Technical Papers
Feb 14, 2018

Efficient Recycling of Copper from Waste-Printed Circuit Boards via Suspension Electrolysis Using Response Surface Methodology

Publication: Journal of Environmental Engineering
Volume 144, Issue 4

Abstract

Recycling of waste printed circuit boards (WPCBs) is an important subject not only for the protection of the environment, but also for the recovery of valuable materials, especially copper. In this paper, an effective and benign process for copper recovery from WPCBs is presented. In the process, copper in the WPCBs was treated through suspension electrolysis to gain copper powder. The effects of process parameters of H2SO4 and CuSO4 concentrations and the current density were studied. Experimental results showed that the suspension electrolysis process is an effective method to recover copper from WPCBs. The X-ray diffraction (XRD) and electronic differential system (EDS) spectra indicated no other impurities in the recycled copper. The copper recovery conditions were optimized using a Box-Behnken design of response surface methodology. The optimum conditions were observed when the solution contained 30  g/LCuSO4, 110  g/L  H2SO4, and current density of 3  A/dm2, resulting in a recovery efficiency of 86.46%. The results indicate the process as a promising method to recover copper from WPCBs.

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Acknowledgments

This work was financially supported by the National Natural Science Foundation of China (51568050, 51768046), the Technology Support Program of Jiangxi Province (20161BBG70042), and the Young Scientist Cultivation Plan of Jiangxi Province (20153BCB23039).

References

Ahmadi, M., Vahabzadeh, F., Bonakdarpour, B., Mofarrah, E., and Mehranian, M. (2005). “Application of the central composite design and response surface methodology to the advanced treatment of olive oil processing wastewater using Fenton’s peroxidation.” J. Hazard. Mater., 123(1–3), 187–195.
Birloaga, I., De Michelis, I., Ferella, F., Buzatu, M., and Vegliò, F. (2013). “Study on the influence of various factors in the hydrometallurgical processing of waste printed circuit boards for copper and gold recovery.” Waste Manage., 33(4), 935–941.
Chi, T. D., Lee, J. C., Pandey, B. D., Yoo, K., and Jeong, J. (2011). “Bioleaching of gold and copper from waste mobile phone PCBs by using a cyanogenic bacterium.” Miner. Eng., 24(11), 1219–1222.
Ebrahimzadeh, H., Behbahani, M., Yamini, Y., Adlnasab, L., and Asgharinezhad, A. A. (2013). “Optimization of Cu(II)-ion imprinted nanoparticles for trace monitoring of copper in water and fish samples using a Box-Behnken design.” React. Funct. Polym., 73(1), 23–29.
Fogarasi, S., Imre-Lucaci, F., Ilea, P., and Imre-Lucaci, Á. (2013). “The environmental assessment of two new copper recovery processes from waste printed circuit boards.” J. Cleaner Prod., 54(1), 264–269.
Huang, J., Chen, M., Chen, H., Chen, S., and Sun, Q. (2014). “Leaching behavior of copper from waste printed circuit boards with Brønsted acidic ionic liquid.” Waste manage., 34(2), 483–488.
Huang, K., Guo, J., and Xu, Z. M. (2009). “Recycling of waste printed circuit boards: A review of current technologies and treatment status in China.” J. Hazard. Mater., 164(2–3), 399–408.
Li, J., Lu, H., Guo, J., Xu, Z., and Zhou, Y. H. (2007). “Recycle technology for recovering resources and products from waste printed circuit boards.” Environ. Sci. Technol., 41(6), 1995–2000.
Liu, M., Huang, B., Bi, X. H., Ren, Z. F., Sheng, G. Y., and Fu, J. M. (2013). “Heavy metals and organic compounds contamination in soil from an e-waste region in south China.” Environ. Sci. Processes Impacts, 15(5), 919–929.
Mathews, P. G. (2005). Design of experiments with MINITAB, ASQ Quality, Milwaukee.
Montgomery, D. C. (2001). Design and analysis of experiments, 5th Ed., Wiley, Hoboken, NJ.
Mourabet, M., El Rhilassi, A., El Boujaady, H., Bennani-Ziatni, M., El Hamri, R., and Taitai, A. (2012). “Removal of fluoride from aqueous solution by adsorption on apatitic tricalcium phosphate using Box-Behnken design and desirability function.” Appl. Surf. Sci., 258(10), 4402–4410.
Wu, D., Zhou, J., and Li, Y. (2009). “Effect of the sulfidation process on the mechanical properties of a CoMoP/Al2O3 hydrotreating catalyst.” Chem. Eng. Sci., 64(2), 198–206.
Xiang, Y., et al. (2010). “Bioleaching of copper from waste printed circuit boards by bacterial consortium enriched from acid mine drainage.” J. Hazard. Mater., 184(1), 812–818.
Xing, M. F., and Zhang, F. S. (2013). “Degradation of brominated epoxy resin and metal recovery from waste printed circuit boards through batch sub/supercritical water treatments.” Chem. Eng. J., 219(1), 131–136.
Xiu, F. R., Qi, Y. Y., and Zhang, F. S. (2014). “Co-treatment of waste printed circuit boards and polyvinyl chloride by subcritical water oxidation: Removal of brominated flame retardants and recovery of Cu and Pb.” Chem. Eng. J., 237(1), 242–249.
Xiu, F. R., and Zhang, F. S. (2009). “Recovery of copper and lead from waste printed circuit boards by supercritical water oxidation combined with electrokinetic process.” J. Hazard. Mater., 165(1–3), 1002–1007.
Xiu, F. R., and Zhang, F. S. (2010). “Materials recovery from waste printed circuit boards by supercritical methanol.” J. Hazard. Mater., 178(1), 628–634.
Xiu, F. R., and Zhang, F. S. (2014). “Copper recovery and gold enrichment from waste printed circuit boards by mediated electrochemical oxidation.” J. Hazard. Mater., 273(30), 215–221.
Yang, J. G., Wu, Y. T., and Li, J. (2012). “Recovery of ultrafine copper particles from metal components of waste printed circuit boards.” Hydrometallurgy, 121–124(6), 1–6.
Yang, Y. K., Chen, S., Li, S. C., Chen, M. J., Chen, H. Y., and Liu, B. J. (2014). “Bioleaching waste printed circuit boards by Acidithiobacillus ferrooxidans and its kinetics aspect.” J. Biotechnol., 173(10), 24–30.
Zeng, X. L., et al. (2012). “Current status and future perspective of waste printed circuit boards recycling.” Procedia Environ. Sci., 16(4), 590–597.
Zhang, K., Schnoor, J. L., and Zeng, E. Y. (2012). “E-waste recycling: Where does it go from here?” Environ. Sci. Technol., 46(20), 10861–10867.
Zhao, G. H., Luo, X. Z., and Chen, G. (2014). “A long-term static immersion experiment on the leaching behavior of heavy metals from waste printed circuit boards.” Environ. Sci. Processes Impacts, 16(8), 1967–1974.
Zhu, N., et al. (2011). “Bioleaching of metal concentrates of waste printed circuit boards by mixed culture of acidophilic bacteria.” J. Hazard. Mater., 192(2), 614–619.
Zhu, P., et al. (2013a). “Dissolution of brominated epoxy resins by dimethyl sulfoxide to separate waste printed circuit boards.” Environ. Sci. Technol., 47(6), 2654–2660.
Zhu, P., Chen, Y., Wang, L. Y., Zhou, M., and Zhou, J. (2013b). “The separation of waste printed circuit board by dissolving bromine epoxy resin using organic solvent.” Waste Manage., 33(2), 484–488.

