi.org/10.1016/S1383-5866(96)01001-5.
Gabrus, E., and D. Downarowicz. 2016. “Anhydrous ethanol recovery from wet air in TSA systems—Equilibrium and column studies.” Chem. Eng. J. 288 (Mar): 321–331. https://doi.org/10.1016/j.cej.2015.11.110.
Huang, Z., F. Kang, K. Liang, and J. Hao. 2003. “Breakthrough of methyethylketone and benzene vapors in activated carbon fiber beds.” J. Hazard. Mater. 98 (1–3): 107–115. https://doi.org/10.1016/S0304-3894(02)00284-4.
Jia, L., J. Ma, Q. Shi, and C. Long. 2017a. “Prediction of adsorption equilibrium of VOCs onto hyper-cross-linked polymeric resin at environmentally relevant temperatures and concentrations using inverse gas chromatography.” Environ. Sci. Technol. 51 (1): 522–530. https://doi.org/10.1021/acs.est.6b05039.
Jia, L., Q. Shi, S. Xie, and C. Long. 2018. “Effect of pre-adsorbed water in hydrophobic polymeric resin on adsorption equilibrium and breakthrough of 1, 2-dichloroethane.” Adsorption 24 (1): 73–80. https://doi.org/10.1007/s10450-017-9919-9.
Jia, L., X. Song, J. Wu, and C. Long. 2015. “Surface properties of hyper-cross-linked polymeric resins using inverse gas chromatography: Effect of post-cross-linking solvents.” J. Phys. Chem. C 119 (37): 21404–21412. https://doi.org/10.1021/acs.jpcc.5b07110.
Jia, L., X. Yao, J. Ma, and C. Long. 2017b. “Adsorption kinetics of water vapor on hypercrosslinked polymeric adsorbent and its comparison with carbonaceous adsorbents.” Microporous Mesoporous Mater. 241 (Mar): 178–184. https://doi.org/10.1016/j.micromeso.2016.12.028.
Kane, A., S. Giraudet, J. B. Vilmain, and P. Le Cloirec. 2015. “Intensification of the temperature-swing adsorption process with a heat pump for the recovery of dichloromethane.” J. Environ. Chem. Eng. 3 (2): 734–743. https://doi.org/10.1016/j.jece.2015.02.021.
Karanfil, T., and S. A. Dastgheib. 2004. “Trichloroethylene adsorption by fibrous and granular activated carbons: Aqueous phase, gas phase, and water vapor adsorption studies.” Environ. Sci. Technol. 38 (22): 5834–5841. https://doi.org/10.1021/es0497936.
Kato, Y., M. Machida, and H. Tatsumoto. 2008. “Inhibition of nitrobenzene adsorption by water cluster formation at acidic oxygen functional groups on activated carbon.” J. Colloid Interf. Sci. 322 (2): 394–398. https://doi.org/10.1016/j.jcis.2008.03.027.
Le Cloirec, P., P. Pre, F. Delage, and S. Giraudet. 2012. “Visualization of the exothermal VOC adsorption in a fixed-bed activated carbon adsorber.” Environ. Technol. 33 (3): 285–290. https://doi.org/10.1080/09593330.2011.571713.
Lee, J. W., J. W. Lee, W. G. Shim, S. H. Suh, and H. Moon. 2003. “Adsorption of chlorinated volatile organic compounds on MCM-48.” J. Chem. Eng. Data 48 (2): 381–387. https://doi.org/10.1021/je020158u.
Lin, X., Q. Huang, G. Qi, S. Shi, L. Xiong, C. Huang, X. Chen, H. Li, and X. Chen. 2017. “Estimation of fixed-bed column parameters and mathematical modeling of breakthrough behaviors for adsorption of levulinic acid from aqueous solution using SY-01 resin.” Sep. Purif. Technol. 174 (Mar): 222–231. https://doi.org/10.1016/j.seppur.2016.10.016.
Liu, P., C. Long, Q. Li, H. Qian, A. Li, and Q. Zhang. 2009. “Adsorption of trichloroethylene and benzene vapors onto hypercrosslinked polymeric resin.” J. Hazard. Mater. 166 (1): 46–51. https://doi.org/10.1016/j.jhazmat.2008.10.124.
Long, C., Y. Li, W. Yu, and A. Li. 2012. “Removal of benzene and methyl ethyl ketone vapor: Comparison of hypercrosslinked polymeric adsorbent with activated carbon.” J. Hazard. Mater. 203–204 (Feb): 251–256. https://doi.org/10.1016/j.jhazmat.2011.12.010.
Lorimier, C., A. Subrenat, L. Le Coq, and P. Le Cloirec. 2005. “Adsorption of toluene onto activated carbon fiber cloths and felts: Application to indoor air treatment.” Environ. Technol. 26 (11): 1217–1230. https://doi.org/10.1080/09593332608618600.
Mohammed, N., N. Grishkewich, H. A. Waeijen, R. M. Berry, and K. C. Tam. 2016. “Continuous flow adsorption of methylene blue by cellulose nanocrystal-alginate hydrogel beads in fixed bed columns.” Carbohydr. Polym. 136 (Jan): 1194–1202. https://doi.org/10.1016/j.carbpol.2015.09.099.
Moon, D. K., Y. Park, S. H. Kim, M. Oh, and C. H. Lee. 2017. “Analysis of thermal parameter effects on an adsorption bed for purification and bulk separation.” Sep. Purif. Technol. 181 (Jun): 95–106. https://doi.org/10.1016/j.seppur.2017.03.015.
