Technical Papers
Jul 6, 2017

Aggregation and Fouling Impacts in Determining Organic and Clay Removal by Electropositive Filtration

Publication: Journal of Environmental Engineering
Volume 143, Issue 9

Abstract

Electropositive filtration (EPF) uses a macroporous filter media with a strong positive charge to achieve high separation factors for substances many times smaller than its nominal pore size; however, the variables that affect its performance are poorly understood. The objective of this work was to elucidate the significance of filter fouling and particle size in relation to electroadhesion in determining material removal by an electropositive filter. EPF performance was evaluated using humic acid (HA) and montmorillonite clay in adsorption and dead-end filtration experiments. Comparative analyses were done with a negatively charged microglass filter of similar nominal pore size. The electropositive filter had a higher selectivity for HA and clay because of favorable charge–charge interactions. HA and clay removal were governed by aggregate size and filter fouling. For the HA, accumulation of negatively charged material on the electropositive filter resulted in decreased removal as filtration progressed because of screening of the charge interactions. For the clay, rapid fouling resulted in high removal but plugging of the filter. Precoagulation resulted in optimum performance conditions—high selectivity and low headloss development.

Get full access to this article

View all available purchase options and get full access to this article.

Acknowledgments

We would like to thank Ahlstrom Corporation for funding this work and for providing samples of electropositive filters for testing. We would also like to thank Dr. Tzahi Cath for carrying out the streaming potential analysis of the electropositive filters.

