Technical Notes
Nov 13, 2014

Sulfide Production Control in UASB Reactor by Addition of Iron Salt

Publication: Journal of Environmental Engineering
Volume 141, Issue 6

Abstract

Hydrogen sulfide (H2S) is one of the main odorant gases emitted from anaerobic sludge blanket (UASB) sewage treatment plants (STPs) and other anaerobic environments. The present work is an attempt to quantify H2S formation in seven full-scale UASB reactors across India and suppression of sulfide formation using pilot-scale UASB reactors and adopting a liquid-phase odor and corrosion control method that enhances sulfate (SO42) concentration in raw sewage up to 100120mg/L. Results for full-scale UASBs reveal that H2S varies 0–20.3 ppm because of high influent sulfates that range 100150mg/L as the result of ingress of industrial wastewater in domestic sewage. However, results for the pilot-scale UASBs reveal that SO42 in the influent (3840mg/L) converted to sulfide (1520mg/L) at ORP and pH to the safe range (ORP=75mV; pH=6.97.3). After sulfate enhancement, sulfide was observed to be 3040mg/L; COD removal, 80–85%; and ORP ranging from 65 to 103mV. Furthermore, iron salt (FeCl3), which was added at 30mg/L (a 11 ratio to sulfide concentration) minimized sulfide in the reactor up to 99%.

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References

American Public Health Association (APHA), American Water Works Association (AWWA), and Water Environmental Federation (WEF). (2005) “Standards methods for the examination of water and wastewater.” 20th Ed., Washington, DC.
De Lomas, J. G., Corzo, A., Gonzalez, J. M., Andrades, J. A., Iglesias, E., and Montero, M. J (2005). “Nitrate promotes biological oxidation of sulfide in wastewaters: experiment at plant-scale.” Biotechnol. Bioeng., 93(4), 801–811.
Isa, Z., Grusenmeyer, S., and Verstraete, W. (1986a). “Sulfate reduction relative to methane production in high-rate anaerobic digestion: Microbiological aspects.” Appl. Environ. Microbiol., 51(3), 580–587.
Isa, Z., Grusenmeyer, S., and Verstraete, W. (1986b). “Sulfate reduction relative to methane production in high-rate anaerobic digestion: Technical aspects.” Appl. Environ. Microbiol., 51(3), 572–579.
Jefferson, B., Hurst, A., Stuetz, R., and Parsons, S. A. (2002). “Comparison of chemical methods for the control of odors in wastewater process.” Environ. Prot., 80(2), 93–99.
Johnson, D. B., and Hallberg, K. B. (2005). “Acid mine drainage options: A review.” Sci. Total Environ., 338(1–2), 3–14.
Khalil, N., Sinha, R., Raghav, A. K., and Mittal, A. K. (2008). “UASB technology for sewage treatment in India: Experience, economic evaluation and its potential in other developing countries.” Twelfth Int. Water Technology Conf., IWTC12, Alexandria, Egypt.
Lens, P., Boncz, M., Sipma, J., Brunning, H., and Rulkens, W. (2001). “Catalytical oxidation of odourous compounds.” Wastewater treatment odor abatement, R. Stuetz, and F.-B. Frechen, eds., International Water Association, London.
Lens, P., Vallero, M., Esposito, G., and Zadvoort, M. (2002). “Perspectives of sulphate reducing bioreactors in environmental biotechnology.” Rev. Environ. Sci. Biotechnol., 1(4), 311–325.
Lens, P. N. L., Van Den Bosch, M. C., Hulshoff Pol, L. W., and Lettinga, G. (1998). “Effect of staging on volatile fatty acid degradation in sulfidogenic granular sludge reactor.” Water Res., 32, 1178–1192.
Lettinga, G., and Pol, L. H. (1986). “Advanced reactor design, operation and economy.” Water Sci. Technol., 18(12), 99–108.
Lettinga, G. A., van Velsen, F. M., Hobma, S. W., de Zeeuw, W. J., and Klapwijk, A. (1980). “Use of the upflow sludge blanket (USB) reactor concept for biological wastewater treatment.” Biotechnol. Bioeng., 22(4), 699–734.
Nemati, M., Mazutinec, T. J., Jenneman, G. E., and Voordouw, G. (2001). “Control of biogenic H S production with nitrate and molybdate.” J. Ind. Microbiol. Biotechnol., 26(6), 350–355.
Nielsen, A. H., Lens, P., Vollertsen, J., and Hvitved-Jacobsen, T. (2005). “Sulfide–iron interactions in domestic wastewater from a gravity sewer.” Water Res., 39(17), 4119–4125.
O’Flaherty, V., and Colleran, E. (2000). “Effects of sulphate addition on volatile fatty acid and ethanol degradation in an anaerobic hybrid reactor. I: Process disturbance and remediation.” Bioresour. Technol., 68(2), 101–107.
Postgate, J. R. (1984). The sulphate reducing bacteria, Cambridge University Press, Cambridge.
Vincke, E., Boon, N., and Verstraete, W. (2001). “Analysis of the microbial communities on corroded sewer pipes: Case study.” Appl. Microbiol. Biotechnol., 57(5–6), 776–785.
Wei, C.-H., Wang, W.-X., Deng, Z.-Y., and Wu, C.-F. (2007). “Characteristics of high-sulfate wastewater treatment by two-phase anaerobic digestion process with jet-loop anaerobic fluidized bed.” J. Environ. Sci., 19(3), 264–270.
Zhang, L., De Schryver, P., De Gusseme, B., De Muynck, W., Boon, N., and Verstraete, W. (2008). “Chemical and biological technologies for hydrogen sulfide emission control in sewer systems: A review.” Water Res., 42(1–2), 1–12.

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Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 141Issue 6June 2015

History

Received: Jul 18, 2013
Accepted: Sep 16, 2014
Published online: Nov 13, 2014
Discussion open until: Apr 13, 2015
Published in print: Jun 1, 2015

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Muntjeer Ali [email protected]
Research Associate, Dept. of Civil Engineering, IIT Roorkee, Roorkee 247667, India (corresponding author). E-mail: [email protected]
Nitin Kumar Singh [email protected]
Research Scholar, Dept. of Civil Engineering, IIT Roorkee, Roorkee 247667, India. E-mail: [email protected]
Akansha Bhatia [email protected]
Research Associate, Dept. of Civil Engineering, IIT Roorkee, Roorkee 247667, India. E-mail: [email protected]
Shriom Singh [email protected]
Senior Research Fellow, Dept. of Civil Engineering, IIT Roorkee, Roorkee 247667, India. E-mail: [email protected]
Anwar Khursheed [email protected]
Associate Professor, Dept. of Civil Engineering, Aligarh Muslim Univ., Aligarh 202002, India. E-mail: [email protected]
A. A. Kazmi [email protected]
Associate Professor, Dept. of Civil Engineering, IIT Roorkee, Roorkee 247667, India. E-mail: [email protected]

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