Technical Papers
Sep 18, 2015

Comparison of Single and Two-Stage Ballasted Flocculation Processes for Enhanced Removal of Arsenic from Mine Water

Publication: Journal of Environmental Engineering
Volume 142, Issue 2

Abstract

Single-stage and two-stage treatment processes using ferric sulphate (Fe2(SO4)3) coagulation, lime precipitation, ballasted flocculation, and sedimentation were compared for the removal of high concentrations (i.e., 60mg/L) of arsenic in a synthetic mine water (SMW). Single-stage treatment was found to reduce arsenic to 0.39±0.04mg/L in As(V) SMW and 0.78±0.07mg/L in As(III) SMW using either preoxidation with KMnO4 or higher pH and coagulant dose compared to As(V) (i.e., 9.0 to 9.5 versus 5.5 to 6.0 and 151 versus 76mgFe/L), above a proposed national discharge guideline of 0.10mgAs/L. The two-stage treatment process was able to reduce total arsenic concentrations to 0.004±0.002mg/L for As(V) SMW using coagulation and ballasted flocculation alone in Stage 2, 0.010±0.008mg/L for As(III) with oxidation upstream of the second coagulation stage, and 0.037±0.006mg/L for As(III) with pH adjustment downstream of it. The two-stage process was shown to achieve optimum performance at colder operating temperatures (i.e., 3 versus 23°C).

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Acknowledgments

The authors would like to thank the National Sciences and Engineering Research Council of Canada (NSERC), Josée Lalonde of VWS, and Heather Daurie of Dalhousie University.

