Technical Papers
Aug 4, 2014

Fast Removal of Methylene Blue from Aqueous Solution Using Magnetic-Modified Fe3O4 Nanoparticles

Publication: Journal of Environmental Engineering
Volume 141, Issue 1

Abstract

Tannic acid modified super paramagnetic Fe3O4 nanoparticles (Fe3O4-TAN) were synthesized by a simple strategy and were used as adsorbents for removal of methylene blue (MB) from water solution. The prepared magnetic nanoparticles (MNPs) were characterized by Fourier transform infrared (FT-IR), transmission electron microscopy (TEM), thermogravimetric (TGA), and X-ray diffraction (XRD) analyses. The effects of pH, contact time, dye concentration, and temperature on adsorption were determined. The experimental data were analyzed using the Langmuir adsorption model. The data fitted well to the model with maximum adsorption capacities 90.9mg/g under pH=10.5. Also, the adsorption kinetics and thermodynamic parameters were studied and evaluated. Adsorption of the MB to nanoparticles reached equilibrium after 25 min. In addition, the external magnetic field could easily separate nanoparticles from water with high separation efficiency. Desorption process of the adsorbed dyes was also investigated.

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Acknowledgments

The financial support of this work by the Iran National Science Foundation (INSF 91002199) is gratefully acknowledged.

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Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 141Issue 1January 2015

History

Received: Aug 23, 2013
Accepted: Jun 23, 2014
Published online: Aug 4, 2014
Published in print: Jan 1, 2015
Discussion open until: Jan 4, 2015

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Authors

Affiliations

Shiva Dehghan Abkenar [email protected]
Assistant Professor, Dept. of Chemistry, Islamic Azad Univ., Savadkooh Branch, 155 Mazandaran, Iran (corresponding author). E-mail: [email protected]
Mehdi Khoobi [email protected]
Assistant Professor, Dept. of Medicinal Chemistry, Faculty of Pharmacy and Pharmaceutical Sciences Research Center, Tehran Univ. of Medical Sciences, 14176 Tehran, Iran. E-mail: [email protected]
Roghayeh Tarasi [email protected]
Ph.D. Student, Chemistry Dept., Zanjan Univ., P.O. Box 45195-313, Zanjan, Iran. E-mail: [email protected]
Morteza Hosseini [email protected]
Assistant Professor, Dept. of Life Science Engineering, Faculty of New Sciences and Technologies, Univ. of Tehran, 14395-1561 Tehran, Iran. E-mail: [email protected]
Abbas Shafiee [email protected]
Professor, Dept. of Medicinal Chemistry, Faculty of Pharmacy and Pharmaceutical Sciences Research Center, Tehran Univ. of Medical Sciences, 14176 Tehran, Iran. E-mail: [email protected]
Mohammad R. Ganjali [email protected]
Professor, Center of Excellence in Electrochemistry, Faculty of Chemistry, Univ. of Tehran, 14155-6455 Tehran, Iran. E-mail: [email protected]

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