Preparation of AC/Cu-BTC Composite and Its Adsorption Mechanisms
Publication: Journal of Environmental Engineering
Volume 146, Issue 4
Abstract
The copper-based metal organic framework Cu-BTC (Copper Benzene-1,3,5-tricarboxylate) was synthesized by the solvothermal method, and AC/Cu-BTC composites were prepared by introducing different proportions of activated carbon (AC) into the reaction process by in situ synthesis. Various measures, including the use of an X-ray diffractometer (XRD), Fourier transform infrared spectrometer (FT-IR), scanning electron microscope (SEM), and adsorption apparatus were applied to characterize the structure, morphology, and surface area of Cu-BTC and AC/Cu-BTC. The adsorption properties and mechanism of methylene blue (MB) and methylene orange (MO) onto Cu-BTC and AC/Cu-BTC were studied. The results showed that Cu-BTC and AC/Cu-BTC have the same octahedral structure. The adsorption amount of MB onto AC/Cu-BTC composites was higher than that of Cu-BTC. The adsorption of MB onto Cu-BTC and AC/Cu-BTC was much higher than MO. The adsorption isotherms of MB and MO onto Cu-BTC and AC/Cu-BTC could be described by the Langmuir model, while the adsorption kinetics of the two adsorbents followed the pseudo second-order model. The negative values and illustrate the spontaneity and exothermicity of the process. The adsorption amount of MB on AC/Cu-BTC decreased from 49.39 to after 3 cycles of reuse.
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Data Availability Statement
All data and models generated or used during this study appear in the published article.
Acknowledgments
This work was supported by the National Natural Science Foundation (No. 51278418) of the PR China.
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Journal of Environmental Engineering
Volume 146 • Issue 4 • April 2020
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©2020 American Society of Civil Engineers.
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Received: May 18, 2019
Accepted: Sep 18, 2019
Published online: Feb 13, 2020
Published in print: Apr 1, 2020
Discussion open until: Jul 13, 2020
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