References

APHA, AWWA, and WEF (American Public Health Association, American Water Works Association, and Water Environment Federation). (2005). “Standard methods for the examination of water and wastewater.” Washington, DC.
Bednar, A. J., Garbarino, J. R., Ranville, J. F., and Wildeman, T. R. (2005). “Effects of iron on arsenic speciation and redox chemistry in acid mine water.” J. Geochem. Explor., 85(2), 55–62.
Bissen, M., and Frimmel, F. H. (2003). “Arsenic–A review. Part II: Oxidation of arsenic and its removal in water treatment.” Acta Hydroch. Hydrob., 31(2), 97–107.
Bowell, R. (2003). “The influence of speciation in the removal of arsenic from mine waters.” Land Contam. Reclam., 11(2), 231–238.
Braul, L., Viraraghavan, T., and Corkal, D. (2001). “Cold water effects on enhanced coagulation of high DOC, low turbidity water.” Water Qual. Res. J. Can., 36(4), 701–717.
CCME (Canadian Council of Ministers of the Environment). (2007). “Canadian water quality guidelines for the protection of aquatic life: Summary table.” Canadian environmental quality guidelines, Winnipeg, MB.
Clark, I. D., and Raven, K. G. (2004). “Sources and circulation of water and arsenic in the Giant Mine, Yellowknife, NWT, Canada.” Isot. Environ. Health Stud., 40(2), 115–128.
Desjardins, C., Koudjonou, B., and Desjardins, R. (2002). “Laboratory study of ballasted flocculation.” Water Res., 36(3), 744–754.
Droste, R. L. (1997). Theory and practice of water and wastewater treatment, Wiley, Hoboken, NJ.
Edwards, M. (1994). “Chemistry of arsenic removal during coagulation and Fe-Mn oxidation.” J. Am. Water Works Assn., 86(9), 64–78.
Environment Canada. (2012). “10-year review of metal mining effluent regulations.” 〈http://www.coal.ca/wp-content/uploads/2013/01/10year-review-MMR_Dec14.pdf〉 (Jul. 4, 2013).
Exall, K. N., and VanLoon, G. W. (2000). “Using coagulants to remove organic matter.” J. Am. Water Works Assn., 92(11), 93–102.
Fan, M., Brown, R. C., Sung, S. W., Huang, C.-P., Ong, S. K., and van Leeuwen, J. H. (2003). “Comparisons of polymeric and conventional coagulants in Arsenic(V) removal.” Water Environ. Res., 75(4), 308–313.
Faust, S. D., and Aly, O. M. (1998). Chemistry of water treatment, 2nd. Ed., Lewis Publishers, Boca Raton, FL.
Fisheries Act. (2002). “Metal mining effluent regulations.” 〈http://laws-lois.justice.gc.ca/eng/regulations/SOR-2002-222/〉 (Nov. 26, 2012).
Fitzpatrick, C. S. B., Fradin, E., and Gregory, J. (2004). “Temperature effects on flocculation, using different coagulants.” Water Sci. Technol., 50(12), 171–175.
Ghanem, A. V., Young, J. C., and Edwards, F. G. (2007). “Mechanisms of ballasted floc formation.” J. Environ. Eng., 271–277.
Goldberg, S., and Johnston, C. T. (2001). “Mechanisms of arsenic adsorption on amorphous oxides evaluated using macroscopic measurements, vibrational spectroscopy, and surface complexation modeling.” J. Colloid Interface Sci., 234(1), 204–216.
Guan, X., Ma, J., Dong, H., and Jiang, L. (2009). “Removal of arsenic from water: Effect of calcium ions on As(III) removal in the KMnO4-Fe(II) process.” Water Res., 43(20), 5119–5128.
Harper, T. R., and Kingham, N. W. (1992). “Removal of arsenic from wastewater using chemical precipitation methods.” Water Environ. Res., 64(3), 200–203.
Harris, B. (2003). “The removal of arsenic from process solutions: Theory and industrial practice.” Hydrometallurgy 2003–5th Annual Conf. in Honor of Professor Ian M. Ritchie, Vol. 2, C. A. Young, A. M. Alfantazi, C. G. Anderson, D. B. Dreisinger, B. Harris, and A. James, eds., TMS, Warrendale, PA, 1889–1902.
Health Canada. (2012). “Guidelines for Canadian drinking water quality—Summary table.” WaterAir and Climate Change Bureau, Healthy Environments and Consumer Safety Branch, Health Canada, Ottawa, ON.
Hering, J. G., Chen, P.-Y., Wilkie, J. A., and Elimelech, M. (1997). “Arsenic removal from drinking water during coagulation.” J. Environ. Eng., 800–807.
Hering, J. G., Chen, P.-Y., Wilkie, J. A., Elimelech, M., and Liang, S. (1996). “Arsenic removal by ferric chloride.” J. Am. Water Works Assn., 88(4), 155–167.
Hingston, F. J., Posner, A. M., and Quirk, J. P. (1972). “Anion adsorption by goethite and gibbsite.” J. Soil Sci., 23(2), 177–192.
Jain, A., Raven, K. P., and Loeppert, R. H. (1999). “Arsenite and arsenate adsorption on ferrihydrite: Surface charge reduction and net OH- release stoichiometry.” Environ. Sci. Technol., 33(8), 1179–1184.
Jia, Y., and Demopoulos, G. P. (2005). “Adsorption of arsenate onto ferrihydrite from aqueous solution: Influence of media (sulphate vs nitrate), added gypsum, and pH alteration.” Environ. Sci. Technol., 39(24), 9523–9527.
Jia, Y., and Demopoulos, G. P. (2008). “Coprecipitation of arsenate with iron(III) in aqueous sulphate media: Effect of time, lime as base and co-ions on arsenic retention.” Water Res., 42(3), 661–668.
Jia, Y., Zhang, D., Pan, R., Xu, L., and Demopoulos, G. P. (2012). “A novel two-step coprecipitation process using Fe(III) and Al(III) for the removal and immobilization of arsenate from acidic aqueous solution.” Water Res., 46(2), 500–508.
Kang, L.-S., and Cleasby, J. L. (1995). “Temperature effects on flocculation kinetics using Fe(III) coagulant.” J. Environ. Eng., 893–901.
MacBerthouex, P., and Brown, L. C. (2002). Statistics for environmental engineers, 2nd Ed., Lewis, Boca Raton, FL, 215–221.