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Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 144Issue 4April 2018

History

Received: Jun 2, 2017
Accepted: Sep 28, 2017
Published online: Feb 14, 2018
Published in print: Apr 1, 2018
Discussion open until: Jul 14, 2018

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Authors

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Guisheng Zeng [email protected]
Professor, Key Laboratory of Jiangxi Province for Persistent Pollutants Control and Resources Recycle, School of Environmental and Chemical Engineering, Nanchang Hangkong Univ., Nanchang 330063, China (corresponding author). E-mail: [email protected]
Xingzhen Sui [email protected]
Master’s Student, Key Laboratory of Jiangxi Province for Persistent Pollutants Control and Resources Recycle, School of Environmental and Chemical Engineering, Nanchang Hangkong Univ., Nanchang 330063, China. E-mail: [email protected]
Master’s Student, Key Laboratory of Jiangxi Province for Persistent Pollutants Control and Resources Recycle, School of Environmental and Chemical Engineering, Nanchang Hangkong Univ., Nanchang 330063, China. E-mail: [email protected]
Zhongjun Li [email protected]
Master’s Student, Key Laboratory of Jiangxi Province for Persistent Pollutants Control and Resources Recycle, School of Environmental and Chemical Engineering, Nanchang Hangkong Univ., Nanchang 330063, China. E-mail: [email protected]
Master’s Student, Key Laboratory of Jiangxi Province for Persistent Pollutants Control and Resources Recycle, School of Environmental and Chemical Engineering, Nanchang Hangkong Univ., Nanchang 330063, China. E-mail: [email protected]

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