Technical Papers
Jan 22, 2015

Polyvinylchloride Ultrafiltration Membranes Modified with Different SiO2 Particles and Their Antifouling Mechanism for Oil Extraction Wastewater

Publication: Journal of Environmental Engineering
Volume 141, Issue 8

Abstract

Novel low-cost and antifouling polyvinylchloride (PVC)–based membranes were fabricated with regular and hydrophilic nano-SiO2 particles as additives. The modified membranes exhibited significant improvements in mechanical properties, surface hydrophilicities, and antifouling performances in filtration of oil extraction wastewater. The addition of two types of nano-SiO2 particles increased the quantities of hydrophilic functional groups on the surface of the PVC membranes, which enhanced the resistance to adsorption of oily hydrophobic contaminants. Compared with the unmodified membrane, the membranes modified by regular and hydrophilic nano-SiO2 (at optimal addition of 1.5 g) presented more steady initial fluxes and higher flux recovery ratios in every filtration cycle. Meanwhile, both modified membranes exhibited high removal efficiencies of suspended solids (more than 98%) and oil components (up to 95%). These findings indicate that PVC membranes modified with two types of nano-SiO2 particles have great potential for applications in the reuse of oil extraction wastewater.

Get full access to this article

View all available purchase options and get full access to this article.

Acknowledgments

This work was supported by the National Natural Science Foundation of China (51108112), the Natural Science Foundation of Heilongjiang Province (E201252), Fundamental Research Funding of Harbin Engineering University (HEUFT06029), and Open Project of State Key Laboratory of Urban Water Resource and Environment, Harbin Institute of Technology (ESK201004).