McNeill, L., and Edwards, M. (1997). “Arsenic removal during precipitative softening.” J. Environ. Eng., 453–460.
Meng, X., Bang, S., and Korfiatis, G. P. (2000). “Effects of silicate, sulphate, and carbonate on arsenic removal by ferric chloride.” Water Res., 34(4), 1255–1261.
Mercer, K. L., and Tobiason, J. E. (2008). “Removal of arsenic from high ionic strength solutions: Effects of ionic strength, pH, and preformed versus in situ formed HFO.” Environ. Sci. Technol., 42(10), 3797–3802.
Morris, J. K., and Knocke, W. R. (1984). “Temperature effects on the use of metal-ion coagulants for water treatment.” J. Am. Water Works Assn., 76(3), 74–79.
Nishimura, T., and Umetsu, Y. (2000). “Chemistry on elimination of arsenic, antimony, and selenium from aqueous solution with Iron(III) species.” Minor elements, C. Young, ed., SME, Littleton, CO, 150–112.
Ore Mining and Dressing Point Source Category. (2011). “Code of federal regulations, Title 40, Part 440.” Washington, DC.
Pakzadeh, B., and Batista, J. R. (2011). “Surface complexation modeling of the removal of arsenic from ion-exchange waste brines with ferric chloride.” J. Hazard. Mater., 188(1–3), 399–407.
Parks, J. L., Novak, J., MacPhee, M., Itle, C., and Edwards, M. (2003). “Effect of Ca on As release from ferric and alum residuals.” J. Am. Water Works Assn., 95(6), 108–118.
Pierce, M. L., and Moore, C. B. (1980). “Adsorption of arsenite on amorphous iron hydroxide from dilute aqueous suspension.” Environ. Sci. Technol., 14(2), 214–216.
Qiao, J., Jiang, Z., Sun, B., Sun, Y., Wang, Q., and Guan, X. (2012). “Arsenate and arsenite removal by FeCl3: Effects of pH, As/Fe ratio, initial as concentration and co-existing solutes.” Sep. Purif. Technol., 92, 106–114.
Raven, K. P., Jain, A., and Loeppert, R. H. (1998). “Arsenite and arsenate adsorption on ferrihydrite: Kinetics, equilibrium, and adsorption envelopes.” Environ. Sci. Technol., 32(3), 344–349.
Riveros, P. A., Dutrizak, J. E., and Spencer, P. (2001). “Arsenic disposal practices in the metallurgical industry.” Can. Metall. Q., 40(4), 395–420.
Sharma, V. K., and Sohn, M. (2009). “Aquatic arsenic: Toxicity, speciation, transformations, and remediation.” Environ. Int., 35(4), 743–759.
Sigg, L., and Stumm, W. (1981). “The interaction of anions and weak acids with the hydrous goethite (α-FeOOH) surface.” Colloids Surf., 2(2), 101–117.
Smith, S. D., and Edwards, M. (2002). “Bench-scale evaluation of innovative arsenic-removal processes.” J. Am. Water Works Assn., 94(9), 78–87.
Sorlini, S., and Gialdini, F. (2010). “Conventional oxidation treatments for the removal of arsenic with chlorine dioxide, hypochlorite, potassium permanganate and monochloramine.” Water Res., 44(19), 5653–5659.
Twidwell, L. G., and McCloskey, J. W. (2011). “Removing arsenic from aqueous solution and long-term product storage.” JOM, 63(8), 94–100.
U.S. EPA. (1990). “Final best demonstrated available technology (BDAT) background document for K031, K084, K101, K102, characteristic arsenic wastes (D004), characteristic selenium wastes (D010), and P and U wastes containing arsenic and selenium listing constituents.” Office of Solid Waste, Washington, DC.
U.S. EPA. (2012). “Arsenic in drinking water.” 〈http://water.epa.gov/lawsregs/rulesregs/sdwa/arsenic/index.cfm〉 (Sep. 26, 2012).
Wang, H.-J., Gong, W.-X., Liu, R.-P., Liu, H.-J., and Qu, J.-H. (2011). “Treatment of high arsenic content wastewater by a combined physical-chemical process.” Colloids Surf., A, 379(1), 116–120.
Wang, J. W., Bejan, D., and Bunce, N. J. (2003). “Removal of arsenic from synthetic acid mine drainage by electrochemical pH adjustment and coprecipitation with iron hydroxide.” Environ. Sci. Technol., 37(19), 4500–4506.
Wang, Q., Nishimura, T., and Umetsu, Y. (2000). “Oxidative precipitation for arsenic removal in effluent treatment.” Minor elements, C. Young, ed., SME, Littleton, CO, 39–52.
Wang, S., and Mulligan, C. N. (2006). “Occurrence of arsenic contamination in Canada: Sources, behaviour and distribution.” Sci. Total Environ., 366(2–3), 701–721.
WHO (World Health Organization). (2011). Guidelines for drinking-water quality, 4th Ed., Geneva, Switzerland.
Williams, M. (2001). “Arsenic in mine waters: An international study.” Environ. Geol., 40(3), 267–278.
Young, J. C., and Edwards, F. G. (2003). “Factors affecting ballasted flocculation reactions.” Water Environ. Res., 75(3), 263–272.

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Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 142Issue 2February 2016

History

Received: Aug 12, 2014
Accepted: Aug 5, 2015
Published online: Sep 18, 2015
Published in print: Feb 1, 2016
Discussion open until: Feb 18, 2016

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Authors

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A. L. Mackie [email protected]
Ph.D. Candidate, Dept. of Civil and Resource Engineering, Dalhousie Univ., P.O. Box 15000, Halifax, NS, Canada B3H 4R2. E-mail: [email protected]
M. Laliberté [email protected]
Senior Industrial Process Engineer, Veolia Water Technologies Canada, 4105 rue Sartelon, Saint–Laurent, QC, Canada H4S 2B3. E-mail: [email protected]
M. E. Walsh, Ph.D. [email protected]
P.Eng.
Associate Professor, Dept. of Civil and Resource Engineering, Dalhousie Univ., P.O. Box 15000, Halifax, NS, Canada B3H 4R2 (corresponding author). E-mail: [email protected]

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