Technical Notes
Jul 27, 2017

Shipboard Wastewater Treatment Using Granular Activated Carbon: Adsorption Test and Bioregeneration

Publication: Journal of Environmental Engineering
Volume 143, Issue 10

Abstract

In this study, the adsorption of granular activated carbon (GAC) was evaluated in the treatment of slop with the aim of reducing the organic matter concentration in terms of chemical oxygen demand (COD), dissolved organic carbon (DOC), and total petroleum hydrocarbons (TPH). The process was optimized for the oily wastewaters sampled from a floating tank of an oil coastal deposit in the Augusta Harbor (Sicily, Italy). In particular, both batch and dynamic tests were performed. Two different GACs were used and compared. In general, the application of the adsorption process was effective in the treatment of the slop. In fact, the percentages of removal, although rarely exceeding 65% in term of COD, reduced the overall organic load resulting from recalcitrant or poorly biodegradable substances (efficiency greater than 70–80% in terms of DOC and TPH). However, a pretreatment with 20  gGAC/L is also sustainable for the removal of the main contaminants and for the pretreatment of the wastewater, improving the treatment before a subsequent biological process.

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Acknowledgments

This work was supported by an industrial scientific project financed by the Italian government inside the National Operative Program “Research and Competitiveness 2007–2013” (title of project: “SibSac—An integrated system for sediments remediation and high salinity marine wastewaters treatment”).

