Enhanced Electrokinetic Remediation of Copper-Contaminated Soils near a Mine Tailing Using the Approaching-Anode Technique
Publication: Journal of Environmental Engineering
Volume 142, Issue 2
Abstract
The soils contaminated by copper (Cu) near a mine tailing are remedied via an enhanced electrokinetical (EK) method utilizing approaching anodes (AAs). The variations in the removal efficiency and soil pH as a function of treatment time are determined. The maximum Cu removal efficiency is as high as 61.98% under a voltage gradient of for 48 h; in contrast to 38.97% when the conventional electrokinetic remediation with one fixed anode (FA) is employed. Several anodes were inserted as AAs in the treated soil. They were switched in turn from the anode towards the cathode allowing for high ions concentrations and high redox potentials to quickly migrate towards the cathode. As a result, the soil remediation is accelerated. The mechanism of Cu electromigration behavior in soils during an enhanced EK method is described as the elution in an electrokinetically-driven chromatogram.
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Acknowledgments
This work was financially supported jointly as a project of National Natural Science Foundation of China (No. 21003054) and a scientific research project of Department of Education of Guangdong Province (Grant No. 2013CXZDA013).
References
Amrate, S., Akretche, D. E., Innocent, C., and Seta, P. (2006). “Use of cation-exchange membranes for simultaneous recovery of lead and EDTA during electrokinetic extraction.” Desalination, 193(1–3), 405–410.
Cao, X. D., Chen, Y., Wang, X. R., and Deng, X. H. (2001). “Effects of redox potential and pH value on the release of rare earth elements from soil.” Chemosphere, 44(4), 655–661.
Franco, P. E., et al. (2013). “Nickel(II) and zinc(II) removal using Amberlite IR-120 resin: Ion exchange equilibrium and kinetics.” Chem. Eng. J., 221, 426–435.
Guemiza, K., Mercier, G., and Blais, J. (2015). “Pilot-scale decontamination of small-arms shooting range soil polluted with copper, lead, antimony, and zinc by acid and saline leaching.” J. Environ. Eng., 04014054.
Gunvor, M. K., Lisbeth, M. O., and Arne, V. (2009). “Electrodialytic remediation of harbour sediment in suspension-evaluation of effects induced by changes in stirring velocity and current density on heavy metal removal and pH.” J. Hazard. Mater., 169(1–3), 685–690.
Hansen, H. K., Rojo, A., and Ottosen, L. M. (2007). “Electrokinetic remediation of copper mine tailings: Implementing bipolar electrodes.” Electrochim. Acta, 52(10), 3355–3359.
Huang, J. Y., Liao, W. P., Lai, S. M., and Yang, R. (2013). “Use of hydraulic pressure—Improved electrokinetic technique to enhance the efficiencies of the remediation of PCP-contaminated soil.” J. Environ. Eng., 1213–1221.
Li, D., Xiong, Z., Nie, Y., Niu, Y. Y., Wang, L., and Liu, Y. Y. (2012a). “Near-anode focusing phenomenon caused by the high anolyte concentration in the electrokinetic remediation of chromium(VI)—Contaminated soil.” J. Hazard. Mater., 229, 282–291.
Li, G., Guo, S. H., Li, S. C., Zhang, L. Y., and Wang, S. S. (2012b). “Comparison of approaching and fixed anodes for avoiding the ‘focusing’effect during electrokinetic remediation of chromium-contaminated soil.” Chem. Eng. J., 203, 231–238.
Li, Z. Y., Ma, Z. W., Kuijp, T. J., Yuan, Z. W., and Huang, L. (2014). “A review of soil heavy metal pollution from mines in China: Pollution and health risk assessment.” Sci. Tot. Environ., 468–469, 843–853.
Liu, Q., Sun, X., Hu, A., Yanan Zhang, Y. N., and Cao, Z. H. (2014). “Characteristics of toxic metal accumulation in farmland in relation to long-term chicken manure application: A case study in the Yangtze River delta region, China.” Bull. Environ. Contam. Toxicol., 92(3), 279–284.
Lu, P., Feng, Q. Y., Meng, Q. J., and Yuan, T. (2012). “Electrokinetic remediation of chromium and cadmium-contaminated soil from abandoned industrial site.” Sep. Purif. Technol., 98, 216–220.
Méndez, E. (2012). “Effects of electrode material on the efficiency of hydrocarbon removal by an electrokinetic remediation process.” Electrochim. Acta, 86, 148–156.
Ottosen, L. M., Pedersen, A. J., Ribeiro, A. B., and Hansen, H. K. (2005). “Case study on the strategy and application of enhancement solutions to improve remediation of soils contaminated with Cu, Pb and Zn by means of electrodialysis.” Eng. Geol., 77(3–4), 317–329.
Özkök, E., Davis, A. P., and Aydilek, A. H. (2013). “Leaching of As, Cr, and Cu from high-carbon fly ash–soil mixtures.” J. Environ. Eng., 11, 1397–1408.
Page, M. M., and Page, C. L. (2002). “Electroremediation of contaminated soils.” J. Environ. Eng., 208–219.
Probstein, R. F., and Hicks, R. E. (1993). “Removal of contaminants from soils by electric fields.” Science, 260(5107), 498–503.
Rajić, L., Božo, D., Dalmacija, M., Rončević, S., and Perović, S. U. (2012). “Enhancing electrokinetic lead removal from sediment: Utilizing the moving anode technique and increasing the cathode compartment length.” Electrochim. Acta, 86(30), 36–40.
Rojo, A., and Cubillos, L. (2009). “Electrodialytic remediation of copper mine tailings using bipolar electrodes.” J. Hazard. Mater., 168(2–3), 1177–1183.
Shen, Z. M., Chen, X. J., Jia, J. P., Qu, L. Y., and Wang, W. H. (2007) “Comparison of electrokinetic soil remediation methods using one fixed anode and approaching anodes.” Environ. Pollut., 150, 193–199.
Shrestha, R., Fischer, R., and Rahner, D. (2003). “Behavior of cadmium, lead and zinc at the sediment-water interface by electrochemically initiated processes.” Colloid. Surf. A, 222(1–3), 261–271.
Sun, T. R., and Ottosen, L. M. (2012). “Effects of pulse current on energy consumption and removal of heavy metals during electrodialytic soil remediation.” Electrochim. Acta, 86, 28–35.
Xu, W. S., and Regnier, F. E. (1999). “Electrokinetically-driven cation-exchange chromategraphy of proteins and its comparison with pressure-driven high-performance liquid chromatography.” J. Chromatogr. A, 853(1–2), 243–256.
Zhang, X. H., Zhang, G. L., and Yang, J. L. (2014). “Dynamic change of point of zero charge along atypical soil chronosequence in tropical Hainan Island and its implications for pedogenesis.” Soils, 46(2), 347–351.
Zhou, D. M., Deng, C. F., Cang, L., and Alshawabkeh, A. N. (2005). “Electrokinetic remediation of a Cu-Zn contaminated red soil by controlling the voltage and conditioning catholyte pH.” Chemosphere, 61(4), 519–527.
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© 2015 American Society of Civil Engineers.
History
Received: Dec 21, 2014
Accepted: Jul 8, 2015
Published online: Oct 20, 2015
Published in print: Feb 1, 2016
Discussion open until: Mar 20, 2016
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