Potential Low-Cost Biosorbent for Copper Removal: Pineapple Leaf Powder
Publication: Journal of Environmental Engineering
Volume 138, Issue 3
Abstract
The present study investigates the adsorption characteristics of Cu(II) onto a low-cost biosorbent, pineapple leaf powder (PLP). Results of batch adsorption experiments showed that PLP could effectively remove Cu(II) from aqueous solution. Functional groups of PLP responsible for binding the were identified. The uptake of by PLP was very rapid, and 90% of Cu could be removed within the first 20 min. A pseudo-second-order equation could describe the kinetic data well. Copper adsorption was highly dependent on solution pH, and the removal efficiency was greater at a higher pH and low ionic strength. The apparent activation energy was calculated to be . The adsorption increased with temperature, suggesting an endothermic reaction. The maximum adsorption capacities calculated from Langmuir isotherms was at pH 5.0. From the perspective of waste utilization, high copper adsorption capacity, and freely abundant availability of this low-cost adsorbent, PLP is potentially useful for future practical applications.
Get full access to this article
View all available purchase options and get full access to this article.
Acknowledgments
This research was supported by the National Science Council of R.O.C. (Grant No. NSC NRC96-2221-E-214-013-MY3). The authors express their thanks to the fellows of MANALAB at I-Shou University for supporting the Field-SEM analysis.
References
Agriculture Annual Reports (AAR). (2007). “Council of agriculture, executive yuan.” Taipei, Taiwan.
Álvarez-Merino, M. A., López-Ramón, V., and Moreno-Castilla C. (2005). “A study of the static and dynamic adsorption of Zn(II) ions on carbon materials from aqueous solutions.” J. Colloid Interface Sci., 288(2), 335–341.
Aman, T., Kazi, A. A., Sabri, M. U., and Bano, Q. (2008). “Potato peels as solid waste for the removal of heavy metal copper(II) from waste water/industrial effluent.” Colloids Surf., B, 63(1), 116–121.
Argun, M. E., Dursun, S., Ozdemir C., and Karatas, M. (2007). “Heavy metal adsorption by modified oak sawdust: Thermodynamics and kinetics.” J. Hazard. Mater., 141(1), 77–85.
Bassi, R., Prasher, S. O., and Simpson, B. K. (2000). “Removal of selected metal ions form aqueous solutions using chitosan flakes.” Sep. Sci. Technol., 35(4), 547–560.
Bhattacharyya, K. G., and Sharma, A. (2005). “Kinetics and thermodynamics of Methylene Blue adsorption on Neem (Azadirachta indica) leaf powder.” Dyes Pigm., 65(1), 51–59.
Cay, S., Uyanik, A., and Ozajik, A. (2004). “Single and binary component adsorption of copper(II) and cadmium(II) from aqueous solutions using tea-industry waste.” Sep. Purif. Technol., 38(3), 273–280.
Chegrouche, S., Mellah, A., and Barkat, M. (2009). “Removal of strontium from aqueous solutions by adsorption onto activated carbon: Kinetic and thermodynamic studies.” Desalination, 235(1–3), 306–318.
Corapcioglu, M. O., and Huang, C. P. (1987a). “Surface acidity and characterization of some commercial activated carbons.” Carbon, 25(4), 569–578.
Corapcioglu, M. O., and Huang, C. P. (1987b). “The adsorption of heavy metals onto hydrous activated carbon.” Water Res., 21(9), 1031–1044.
Doğan, M., Abak, H., and Alkan M. (2009). “Adsorption of methylene blue onto hazelnut shell: Kinetics, mechanism and activation parameters.” J. Hazard. Mater., 164(1), 172–181.
Ertugay, N., and Bayhan, Y. K. (2010). “The removal of copper (II) ion by using mushroom biomass (Agaricus bisporus) and kinetic modeling.” Desalination, 255(1–3), 137–142.
Ho, Y. S., McKay, G. (1998). “A comparison of chemisorption kinetic models applied to pollutant removal on various adsorbents.” Trans. Inst. Chem. Eng., 76 Part B(4), 332–340.
Ho, Y. S., and McKay, G. (1999). “Pseudo-second order model for sorption processes.” Process Biochem., 34(5), 451–465.
Huang, C. P., and Blankenship, D. W. (1984). “The removal of mercury(II) from dilute aqueous solution by activated carbon.” Water Res., 18(1), 37–46.