References

Baik, M., and Lee, S. (2010). “Colloidal stability of bentonite clay considering surface charge properties as a function of pH and ionic strength.” J. Ind. Eng. Chem., 16(5), 837–841.
Benjamin, M. M. L., and Desmond, F. (2013). Water quality engineering, Wiley, Hoboken, NJ.
Brant, J. A., and Childress, A. E. (2004). “Colloidal adhesion to hydrophilic membrane surfaces.” J Membr. Sci, 241(2), 235–248.
Cashdollar, J., and Dahling, D. (2006). “Evaluation of a method to re-use electropositive cartridge filters for concentrating viruses from tap and river water.” J. Virological Methods, 132(1–2), 13–17.
Duman, O., and Tunc, S. (2009). “Electrokinetic and rheological properties of Na-bentonite in some electrolyte solutions.” Microporous Mesoporous Mater., 117(1–2), 331–338.
El-Azizi, I. M., Schmalenberger, A., Komlenic, R., and Edyvean, R. G. J. (2011). “Study of a depth filter (Disruptor (TM)) for the novel application of reducing SWRO membrane fouling.” Desalin Water Treat, 29(1–3), 20–28.
Etelka Tombácz, M. S. (2006). “Surface charge heterogeneity of kaolinite in aqueous suspension in comparison with montmorillonite.” Appl. Clay Sci., 34(1–4), 105–124.
Gaffney, J., Marley, N., and Clark, S. (1996). “Humic and fulvic acids and organic colloidal materials in the environment.” Humic Fulvic Acids, 651(1), 2–16.
Grenier, A., Meireles, M., Aimar, P., and Carvin, P. (2008). “Analysing flux decline in dead-end filtration.” Chem. Eng. Res. Des., 86(11A), 1281–1293.
Henry, C., Dorr, B., and Brant, J. A. (2012). “Buckminsterfullerene (C-60) nanoparticle fouling of microfiltration membranes operated in a cross-flow configuration.” Sep Purif Technol, 100(1), 30–43.
Hermia, J. (1982). “Constant pressure blocking filtration laws—Application to power-law non-Newtonian fluids.” T I Chem Eng-Lond, 60(3), 183–187.
Hinds, W. C. (1999). Aerosol technology: Properties, behavior, and measurement of airborne particles, Wiley, New York.
Ho, C., and Zydney, A. (2000). “A combined pore blockage and cake filtration model for protein fouling during microfiltration.” J. Colloid Interface Sci., 232(2), 389–399.
Hong, S., and Elimelech, M. (1996). “Chemical and physical aspects of natural organic matter fouling of nanofiltration membranes.” J. Membr. Sci. 132(2), 159–181.
Katsoufidou, K., Yiantsios, S., and Karabelas, A. (2008). “An experimental study of UF membrane fouling by humic acid and sodium alginate solutions: The effect of backwashing on flux recovery.” Desalination, 220(1–3), 214–227.
Komlenic, R. (2007). “Water filtration media: Talking about a revolution?” Filtr Separat, 44(5), 26–29.
Kornbrekke, R. E., Morrison, I. D., and Oja, T. (1992). “Electrophoretic mobility measurements in low conductivity media.” Langmuir, 8(4), 1211–1217.
Lee, K. W., and Liu, B. Y. H. (1982). “Theoretical-study of aerosol filtration by fibrous filters.” Aerosol Sci Tech, 1(2), 147–161.
Michael-Kordatou, I., et al. (2015). “Dissolved effluent organic matter: Characteristics and potential implications in wastewater treatment and reuse applications.” Water Res., 77(15), 213–248.
Ning, R. Y., and Troyer, T. L. (2007). “Colloidal fouling of RO membranes following MF/UF in the reclamation of municipal wastewater.” Desalination, 208(1–3), 232–237.
Ritchie, J. D., and Purdue, E. M. (2003). “Acidic functional groups of IHSS samples.” Geochim. Cosmochim, 67(1), 85–96.
Saka, E. E., and Guler, C. (2006). “The effects of electrolyte concentration, ion species and pH on the zeta potential and electrokinetic charge density of montmorillonite.” Clay Miner, 41(4), 853–861.
Sakka S. (ed.) (2005). “Processing, characterization and applications, Volumes I–III.” Handbook of sol-gel science and technology, American Chemical Society, Washington, DC.
Schafer, A. I., Fane, A. G., and Waite, T. D. (2000). “Fouling effects on rejection in the membrane filtration of natural waters.” Desalination, 131(1–3), 215–224.
Sutzkover-Gutman, I., Hasson, D., and Semiat, R. (2010). “Humic substances fouling in ultrafiltration processes.” Desalination, 261(3), 218–231.
Tepper, F., and Kaledin, L. (2006). “A high-performance electropositive filter.” BioProcess Int., 4(6), 64–68.
Thurman, E. M. (1985). Organic geochemistry of natural waters, Kluwer Academic, Hingham, MA.
Tien, C. (2012). Principles of filtration, Elsevier, Oxford, U.K.
Tien, C., and Ramarao, B. (2011). “Revisiting the laws of filtration: An assessment of their use in identifying particle retention mechanisms in filtration.” J. Membr. Sci., 383(1–2), 17–25.
Tombacz, E., and Szekeres, M. (2004). “Colloidal behavior of aqueous montmorillonite suspensions: The specific role of pH in the presence of indifferent electrolytes.” Appl. Clay Sci., 27(1–2), 75–94.
Wang, F. L., and Tarabara, V. V. (2008). “Pore blocking mechanisms during early stages of membrane fouling by colloids.” J Colloid Interf Sci, 328(2), 464–469.
Westerhoff, P., and Chiu, C.-A. (2008). “Evaluating filtration products for organic carbon removal.” Ahlstrom Filtration LLC, Helsinki, Finland, 1–10.
Wiesner, M., Lowry, G. V., Alvarez, P., Dionysiou, D., and Biswas, P. (2006). “Assessing the risks of manufactured nanomaterials.” Environ. Sci. Technol., 40(14), 4336–4345.
Wu, J., He, C. D., Jiang, X. Y., and Zhang, M. (2011). “Modeling of the submerged membrane bioreactor fouling by the combined pore constriction, pore blockage and cake formation mechanisms.” Desalination, 279(1–3), 127–134.
Yiantsios, S., and Karabelas, A. (1998). “The effect of colloid stability on membrane fouling.” Desalination, 118(1–3), 143–152.
Yuan, W., Kocic, A., and Zydney, A. (2002). “Analysis of humic acid fouling during microfiltration using a pore blockage-cake filtration model.” J. Membr. Sci., 198(1), 51–62.
Yuan, W., and Zydney, A. L. (1999). “Humic acid fouling during microfiltration.” J Membr. Sci., 157(1), 1–12.
Zularisam, A., Ismail, A., and Salim, R. (2006). “Behaviours of natural organic matter in membrane filtration for surface water treatment—A review.” Desalination, 194(1–3), 211–231.

Information & Authors

Information

Published In

Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 143Issue 9September 2017

History

Received: Sep 8, 2016
Accepted: Apr 5, 2017
Published online: Jul 6, 2017
Published in print: Sep 1, 2017
Discussion open until: Dec 6, 2017

Permissions

Request permissions for this article.

Authors

Affiliations

Jonathan A. Brant, Ph.D., P.E. [email protected]
Associate Professor, Univ. of Wyoming, Dept. of Civil and Architectural Engineering, 1000 E University Ave., Laramie, WY 82071 (corresponding author). E-mail: [email protected]
Graduate Student, Univ. of Wyoming, Dept. of Civil and Architectural Engineering, 1000 E University Ave., Laramie, WY 82071. E-mail: [email protected]

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

Cited by

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share