References

Afonso, M. D., and Bórquez, R. (2002). “Review of the treatment of seafood processing wastewaters and recovery of proteins therein by membrane separation processes—Prospects of the ultrafiltration of wastewaters from the fish meal industry.” Desalination, 142(1), 29–45.
Ahmad, A. L., Majid, M. A., and Ooi, B. S. (2011). “Functionalized PSf/SiO2 nanocomposite membrane for oil-in-water emulsion separation.” Desalination, 268(1–3), 266–269.
Basri, H., Ismail, A. F., and Aziz, M. (2011). “Polyethersulfone (PES)–silver composite UF membrane: Effect of silver loading and PVP molecular weight on membrane morphology and antibacterial activity.” Desalination, 273(1), 72–80.
Benito, J. M., Sánchez, M. J., Pena, P., and Rodríguez, M. A. (2007). “Development of a new high porosity ceramic membrane for the treatment of bilge water.” Desalination, 214(1–3), 91–101.
Boussu, K., Van der Bruggen, B., Volodin, A., Snauwaert, J., Van Haesendonck, C., and Vandecasteele, C. (2005). “Roughness and hydrophobicity studies of nanofiltration membranes using different modes of AFM.” J. Colloid Interface Sci., 286(2), 632–638.
Chang, I., Le Clech, P., Jefferson, B., and Judd, S. (2002). “Membrane fouling in membrane bioreactors for wastewater treatment.” J. Environ. Eng., 1018–1029.
Chen, W., Peng, J., Su, Y., Zheng, L., Wang, L., and Jiang, Z. (2009a). “Separation of oil/water emulsion using Pluronic F127 modified polyethersulfone ultrafiltration membranes.” Sep. Purif. Technol., 66(3), 591–597.
Chen, W., Su, Y., Zheng, L., Wang, L., and Jiang, Z. (2009b). “The improved oil/water separation performance of cellulose acetate-graft-polyacrylonitrile membranes.” J. Membr. Sci., 337(1–2), 98–105.
Chen, X., Su, Y., Shen, F., and Wan, Y. (2011). “Antifouling ultrafiltration membranes made from PAN-b-PEG copolymers: Effect of copolymer composition and PEG chain length.” J. Membr. Sci., 384(1–2), 44–51.
Dong, B.-Z., Chen, Y., Gao, N.-Y., and Fan, J.-C. (2007). “Effect of coagulation pretreatment on the fouling of ultrafiltration membrane.” J. Environ. Sci., 19(3), 278–283.
Gu, Q., and Jia, Z. (2013). “Preparation of quaternized poly(vinylidene fluoride) membranes by γ-ray irradiation induced graft polymerization and their antibacterial property.” React. Funct. Polym., 73(8), 1114–1121.
Han, B., Zhang, D., Shao, Z., Kong, L., and Lv, S. (2013). “Preparation and characterization of cellulose acetate/carboxymethyl cellulose acetate blend ultrafiltration membranes.” Desalination, 311, 80–89.
Hong, A., Fane, A. G., and Burford, R. (2003). “Factors affecting membrane coalescence of stable oil-in-water emulsions.” J. Membr. Sci., 222(1–2), 19–39.
Howe, K. J., and Clark, M. M. (2002). “Fouling of microfiltration and ultrafiltration membranes by natural waters.” Environ. Sci. Technol., 36(16), 3571–3576.
Hua, H., et al. (2008). “Anti-fouling ultrafiltration membrane prepared from polysulfone-graft-methyl acrylate copolymers by UV-induced grafting method.” J. Environ. Sci., 20(5), 565–570.
Jin, L. M., et al. (2012). “Synthesis of a novel composite nanofiltration membrane incorporated SiO2 nanoparticles for oily wastewater desalination.” Polymer, 53(23), 5295–5303.
Lee, H. S., Im, S. J., Kim, J. H., Kim, H. J., Kim, J. P., and Min, B. R. (2008). “Polyamide thin-film nanofiltration membranes containing TiO2 nanoparticles.” Desalination, 219(1–3), 48–56.
Lee, S.-H., Chung, K.-C., Shin, M.-C., Dong, J.-I., Lee, H.-S., and Auh, K. H. (2002). “Preparation of ceramic membrane and application to the crossflow microfiltration of soluble waste oil.” Mater. Lett., 52(4–5), 266–271.
Li, J.-F., Xu, Z.-L., Yang, H., Yu, L.-Y., and Liu, M. (2009). “Effect of TiO2 nanoparticles on the surface morphology and performance of microporous PES membrane.” Appl. Surf. Sci., 255(9), 4725–4732.
Liang, S., Xiao, K., Mo, Y., and Huang, X. (2012). “A novel ZnO nanoparticle blended polyvinylidene fluoride membrane for anti-irreversible fouling.” J. Membr. Sci., 394–395, 184–192.
Liao, C., Zhao, J., Yu, P., Tong, H., and Luo, Y. (2012). “Synthesis and characterization of low content of different SiO2 materials composite poly (vinylidene fluoride) ultrafiltration membranes.” Desalination, 285, 117–122.
Liu, B., Chen, C., Zhang, W., Crittenden, J., and Chen, Y. (2012). “Low-cost antifouling PVC ultrafiltration membrane fabrication with Pluronic F 127: Effect of additives on properties and performance.” Desalination, 307, 26–33.
Majeed, S., et al. (2012). “Multi-walled carbon nanotubes (MWCNTs) mixed polyacrylonitrile (PAN) ultrafiltration membranes.” J. Membr. Sci., 403–404, 101–109.
Maximous, N., Nakhla, G., Wan, W., and Wong, K. (2010). “Performance of a novel ZrO2/PES membrane for wastewater filtration.” J. Membr. Sci., 352(1–2), 222–230.
Mei, S., Xiao, C., Hu, X., and Shu, W. (2011). “Hydrolysis modification of PVC/PAN/SiO2 composite hollow fiber membrane.” Desalination, 280(1–3), 378–383.
Mosqueda-Jimenez, D., Narbaitz, R., and Matsuura, T. (2004). “Impact of membrane surface modification on the treatment of surface water.” J. Environ. Eng., 1450–1459.
Nano Measurer 1.2 [Computer software]. China, Fudan Univ.
Nanoscope version 5.30 [Computer software]. Germany, Bruker.
Ogoshi, T., and Chujo, Y. (2005). “Synthesis of poly(vinylidene fluoride) (PVdF)/silica hybrids having interpenetrating polymer network structure by using crystallization between PVdF chains.” J. Polym. Sci., Part A: Polym. Chem., 43(16), 3543–3550.
Ouyang, K., and Liu, J. (2009). “Effect of sludge retention time on sludge characteristics and membrane fouling of membrane bioreactor.” J. Environ. Sci., 21(10), 1329–1335.
Rana, D., and Matsuura, T. (2010). “Surface modifications for antifouling membranes.” Chem. Rev., 110(4), 2448–2471.
Reed, B., Lin, W., Viadero, R., Jr., and Young, J. (1997). “Treatment of oily wastes using high-shear rotary ultrafiltration.” J. Environ. Eng., 1234–1242.
Shen, J.-N., Ruan, H.-M., Wu, L.-G., and Gao, C.-J. (2011). “Preparation and characterization of PES–SiO2 organic–inorganic composite ultrafiltration membrane for raw water pretreatment.” Chem. Eng. J., 168(3), 1272–1278.
Shen, L., et al. (2012). “Preparation and characterization of ZnO/polyethersulfone (PES) hybrid membranes.” Desalination, 293, 21–29.
Su, Y., Huang, C., Pan, J., Hsieh, W., and Chu, M. (2011). “Fouling mitigation by TiO2 composite membrane in membrane bioreactors.” J. Environ. Eng., 344–350.
Vatanpour, V., Madaeni, S. S., Khataee, A. R., Salehi, E., Zinadini, S., and Monfared, H. A. (2012). “TiO2 embedded mixed matrix PES nanocomposite membranes: Influence of different sizes and types of nanoparticles on antifouling and performance.” Desalination, 292, 19–29.
Venault, A., et al. (2014). “Low-biofouling membranes prepared by liquid-induced phase separation of the PVDF/polystyrene-b-poly (ethylene glycol) methacrylate blend.” J. Membr. Sci., 450, 340–350.
Wolf, P. H., Siverns, S., and Monti, S. (2005). “UF membranes for RO desalination pretreatment.” Desalination, 182(1–3), 293–300.
Wu, C., Xu, T., and Yang, W. (2003). “A new inorganic–organic negatively charged membrane: Membrane preparation and characterizations.” J. Membr. Sci., 224(1–2), 117–125.
Xu, J., and Xu, Z.-L. (2002). “Poly(vinyl chloride) (PVC) hollow fiber ultrafiltration membranes prepared from PVC/additives/solvent.” J. Membr. Sci., 208(1–2), 203–212.
Yan, L., Li, Y. S., Xiang, C. B., and Xianda, S. (2006). “Effect of nano-sized Al2O3-particle addition on PVDF ultrafiltration membrane performance.” J. Membr. Sci., 276(1–2), 162–167.
Yu, L.-Y., Xu, Z.-L., Shen, H.-M., and Yang, H. (2009). “Preparation and characterization of PVDF–SiO2 composite hollow fiber UF membrane by sol–gel method.” J. Membr. Sci., 337(1–2), 257–265.
Zhang, X., Chen, Y., Konsowa, A. H., Zhu, X., and Crittenden, J. C. (2009). “Evaluation of an innovative polyvinyl chloride (PVC) ultrafiltration membrane for wastewater treatment.” Sep. Purif. Technol., 70(1), 71–78.
Zhang, Y., Tian, J., Liang, H., Nan, J., Chen, Z., and Li, G. (2011). “Chemical cleaning of fouled PVC membrane during ultrafiltration of algal-rich water.” J. Environ. Sci., 23(4), 529–536.

