Technical Papers
Apr 13, 2012

Application of Ferric Chloride for Removal of Glyphosate: Modeling of Axial and Radial Flow Impellers Using Artificial Neural Networks

Publication: Journal of Environmental Engineering
Volume 138, Issue 11

Abstract

This paper studied the removal of the herbicide Glyphosate in aqueous solution using ions capable of forming an insoluble complex Glyphosate salt (ferric chloride). A maximum Glyphosate removal of 67.4% was achieved using 300mg/L of ferric chloride. The precipitation of the insoluble Glyphosate salt was affected by rapid mixing velocity, rapid mixing time, dosage of flocculant, and types of impellers. An artificial neural networks (ANN) model was used to predict the removal of Glyphosate. The results showed good agreement over the range of experimental and predicted data. Increasing the velocity gradient increased the Glyphosate removal. The Glyphosate removal decreased with further increase in shear stress. At higher flocculant dosage, the effect of impeller shear is less as the flocs are stronger. The results showed that the effect of impeller type was highly dependent on the rapid mixing velocity and rapid mixing time.

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Acknowledgment

The authors gratefully acknowledge Ionic Solutions, Ltd. for providing the flocculant throughout this research study.

Reference

Al-Malack, M. H., Abuzaid, N. S., and El-Mubarak, A. F. (1999). “Coagulation of polymeric wastewater discharged by a chemical factory.” Water Res., 33(2), 521–529.
Department of environment (DOE). (2010). “Malaysian CropLife and Public Health Association.” 〈http://www.mcpa.org.my/index.php〉; (Apr. 2, 2011).
Ducoste, J. (2002). “A two-scale PBM for modeling turbulent focculation in water treatment processes.” Chem. Eng. Sci., 57(12), 2157–2168.
Geisler, R., Kerbs, R., and Forschner, P. (1994). Proc., 8th European Conf. on Mixing, IChemE Symp., Series No.
Grundl, T., and Delwiche, J. (1993). “Kinetics of ferric oxyhyroxide precipitation.” J. Contam. Hydrol., 14(1), 71–97.
Gregory, J. (2006). “Floc formation and floc structure.” Interface sci. in drinking water treatment, Hubbard, A.ed., Academic Press, 25–43.
Hodgkinson, I. (1997). Process for the preparation of N-Phosphonomethyglycine. WO Patent WO/1997/005, 149.
Hoerl, R. W., and Snee, R. D. (2002). “Statistical thinking: Improving business performance.” Duxbury Press, San Jose, CA.
Inc, W., and Inc, C. (2006). “Methods for treating wastewaters from industry.” Industrial waste treatment handbook, Butterworth Heinemann, Boston, 149–334.
Ives, K. J. (1990). Coagulation and flocculation part II—Orthokinetic flocculation, 3rd Ed., Butterworth Heinemann, London.
Johnson, C. P., Li, X., and Logan, B. E. (1996). “Settling velocities of fractal aggregates.” Environ. Sci. Technol., 30(6), 1911–1918.
Khrolenko, M. V., and Wieczorek, P. P. (2005). “Determination of glyphosate and its metabolite aminomethylphosphonic acid in fruit juices using supported-liquid membrane preconcentration method with high-performance liquid chromatography and UV detection after derivatization with p-toluenesulphonyl chloride.” J. Chromatogr. A, 1093(1–2), 111–117.
Kim, J. W., and Kramer, T. A. (2005). “Improved models for fractal colloidal agglomeration: Computationally efficient algorithm.” Colloids Surfaces, A, 253(1–3), 33–49.
Lu, S., Pugh, R. J., and Forssberg, H. (2005). “Flocculation with polymers.” Interfacial separation of particles, Möbius, D., and Miller, R., eds., Elsevier, Amsterdam, Netherlands, 354–414.
McBride, M., and Kung, K. H. (1989). “Complexation of Glyphosate and related ligands with Iron(III).” Soil Sci. Soc. Am. J., 53(6), 1668–1673.
Mhaisalkar, V. A., Paramasivam, R., and Bhole, A. G. (1991). “Optimizing physical parameters of rapid mix design for coagulation-flocculation of turbid waters.” Water Res., 25(1), 43–52.
Motojyuku, M., Saito, T., Akieda, K., Otsuka, H., Yamamoto, I., and Inokuchi, S. (2008). “Determination of glyphosate, glyphosate metabolites, and glufosinate in human serum by gas chromatography–mass spectrometry.” J. Chromatogr. B, 875(2), 509–514.
Pimentel, D. (2009). “Pesticides and pest control.” Integrated pest management: Innovation-development process, Rajinder, P., and Dhawan, A. K., eds., Springer, Houten, Netherlands, 83–87.
Prat, O. P., and Ducoste, J. J. (2007). “Simulation of flocculation in stirred vessels Lagrangian versus Eulerian.” Chem. Eng. Res. Des., 85(2), 207–219.
Records, A., and Sutherland, K. (2001). “Flocculation.” Decanter Centrifuge Handbook, Elsevier, Oxford, U.K., 215–241.
Selomulya, C. (2001). “The effect of shear on flocculation and floc size/structure.” Ph.D. thesis, The Univ. of New South Wales, Sydney, Australia.
Spicer, P. T., Keller, W., and Pratsinis, S. E. (1996). “The effect of impeller type on floc size and structure during shear-induced flocculation.” J. Colloid Interface Sci, 184(1), 112–122.
Sun, Y., Peng, Y., Chen, Y., and Shukla, A. J. (2003). “Application of artificial neural networks in the design of controlled release drug delivery systems.” Adv. Drug Delivery Rev., 55(9), 1201–1215.
Tebbutt, T. H. Y. (1998). “Coagulation.” Principles of water quality control, Elsevier, Oxford, U.K., 151–161.

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Published In

Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 138Issue 11November 2012
Pages: 1157 - 1164

History

Received: May 2, 2011
Accepted: Apr 11, 2012
Published online: Apr 13, 2012
Published in print: Nov 1, 2012

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Authors

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M. Mohsen Nourouzi, Ph.D. [email protected]
Dept. of Chemical and Environmental Engineering, Faculty of Engineering, Universiti Putra Malaysia, Sergang, Selangore 43300, Malaysia (corresponding author). E-mail: [email protected]
T. G. Chuah
Professor, Institute of Tropical Forestry and Forest Products (INTROP), Universiti Putra Malaysia, Sergang, Selangore 43300, Malaysia.
Thomas S. Y. Choong
Associate Professor, Dept. of Chemical and Environmental Engineering, Faculty of Engineering, Universiti Putra Malaysia, Sergang, Selangore 43300, Malaysia.

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