Arsenic(V) Removal from Drinking Water by Polyaluminum Chloride in a Sand Filter Medium
Publication: Journal of Environmental Engineering
Volume 143, Issue 9
Abstract
Arsenic-containing groundwater is used normally as drinking water after treatment in rural areas of some developing countries. This study describes removing arsenate [As(V)] by contact filtration on a sand media using polyaluminum chloride (PACl) as a coagulant. Arsenic-contaminated water and PACl coagulant were introduced concurrently into a sand filter column. A PACl dose of reduced the arsenic (As) concentration in a synthetic groundwater () from to less than . The 81-cm deep, 16-mm diameter single-sand column treated 38.4 pore volumes before it reached an assumed maximum allowable experimental head loss (4.50 m). Reducing the PACl dose resulted in an increased As concentration in the filter effluent. The PACl precipitate-As complex could be removed from the filter by flushing. Results suggest precipitated PACl is more efficient than aluminum oxide/hydroxide solid phases in As removal. Filter performance was shown to be independent of how the PACl was distributed in the filter column.
Get full access to this article
View all available purchase options and get full access to this article.
Acknowledgments
This work was supported by the U.S. EPA P1 Grant No. SU835516. The authors thank Cameron Willkens, Paul Charles, Tim Brock, and students William Pennock, Casey Garland, and Jason Koutoudis for their assistance during this research.
References
ATSDR (Agency for Toxic Substances and Disease Registry). (2007). “Toxicological profile for arsenic (update).” Public Health Service, U.S. Dept. of Health and Human Services, Atlanta.
Baig, S. A., Sheng, T., Hu, Y., Lv, X., and Xu, X. (2013). “Adsorptive removal of arsenic in saturated sand filter containing amended adsorbents.” Ecol. Eng., 60, 345–353.
Benjamin, M. M., Sletten, R. S., Bailey, R. P., and Bennett, T. (1996). “Sorption and filtration of metals using iron-oxide-coated sand.” Water Res., 30(11), 2609–2620.
Berg, M., Luzi, S., Trang, P. T. K., Viet, P. H., Giger, W., and Stuben, D. (2006). “Arsenic removal from groundwater by household sand filters: Comparative field study, model calculations, and health benefits.” Environ. Sci. Technol., 40(17), 5567–5573.
Chen, Z., Fan, B., Peng, X., Zhang, Z., Fan, J., and Luan, Z. (2006). “Evaluation of Al30 polynuclear species in polyaluminum solutions as coagulant for water treatment.” Chemosphere, 64(6), 912–918.
Choong, T. S. Y., Chuah, T. G., Robiah, Y., Gregory Koay, F. L., and Azni, I. (2007). “Arsenic toxicity, health hazards and removal techniques from water: An overview.” Desalination, 217(1–3), 139–166.
Clancy, T. M., Hayes, K. F., and Raskin, L. (2013). “Arsenic waste management: A critical review of testing and disposal of arsenic-bearing solid wastes generated during arsenic removal from drinking water.” Environ. Sci. Technol., 47(19), 10799–10812.
Das, B., et al. (2009). “Groundwater arsenic contamination, its health effects and approach for mitigation in West Bengal, India and Bangladesh.” Water Qual. Exposure Health, 1(1), 5–21.
Del Razo, L. M., Arellano, M. A., and Cebrián, M. E. (1990). “The oxidation states of arsenic in well-water from a chronic arsenicism area of northern Mexico.” Environ. Pollut., 64(2), 143–153.
Duan, J., and Gregory, J. (2003). “Coagulation by hydrolysing metal salts.” Adv. Colloid Interface Sci., 100, 475–502.
Fan, M., Brown, R. C., Sung, S. W., Huang, C. P., Ong, S. K., and Hans van Leeuwen, J. (2003). “Comparisons of polymeric and conventional coagulants in arsenic(V) removal.” Water Environ. Res., 75(4), 308–313.
Fitzpatrick, C. S. B. (1998). “Media properties and their effect on filter performance and backwashing.” Water Sci. Technol., 38(6), 105–111.
Gupta, V. K., Saini, V. K., and Jain, N. (2005). “Adsorption of As(III) from aqueous solutions by iron oxide-coated sand.” J. Colloid Interface Sci., 288(1), 55–60.
Jeong, Y., Fan, M., Singh, S., Chuang, C. L., Saha, B., and Hans van Leeuwen, J. (2007). “Evaluation of iron oxide and aluminum oxide as potential arsenic(V) adsorbents.” Chem. Eng. Process. Process Intensif., 46(10), 1030–1039.