Information & Authors

Information

Published In

Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 141Issue 8August 2015

History

Received: Jun 6, 2014
Accepted: Dec 12, 2014
Published online: Jan 22, 2015
Discussion open until: Jun 22, 2015
Published in print: Aug 1, 2015

Permissions

Request permissions for this article.

Authors

Affiliations

Fang-Bo Zhao [email protected]
Associate Professor, School of Material Science and Chemical Engineering, Harbin Engineering Univ., No. 145, Nantong St., Harbin City, Heilongjiang Province 150001, China (corresponding author). E-mail: [email protected]
Zhen-Jiang Yu
Master, School of Material Science and Chemical Engineering, Harbin Engineering Univ., No. 145, Nantong St., Harbin City, Heilongjiang Province 150001, China.
Hee-Deung Park
Associate Professor, School of Civil, Environmental and Architectural Engineering, Korea Univ., Anam-dong, Seongbuk-gu, Seoul 136-701, Republic of Korea.
Xu-Yang Liu
Research Scientist, Shale Water Research Center LLC, 8285 El Rio St., Houston, TX 77054.
Xiang-Ru Song
Master, School of Material Science and Chemical Engineering, Harbin Engineering Univ., No. 145, Nantong St., Harbin City, Heilongjiang Province 150001, China.
Zhan-Shuang Li
Professor, School of Material Science and Chemical Engineering, Harbin Engineering Univ., No. 145, Nantong St., Harbin City, Heilongjiang Province 150001, China.

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

Cited by

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share