Morozov, G., V. Breus, S. Nekludov, and I. Breus. 2014. “Sorption of volatile organic compounds and their mixtures on montmorillonite at different humidity.” Colloid Surf., A 454 (Jul): 159–171. https://doi.org/10.1016/j.colsurfa.2014.03.104.
Netpradit, S., P. Thiravetyan, and S. Towprayoon. 2004. “Evaluation of metal hydroxide sludge from reactive dye adsorption in a fixed-bed column system.” Water Res. 38 (1): 71–78. https://doi.org/10.1016/j.watres.2003.09.007.
Pre, P., F. Delage, and P. Le Cloirec. 2002. “A model to predict the adsorber thermal behavior during treatment of volatile organic compounds onto wet activated carbon.” Environ. Sci. Technol. 36 (21): 4681–4688. https://doi.org/10.1021/es020067h.
Ramalingam, S. G., P. Pre, S. Giraudet, L. Le Coq, P. Le Cloirec, O. Baudouin, and S. Dechelotte. 2012a. “Different families of volatile organic compounds pollution control by microporous carbons in temperature swing adsorption processes.” J. Hazard. Mater. 221–222 (Jun): 242–247. https://doi.org/10.1016/j.jhazmat.2012.04.037.
Ramalingam, S. G., P. Pre, S. Giraudet, L. Le Coq, P. Le Cloirec, O. Baudouin, and S. Dechelotte. 2012b. “Recovery comparisons—Hot nitrogen vs steam regeneration of toxic dichloromethane from activated carbon beds in oil sands process.” J. Hazard. Mater. 205 (Feb): 222–228. https://doi.org/10.1016/j.jhazmat.2011.12.062.
Ramalingam, S. G., J. Saussac, P. Pre, S. Giraudet, L. Le Coq, P. Le Cloirec, S. Nicolas, O. Baudouin, S. Dechelotte, and A. Medevielle. 2011. “Hazardous dichloromethane recovery in combined temperature and vacuum pressure swing adsorption process.” J. Hazard. Mater. 198 (Dec): 95–102. https://doi.org/10.1016/j.jhazmat.2011.10.019.
Salih, H. H., G. A. Sorial, C. L. Patterson, R. Sinha, and E. R. Krishnan. 2012. “Removal of trichloroethylene by activated carbon in the presence and absence of nanoparticles.” Water Air Soil Pollut. 223 (5): 2837–2847. https://doi.org/10.1007/s11270-011-1070-8.
Shafeeyan, M. S., W. Daud, A. Shamirit, and N. Aghamohammadi. 2015. “Modeling of carbon dioxide adsorption onto ammonia-modified activated carbon: Kinetic analysis and breakthrough behavior.” Energy Fuels 29 (10): 6565–6577. https://doi.org/10.1021/acs.energyfuels.5b00653.
Shim, W. G., J. W. Lee, and H. Moon. 2003. “Equilibrium and fixed-bed adsorption of n-hexane on activated carbon.” Sep. Sci. Technol. 38 (16): 3905–3926. https://doi.org/10.1081/SS-120024711.
Shim, W. G., J. W. Lee, and H. Moon. 2006. “Adsorption equilibrium and column dynamics of VOCs on MCM-48 depending on pelletizing pressure.” Microporous Mesoporous Mater. 88 (1–3): 112–125. https://doi.org/10.1016/j.micromeso.2005.08.026.
Virtanen, A., et al. 2010. “An amorphous solid state of biogenic secondary organic aerosol particles.” Nature 467 (7317): 824–827. https://doi.org/10.1038/nature09455.
Wu, C., T. Chung, T. Yang, and M. Chen. 2006. “Dynamic determination of the concentration of volatile alcohols in a fixed bed of zeolite 13X by FT-IR.” J. Hazard. Mater. 137 (2): 893–898. https://doi.org/10.1016/j.jhazmat.2006.03.007.
Wu, J., L. Jia, L. Wu, C. Long, W. Deng, and Q. Zhang. 2016. “Prediction of the breakthrough curves of VOC isothermal adsorption on hypercrosslinked polymeric adsorbents in a fixed bed.” RSC Adv. 6 (34): 28986–28993. https://doi.org/10.1039/C6RA01310D.
Wu, J., L. Zhang, C. Long, and Q. Zhang. 2012. “Adsorption characteristics of pentane, hexane, and heptane: Comparison of hydrophobic hypercrosslinked polymeric adsorbent with activated carbon.” J. Chem. Eng. Data 57 (12): 3426–3433. https://doi.org/10.1021/je300550x.
Wu, L., L. Jia, X. Liu, and C. Long. 2015. “The prediction of adsorption isotherms of ester vapors on hypercrosslinked polymeric adsorbent.” Front. Environ. Sci. Eng. 10 (3): 482–490. https://doi.org/10.1007/s11783-015-0826-6.
Yoon, Y. H., and J. H. Nelson. 1984. “Application of gas adsorption kinetics. I: A theoretical model for respirator cartridge service life.” Am. Ind. Hyg. Assoc. J. 45 (8): 509–516. https://doi.org/10.1080/15298668491400197.
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Received: Dec 26, 2019
Accepted: Mar 10, 2020
Published online: May 30, 2020
Published in print: Aug 1, 2020
Discussion open until: Oct 30, 2020
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