Huang, C. P., and Fu, P. L. K. (1984). “Treatment of arsenic (V)-containing water by the activated carbon process.” J. Water Pollut. Control Fed., 56(3), 233–242.
Huang, C. P., and Ostovic, F. B. (1978). “Removal of cadmium (II) by activated carbon adsorption.” J. Environ. Eng., 104(5), 863–878.
Huang, C. C., and Su, Y. J. (2010). “Removal of copper ions from wastewater by adsorption/electrosorption on modified activated carbon cloths.” J. Hazard. Mater., 175(1–3), 477–483.
Huang, C. P., and Wirth, P. K. (1982). “Activated carbon for treatment of cadmium wastewater.” J. Environ. Eng., 108(6), 1280–1299.
Huang, C. P., and Wu, J. (1975). “Chromium removal by carbon adsorption.” J. Water Pollut. Control Fed., 47(10), 2437–2446.
Li, Y. et al. (2010). “Removal of copper from aqueous solution by carbon nanotube/calcium alginate composites.” J. Hazard. Mater., 177(1–3), 876–880.
Lopattananon, N., Panawarangkul, K. Sahakaro, K., and Ellis, B. (2006). “Performance of pineapple leaf fiber-natural rubber composites: The effect of fiber surface treatments.” J. Appl. Polym. Sci., 102(2), 1974–1984.
Lyklema, J. (1995). Fundamentals of interface and colloid science: Solid—liquid interfaces, Vol. 2, Academic Press, New York.
Machida, M., Aikawa, M., and Tatsumoto, H. (2005). “Prediction of simultaneous adsorption of Cu(II) and Pb(II) onto activated carbon by conventional Langmuir type equations.” J. Hazard. Mater., 120(1–3), 271–275.
Mohan, D., and Pittman, C. U. Jr. (2006). “Activated carbons and low cost adsorbents for remediation of tri- and hexavalent chromium from water.” J. Hazard. Mater., 137(2), 762–811.
Monanty, A. K., Tripathy, P. C., Misra, M., Parija, S., and Sahoo, S. (2000). “Natural fiber pineapple chemical modification of pineapple leaf fiber: Graft copolymerization of acrylonitrile onto defatted pineapple leaf fibers.” J. Appl. Polym. Sci., 77(14), 3035–3043.
Mwaikambo, L. Y., and Ansell, M. J. (2002). “Chemical modification of hemp, sisal, jute, and kapok fibers by alkalization.” J. Appl. Polym. Sci., 84(12), 2222–2234.
Nadaroglu, H., Kalkan, E., and Demir, N. (2010). “Removal of copper from aqueous solution using red mud.” Desalination, 251(1–3), 90–95.
Nollet, H., Roels, M., Lutgen, P., Van der Meeren, P., and Verstraete, W. (2003). “Removal of PCBs from wastewater using fly ash.” Chemosphere, 53(6), 655–665.
Saha, S. C., Das, B. K., Ray, P. K., Pandey, C. M., and Goswami, K. (1991). “Infrared spectra of raw and Chemically modified pineapple leaf fiber (annanus comosus).” J. Appl. Polym. Sci., 43(10), 1885–1890.
Wan, M. W., Kan, C. C., Rogel, B. D., and Dalida, M. L. P. (2010). “Adsorption of copper (II) and lead (II) ions from aqueous solution on chitosan-coated sand.” Carbohydr. Polym., 80(3), 891–899.
Weng, C. H., Lin, Y. T., and Tzeng, T. W. (2009). “Removal of methylene blue from aqueous solution by adsorption onto pineapple leaf powder.” J. Hazard. Mater., 170(1), 417–424.
Weng, C. H., Tsai, C. Z., Chu, S. H., and Sharma, Y. C. (2007). “Adsorption characteristics of copper(II) onto spent activated clay.” Sep. Purif. Technol., 54(2), 187–197.
Wu, F. C., Lingtseng, R., and Juang, R. S. (2001). “Kinetic modeling of liquid-phase adsorption of reactive dyes and metal ions on chitosan.” Water Res., 35(3), 613–618.
Information & Authors
Information
Published In
Copyright
© 2012 American Society of Civil Engineers.
History
Received: Oct 31, 2010
Accepted: May 2, 2011
Published online: May 4, 2011
Published in print: Mar 1, 2012
Authors
Metrics & Citations
Metrics
Citations
Download citation
If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.