Karcher, S., Cdceres, L., Jekel, M., Or-lng, P., and Contreras, R. (1999). “Arsenic removal from water supplies in northern Chile using ferric chloride coagulation.” CIWEM’s Water Environ. J., 13(3), 164–169.
Krishna, M. V. B., Chandrasekaran, K., Karunasagar, D., and Arunachalam, J. (2001). “A combined treatment approach using Fenton’s reagent and zero valent iron for the removal of arsenic from drinking water.” J. Hazard. Mater., 84(2–3), 229–240.
Kunito, T., Kubota, R., Fujihara, J., Agusa, T., and Tanabe, S. (2008). “Arsenic in marine mammals, seabirds, and sea turtles.” Rev. Environ. Contam. Toxicol., 195, 31–69.
Lakshmanan, D., Clifford, D. A., and Samanta, G. (2010). “Comparative study of arsenic removal by iron using electrocoagulation and chemical coagulation.” Water Res., 44(19), 5641–5652.
Lang, J. S., Giron, J. J., Hansen, A. T., Trussell, R. R., and Hodges, W. E. (1993). “Investigating filter performance as a function of the ratio of filter size to media size.” J. Am. Water Works Assoc., 85(10), 122–130.
Mehta, V. S., and Chaudhari, S. K. (2015). “Arsenic removal from simulated groundwater using household filter columns containing iron filings and sand.” J. Water Process Eng., 6, 151–157.
Mertens, J., Casentini, B., Masion, A., Pöthig, R., Wehrli, B., and Furrer, G. (2012). “Polyaluminum chloride with high Al30 content as removal agent for arsenic-contaminated well water.” Water Res., 46(1), 53–62.
Mohan, D., and Pittman, C. U. (2007). “Arsenic removal from water/wastewater using adsorbents: A critical review.” J. Hazard. Mater., 142(1–2), 1–53.
Mondal, P., Bhowmick, S., Chatterjee, D., Figoli, A., and Van der Bruggen, B. (2013). “Remediation of inorganic arsenic in groundwater for safe water supply: A critical assessment of technological solutions.” Chemosphere, 92(2), 157–170.
Nicolli, H. B., García, J. W., Falcón, C. M., and Smedley, P. L. (2012). “Mobilization of arsenic and other trace elements of health concern in groundwater from the Salí River Basin, Tucumán Province, Argentina.” Environ. Geochem. Health, 34(2), 251–262.
Nitzsche, K. S., et al. (2015). “Arsenic removal from drinking water by a household sand filter in Vietnam: Effect of filter usage practices on arsenic removal efficiency and microbiological water quality.” Sci. Total Environ., 502, 526–536.
Rott, U., and Kauffmann, H. (2008). “A contribution to solve the arsenic problem in groundwater of Ganges Delta by in-situ treatment.” Water Sci. Technol., 58(10), 2009–2015.
Shrestha, R. R., et al. (2003). “Groundwater arsenic contamination, its health impact and mitigation program in Nepal.” J. Environ. sci. Health., 38(1), 185–200.
Smedley, P. L., and Kinniburgh, D. G. (2002). “A review of the source, behaviour and distribution of arsenic in natural waters.” Appl. Geochem., 17(5), 517–568.
Tobias, R., and Berg, M. (2011). “Sustainable use of arsenic-removing sand filters in Vietnam: Psychological and social factors.” Environ. Sci. Technol., 45(8), 3260–3267.
USEPA (United States Environmental Protection Agency). (2001). “Arsenic and clarification to compliance and new source monitoring rule: A quick reference guide.” ⟨https://nepis.epa.gov/Exe/ZyPDF.cgi?Dockey=300065YM.txt⟩ (Jan. 22, 2001).
Van Halem, D., et al. (2010). “Subsurface iron and arsenic removal: Low-cost technology for community-based water supply in Bangladesh.” Water Sci. Technol., 62(11), 2702–2709.
Zhi, H. (2016). “Arsenic(V) removal from drinking water by concurrent introduction of As contaminated water and polyaluminum chloride in a sand filter medium.” M.S. thesis, School of Civil and Environmental Engineering, Cornell Univ., Ithaca, NY.
Information & Authors
Information
Published In
Copyright
©2017 American Society of Civil Engineers.
History
Received: Oct 12, 2016
Accepted: Feb 24, 2017
Published online: May 19, 2017
Published in print: Sep 1, 2017
Discussion open until: Oct 19, 2017
Authors
Metrics & Citations
Metrics
Citations
Download citation
If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.