Technical Papers
Aug 4, 2012

Hybrid Treatment Process of using MIEX and High Performance Composite Coagulant for DOM and Bromide Removal

Publication: Journal of Environmental Engineering
Volume 139, Issue 1

Abstract

Dissolved organic matter (DOM) and bromide, two primary precursors of disinfection by-products, cannot be effectively removed by conventional coagulation processes. Alternative methods are required to ensure the safety of drinking water. The effectiveness of using magnetic ion exchange resin (MIEX) and high-performance coagulant (HPAC) in a hybrid process for the removal of turbidity, DOM, and bromide in raw water supplies was investigated. Results showed that a wide range of DOM, with different molecular weights (MWs) containing soluble microbial byproduct-like organic matters, aromatic protein, and fulvic/humic acid, was removed by MIEX in the two studied water sources. In addition, up to 91% of bromide was removed in bromide spiked raw waters. In comparison, HPAC coagulation did not effectively eliminate low MW or soluble microbial byproduct-like organic matters in raw water. The combined MIEX and HPAC process more significantly improved the performance of turbidity, DOM, and bromide removal than coagulation alone. With MIEX pretreatment, the requisite HPAC dosage was reduced by at least 67%.

Get full access to this article

View all available purchase options and get full access to this article.

Acknowledgments

This work was supported by the NSFC for Excellent Youth 51025830 of China and the National Natural Science Foundation of China (No. 50921064). The authors thank Orica Watercare for supplying the MIEX resins and appreciate Morran Jim for his help during preparation of the paper.