References

Anirudhan, T. S., Sreekumari, S. S., and Bringle, C. D. (2009). “Removal of phenols from water and petroleum industry refinery effluents by activated carbon obtained from coconut coir pith.” Adsorption, 15(5–6), 439–451.
APAT and IRSA-CNR (Agenzia per la Protezione dell’Ambiente and Istituto di Ricerca Sulle Acque-Consiglio Nazionale delle Ricerche). (2003). Analytical methods for waters (Manuali e linee guida 29/2003 in Italian).
APHA (American Public Health Association). (2005). Standard methods for the examination of water and wastewater, APHA, AWWA, and WPCF, Washington, DC.
ASTM. (2008). “Standard practice for determination of adsorptive capacity of activated carbon by aqueous phase isotherm technique.” ASTM D 3860-98, West Conshohocken, PA.
Bilello, L. J., and Beaudet, B. A. (1983). “Evaluation of activated carbon by the dynamic minicolumn adsorption technique.” Treatment of water by granular activated carbon, M. J. McGuire and I. H. Suffet, eds., American Chemical Society, Washington, DC.
Cooney, D. O. (1999). Adsorption design for wastewater treatment, CRC Press LLC, Boca Raton, FL.
Crittenden, J. C., et al. (1991). “Predicting GAC performance with rapid small-scale column tests.” J. Am. Water Works Assn., 83(1), 77–87.
Di Bella, G., et al. (2015). “Performance of membrane bioreactor (MBR) systems for the treatment of shipboard slop: Assessment of hydrocarbon biodegradation and biomass activity under salinity variation.” J. Hazard. Mater., 300, 765–778.
Di Bella, G., Giustra, M. G., and Freni, G. (2014). “Optimization of coagulation/flocculation for pre-treatment of high strength and saline wastewater: Performance analysis with different coagulant doses.” Chem. Eng. J., 254, 283–292.
Dobbs, R. A., and Cohen, J. M. (1980). “Carbon adsorption isotherms for toxic organic.”, U.S. Environmental Protection Agency, Washington, DC.
Freundlich, H. M. F. (1906). “Over the adsorption in solution.” J. Phys. Chem., 57(385471), 1100–1107.
Giusti, D. M., Conway, R. A., and Lawson, C. T. (1974). “Activated carbon adsorption of petrochemicals.” J. Water Pollut. Control Fed., 46(5), 947–965.
Guo, D., Shi, Q., He, B., and Yuan, X. (2011). “Different solvents for the regeneration of the exhausted activated carbon used in the treatment of coking wastewater.” J. Hazard. Mater., 186(2–3), 1788–1793.
Islam, M. S., Zhang, Y., McPhedran, K. N., Liu, Y., and El-Din, M. G. (2016). “Mechanistic investigation of industrial wastewater naphthenic acids removal using granular activated carbon (GAC) biofilm based processes.” Sci. Total Environ., 541, 238–246.
Klimenko, N., Smolin, S., Grechanyk, S., Kofanov, V., Nevynna, L., and Samoylenko, L. (2004). “Bioregeneration of activated carbons by bacterial degraders after adsorption of surfactants from aqueous solutions.” Colloids Surf. A: Physicochemical and Engineering Aspects, 230(1–3), 141–158.
Li, G., Guo, S. H., and Li, F. M. (2010). “Treatment of oilfield produced water by anaerobic process coupled with micro-electrolysis.” J. Environ. Sci., 22(12), 1875–1882.
Magriotis, Z. M., Leal de Sales, P. F., Papini, R. M., Viana, P. R. M., and Arroyoc, P. A. (2014). “A comparative study for the removal of mining wastewater by kaolinite, activated carbon and beta zeolite.” Appl. Clay Sci., 91–92, 55–62.
Mancini, G., Cappello, S., Yakimov, M. M., Polizzi, A., and Torregrossa, M. (2010). “Biological approaches to the treatment of saline oily waste (waters) originated from marine transportation.” Chem. Eng. Trans., 27, 37–42.
MARPOL. (1997). “Prevention of air pollution from ships.”, International Maritime Organization, London.
McKay, G. D., Bino, M. J., and Alabama, A. R. (1985). “The adsorption of various pollutants from aqueous solution onto activated carbon.” Water Res., 19(4), 491–495.
Messineo, A., Freni, G., and Volper, R. (2012). “Collection of thermal energy available from a biogas plant for leachate treatment in an urban landfill: A sicilian case study.” Energies, 5(10), 3753–3767.
Metcalf, L., and Eddy, H. P. (2003). Wastewater engineering—Treatment and reuse, 4th Ed., McGraw-Hill, New York.
Mohan, D., Singh, K. P., and Singh, V. K. (2008). “Wastewater treatment using low cost activated carbons derived from agricultural byproducts—A case study.” J. Hazard. Mater., 152(3), 1045–1053.
Šereš, Z., et al. (2016). “Treatment of vegetable oil refinery wastewater using alumina ceramic membrane: Optimization using response surface methodology.” J. Cleaner Prod., 112, 3132–3137.
Snoeyink, V. L., and Weber, W. J. (1967). “The surface chemistry of active carbon: A discussion of structure and surface functional groups.” Environ. Sci. Technol., 1(3), 228–234.
Sun, C., Leiknes, T., Weitzenbock, J., and Thorstensen, B. (2010). “Development of a biofilm-MBR for shipboard wastewater treatment: The effect of process configuration.” Desalination, 250(2), 745–750.
Tong, K., Lin, A., Ji, G., Wang, D., and Wang, X. (2016). “The effects of adsorbing organic pollutants from super heavy oil wastewater by lignite activated coke.” J. Hazard. Mater., 308(5), 113–119.
Tong, K., Zhang, Y., Liu, G., Ye, Z., and Chu, P. K. (2013). “Treatment of heavy oil wastewater by a conventional activated sludge process coupled with an immobilized biological filter.” Int. Biodeterior. Biodegrad, 84(4), 65–71.
Treybal, R. E. (1988). Mass transfer operation, 10th Ed., McGraw-Hill, New York.
Wang, Y., et al. (2016). “An alternative anaerobic treatment process for treatment of heavy oil refinery wastewater containing polar organics.” Biochem. Eng. J., 105(A), 44–51.
Weber, W. J., and Morris, J. C. (1963). “Kinetics of adsorption on carbon from solution.” J. Sanitary Eng. Div., 89(2), 31–60.
Yadav, T. C., Pal, R. R., Shastri, S., Jadeja, N. B., and Kapley, A. (2015). “A comparative metagenomics demonstrating different degradative capacity of activated biomass treating hydrocarbon contaminated wastewater.” Bioresour. Technol., 188, 24–32.
Younker, J. M., and Walsh, M. E. (2015). “Impact of salinity and dispersed oil on adsorption of dissolved aromatic hydrocarbons by activated carbon and organoclay.” J. Hazard. Mater., 299(2), 562–569.

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Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 143Issue 10October 2017

History

Received: Sep 30, 2016
Accepted: Apr 14, 2017
Published online: Jul 27, 2017
Published in print: Oct 1, 2017
Discussion open until: Dec 27, 2017

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Authors

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M. G. Giustra, Ph.D. [email protected]
Assistant Researcher, Univ. of Enna “Kore,” Cittadella Universitaria, 94100 Enna, Italy (corresponding author). E-mail: [email protected]
G. Di Bella, Ph.D. [email protected]
Associate Professor, Univ. of Enna “Kore,” Cittadella Universitaria, 94100 Enna, Italy. E-mail: [email protected]

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