Factors Affecting Slurry Oxidation in a Wet Flue Gas Desulfurization Process
Publication: Journal of Environmental Engineering
Volume 145, Issue 10
Abstract
At present, wet flue gas desulfurization (FGD) systems offer insufficient control of the oxidation process. This study proposes to optimize the oxidation process of desulfurization slurry by an oxidation reduction potential (ORP) control strategy. By designing a orthogonal test, the effects of temperature, concentration, rotation speed, air flow rate, and pH on ORP were investigated at different oxidation stages of . Based on the analysis of variance, the order of contribution of different influencing factors at the specific oxidation stage was obtained. The influence degree of specific influencing factors on ORP was different, and the trend is explained for each different oxidation stage as well. The results indicate that only the temperature plays a significant role in the change of ORP during the whole oxidation process, which clarifies that the temperature affects the oxidation process of by affecting the dissolution of and and the transformation of S(IV) to S(VI). The results also provide theoretical guidance for precise oxidation control of the FGD slurry system.
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References
Brown, S. R., R. F. DeVault, and D. B. Johnson. 2013. “ORP as a predictor of WFGD chemistry and wastewater treatment.” Power 157 (7): 40–42.
CEC (China Electricity Council). 2015. China’s electric power industry annual development report 2015. Beijing: China Electric Power Press.
Cheng, C. M., Y. Cao, and K. Zhang. 2013. “Co-effects of sulfur dioxide load and oxidation air on mercury re-emission in forced-oxidation limestone flue gas desulfurization wet scrubber.” Fuel 106 (4): 505–511. https://doi.org/10.1016/j.fuel.2012.11.068.
Chinese Standard. 2011. Translated english of Chinese Standard. GB 13223. Beijing: Chinese Standard.
Córdoba, P. 2017. “Partitioning and speciation of selenium in wet limestone flue gas desulphurisation (FGD) systems: A review.” Fuel 202 (8): 184–195. https://doi.org/10.1016/j.fuel.2017.04.015.
Córdoba, P., R. Ochoa-Gonzalez, and O. Font. 2012. “Partitioning of trace inorganic elements in a coal-fired power plant equipped with a wet flue gas desulphurisation system.” Fuel 92 (1): 145–157. https://doi.org/10.1016/j.fuel.2011.07.025.
Dedo, J. E. D., F. Z. Idrissi, and P. Garcia. 2017. “ORP-mediated ER contact with endocytic sites facilitates actin polymerization.” Dev. Cell 43 (5): 588–602. https://doi.org/10.1016/j.devcel.2017.10.031.
Geboes, B., K. Baert, and A. Hubin. 2015. “Investigation of the adsorption mechanism of heterocyclic molecules on copper using potentiodynamic ORP-EIR and in-situ Ramans pectroscopy.” Electrochim. Acta 156 (2): 308–315. https://doi.org/10.1016/j.electacta.2015.01.036.
Huang, X. M., J. Ding, and Y. Jia. 2015. “Kinetics of sulfite oxidation in the simultaneous desulfurization and denitrification of the oxidation-absorption process.” Chem. Eng. Technol. 38 (5): 797–803. https://doi.org/10.1002/ceat.201300590.
Huss, A., P. K. Lim, and C. A. Eckert. 2002. “The “uncatalyzed” oxidation of sulfur(IV)in aqueous solutions.” J. Am. Chem. Soc. 100 (19): 6252–6253. https://doi.org/10.1021/ja00487a059.
Li, Q. W., L. D. Wang, and Y. Zhao. 2014. “Oxidation rate of magnesium sulfite catalyzed by cobalt ions.” Environ. Sci. Technol. 48 (7): 4145–4152. https://doi.org/10.1021/es404872w.
Lv, Y., C. E. Romero, and C. Joshua. 2019. “Developing steady and dynamic orp models for mercury emissions control in power plants using WFGD operating data.” Fuel 235 (1): 54–62. https://doi.org/10.1016/j.fuel.2018.07.058.
Mei, Y., L. Gao, and H. Zhou. 2018. “Ranking media for multi-pollutant removal efficiency in bioretention.” Water Sci. Technol. 77 (8): 2023–2035. https://doi.org/10.2166/wst.2018.115.
NSTCC (National Standardization Technical Committee of Chemical). 2002. Chemical reagent—Preparations of reagent solutions for impurity. GB/T 601-2016. Beijing: NSTCC.
Pang, S. L., R. Chen, and J. Mao. 2016. “Separation treatment process for limestone-gypsum wet FGD wastewater from coal-fired power plants.” Therm. Power Gener. 45 (9): 128–133.
Pisu, M., A. Cincotti, and G. Cao. 2004. “Prediction of uncatalysed calcium bisulphite oxidation under operating conditions relevant to wet flue gas desulphurization plants.” Chem. Eng. Res. Des. 82 (7): 927–932. https://doi.org/10.1205/0263876041596652.
SAPRC (Standardization Administration of the People’s Republic of China). 2016. Chemical reagent—Preparations of reference titration solutions. GB/T 603-2002. Beijing: SAPRC.
Solis, K. L. B., G. Nam, and Y. Hong. 2017. “Mercury (II) reduction and sulfite oxidation in aqueous systems: Kinetics study and speciation modeling.” Environ. Chem. 14 (3): 151–159. https://doi.org/10.1071/EN16169.
Vanginkel, S. W., C. Zhou, and M. Lien. 2015. “Hydrogen-based nitrate and selenate bioreductions in flue-gas desulfurization brine.” J. Environ. Eng. 137 (1): 63–68. https://doi.org/10.1061/(ASCE)EE.1943-7870.0000288.
Wang, L. D., J. Wang, and P. Y. Xu. 2015. “Selectivity of transition metal catalysts in promoting the oxidation of solid sulfites in flue gas desulfurization.” Appl. Catal., A 508 (11): 80–85. https://doi.org/10.1016/j.apcata.2015.10.014.
Xu, G., X. Yuan, and Y. P. Yang. 2012a. “Optimization operation of flue gas desulfurization systems in power plants for energy conservation.” Chin. Soc. Electr. Eng. 32 (32): 22–29.
Xu, H. J., S. F. Wang, and W. G. Pan. 2012b. “Investigation of the kinetics of sulfite oxidation on by-production recovery process in WFGD.” Adv. Mater. Res. 610–613 (12): 1980–1985.
Yu, R. F., H. W. Chen, and W. P. Cheng. 2009. “Dosage control of the Fenton process for color removal of textile wastewater applying ORP monitoring and artificial neural networks.” J. Environ. Eng. 135 (5): 325–332. https://doi.org/10.1061/(ASCE)EE.1943-7870.0000016.
Zhang, C., J. B. Guo, and L. Jing. 2018. “Bio-mixotrophic perchlorate reduction to control sulfate production in a step-feed sulfur-based reactor: A study of kinetics, ORP and bacterial community structure.” Bioresour. Technol. 269 (12): 40–49. https://doi.org/10.1016/j.biortech.2018.08.084.
Zhang, L., S. Wang, and Q. Wu. 2016. “Mercury transformation and speciation in flue gases from anthropogenic emission sources: A critical review.” Atmos. Chem. Phys. 16 (4): 2417–2433. https://doi.org/10.5194/acp-16-2417-2016.
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©2019 American Society of Civil Engineers.
History
Received: Sep 8, 2018
Accepted: Jan 18, 2019
Published online: Jul 19, 2019
Published in print: Oct 1, 2019
Discussion open until: Dec 19, 2019
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