References

Allpike, B. P. et al. (2005). “Size exclusion chromatography to characterize DOC removal in drinking water treatment.” Environ. Sci. Technol., 39(7), 2334–2342.
American Public Health Association (APHA), American Water Works Association, Water Environment Federation. (1998). Standard methods for the examination of water and wastewater, 20th Ed., APHA, Washington, DC.
Bolto, B., Dixon, D., and Eldridge, R. (2004). “Ion exchange for the removal of natural organic matter.” React. Funct. Polym., 60(0), 171–182.
Boyer, T. H., Graf, K. C., Comstock, S. E. H., and Townsend, T. G. (2011). “Magnetic ion exchange treatment of stabilized landfill leachate.” Chemosphere, 83(9), 1220–1227.
Boyer, T. H., and Singer, P. C. (2006). “A pilot-scale evaluation of magnetic ion exchange treatment for removal of natural organic material and inorganic anions.” Water Res., 40(15), 2865–2876.
Boyer, T. H., Singer, P. C., and Aiken, G. R. (2008). “Removal of dissolved organic matter by anion exchange: Effect of dissolved organic matter properties.” Environ. Sci. Technol., 42(19), 7431–7437.
Chen, W., Westerhoff, P., Leenheer, J. A., and Booksh, K. (2003). “Fluorescence excitation-emission matrix regional integration to quantify spectra for dissolved organic matter.” Environ. Sci. Technol., 37(24), 5701–5710.
Drikas, M., Chow, C. W. K., and Cook, D. (2003). “The impact of recalcitrant organic character on disinfection stability, trihalomethane formation and bacterial regrowth: An evaluation of magnetic ion exchange resin (MIEX (R)) and alum coagulation.” J. Water Supply Res. Technol., 52(7), 475–487.
Drikas, M., Dixon, M., and Morran, J. (2011). “Long term case study of MIEX pre-treatment in drinking water; Understanding NOM removal.” Water Res., 45(4), 1539–1548.
Fearing, D. A. et al. (2004). “Combination of ferric and MIEX® for the treatment of a humic rich water.” Water Res., 38(10), 2551–2558.
Ge, F., Shu, H., and Dai, Y. (2007). “Removal of bromide by aluminium chloride coagulant in the presence of humic acid.” J. Hazard. Mater., 147(1–2), 457–462.
Hsu, S., and Singer, P. C. (2010). “Removal of bromide and natural organic matter by anion exchange.” Water Res., 44(7), 2133–2140.
Humbert, H., Gallard, H., Jacquemet, V., and Crou, J.-P. (2007). “Combination of coagulation and ion exchange for the reduction of UF fouling properties of a high DOC content surface water.” Water Res., 41(17), 3803–3811.
Humbert, H., Gallard, H., Suty, H., and Crou, J.-P. (2005). “Performance of selected anion exchange resins for the treatment of a high DOC content surface water.” Water Res., 39(9), 1699–1708.
Humbert, H., Gallard, H., Suty, H., and Crou, J.-P. (2008). “Natural organic matter (NOM) and pesticides removal using a combination of ion exchange resin and powdered activated carbon (PAC).” Water Res., 42(6–7), 1635–1643.
Jarvis, P., Mergen, M., Banks, J., McIntosh, B., Parsons, S. A., and Jefferson, B. (2008). “Pilot scale comparison of enhanced coagulation with magnetic resin plus coagulation systems.” Environ. Sci. Technol., 42(4), 1276–1282.
Lykins, B. W., Koffskey, W. E., and Patterson, K. S. (1994). “Alternative disinfectants for drinking water treatment.” J. Environ. Eng., 120(4), 745–758.
Matilainen, A., Vepsäläinen, M., and Sillanpää, M. (2010). “Natural organic matter removal by coagulation during drinking water treatment: A review.” Adv. Colloid Interface Sci., 159(2), 189–197.
Mergen, M. R. D., Jefferson, B., Parsons, S. A., and Jarvis, P. (2008). “Magnetic ion-exchange resin treatment: Impact of water type and resin use.” Water Res., 42(8–9), 1977–1988.
Neale, P., and Schafer, A. (2009). “Magnetic ion exchange: Is there potential for international development?” Desalination, 248(1–3), 160–168.
Rokicki, C. A., and Boyer, T. H. (2011). “Bicarbonate-form anion exchange: Affinity, regeneration, and stoichiometry.” Water Res., 45(3), 1329–1337.
Singer, P. C. (1994). “Control of disinfection by-products in drinking-water.” J. Environ. Eng., 120(4), 727–744.
Singer, P. C., and Bilyk, K. (2002). “Enhanced coagulation using a magnetic ion exchange resin.” Water Res., 36(16), 4009–4022.
United States Environmental Protection Agency (USEPA). (1993). Methods for the determination of inorganic anions in water by ion chromatography, Cincinnati.
Walker, K. M., and Boyer, T. H. (2011). “Long-term performance of bicarbonate-form anion exchange: Removal of dissolved organic matter and bromide from the St. Johns River, FL, USA.” Water Res., 45(9), 2875–2886.
Wang, D., Xu, Z., Zhao, Y., Yan, X., and Shi, J. (2011). “Change of genotoxicity for raw and finished water: Role of purification processes.” Chemosphere, 83(1), 14–20.
Wu, W. W., and Chadik, P. A. (1998). “Effect of bromide ion on haloacetic acid formation during chlorination of Biscayne Aquifer water.” J. Environ. Eng., 124(10), 932–938.

Information & Authors

Information

Published In

Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 139Issue 1January 2013
Pages: 79 - 85

History

Received: Dec 10, 2011
Accepted: Jul 13, 2012
Published online: Aug 4, 2012
Published in print: Jan 1, 2013

Permissions

Request permissions for this article.

Authors

Affiliations

Zhizhen Xu, Ph.D. [email protected]
State Key Laboratory of Environmental Aquatic Chemistry, Research Center for Eco-Environmental Science, Chinese Academy of Science, Beijing 100085, China; and School of Life Science and Bio-Engineering, Beijing Univ. of Technology, Beijing 100124, China. E-mail: [email protected]
Ruyuan Jiao
Master student, School of Environmental Sciences and Resources, Shanxi Univ., Taiyuan, 030006.
Hailong Liu
Assistant Professor, School of Environmental Sciences and Resources, Shanxi Univ., Taiyuan, 030006.
Dongsheng Wang [email protected]
Professor, State Key Lab of Environmental Aquatic Chemistry, Research Center for Eco-Environmental Science, Chinese Academy of Science, Beijing, 100085 (corresponding author). E-mail: [email protected]
Christopher W. K. Chow
Professor, AWQC, SA Water, 250 Victoria Sq., Adelaide, South Australia, 5000.
Mary Drikas
Professor, AWQC, SA Water, 250 Victoria Sq., Adelaide, South Australia, 5000.

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

Cited by

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share