TECHNICAL PAPERS
Dec 18, 2010

Effect of Hydrous Manganese Dioxide on the Treatment of Low-Turbidity Source Water: Plant-Scale Experience

Publication: Journal of Environmental Engineering
Volume 137, Issue 6

Abstract

The effect of potassium permanganate (KMnO4) preoxidation on the treatment of low-turbidity reservoir water was investigated through two years of operational data in a large-scale drinking water treatment plant (DWTP). KMnO4 facilitated the removal of pollutants [e.g., turbidity and chemical oxygen demand (CODMn)] by different units such as clarification, sand filtration, and granular activated carbon (GAC) adsorption. Although the addition of KMnO4 increased the color and total Mn concentrations, the results of removal by clarification and filtration are promising. The average run length of anthracite filters decreased from 48 to 40.8 hours after the introduction of KMnO4 and exhibited a negative correlation with KMnO4 dosages (r2=0.6912). The hydrous manganese dioxide in situ formed (δMnO2) dominated in aiding coagulation and improving filtration to enhance pollutant removal in the KMnO4 preoxidation process, and these effects were achieved at the expense of more frequent backwashing of anthracite filters.

Get full access to this article

View all available purchase options and get full access to this article.

Acknowledgments

This work was supported by a key project of the National Natural Sciences Foundation of China (NNSFC50938004) and a key project of National “863” High-tech Research and Development Program of China (UNSPECIFIED2008AA062501).

References

Aleboyeh, A., Olya, M. E., and Aleboyeh, H. (2009). “Oxidative treatment of azo dyes in aqueous solution by potassium permanganate.” J. Hazard. Mater., 162(2-3), 1530–1535.
Bruchet, A., Duguet, J. P., and Suffe, I. H. (2004). “Role of oxidants and disinfectants on the removal, masking and generation of tastes and odours.” Rev. Environ. Sci. Biotechnol., 3(1), 33–41.
Chen, J. J., and Yeh, H. H. (2005). “The mechanisms of potassium permanganate on algae removal.” Water Res., 39(18), 4420–4428.
Hedberg, T., and Wahlberg, T. A. (1998). “Upgrading of waterworks with a new biooxidation process for removal of manganese and iron.” Water Sci. Technol., 37(9), 121–126.
Li, G. B., and Liu, C. (1989). Removal of iron and manganese from groundwater, Architecture and Building Press, Beijing.
Li, N., Fan, M. H., van Leeuwen, J., Saha, B., Yang, H. Q., and Huang, C. P. (2007). “Oxidation of As(III) by potassium permanganate.” J. Environ. Sci. (China), 19(7), 783–786.
Liu, R. P. (2005). “Effectiveness and mechanisms of permanganate and permanganate composites removing pollutants through integrated oxidation and adsorption.” Ph.D. thesis, Dept. of Municipal Engineering, Harbin Institute of Technology, Harbin, China.
Liu, R. P., Liu, H. J., Qiang, Z. M., Qu, J. H., Li, G. B., and Wang, D. S. (2009). “Effects of calcium ions on surface characteristics and adsorptive properties of hydrous manganese dioxide.” J. Colloid Interface Sci., 331(2), 275–280.
Liu, R. P., Liu, H. J., Zhao, X., Qu, J. H., and Zhang, R. (2010). “Treatment of dye wastewater with permanganate oxidation and in situ formed manganese dioxides adsorption: Cation blue as model pollutant.” J. Hazard. Mater., 176(1-3), 926–931.
Liu, R. P., Yang, Y. L., Li, G. B., He, W. J., and Han, H. D. (2007). “Adsorptive behaviors of humic acid onto freshly prepared hydrous manganese dioxides.” Front. Environ. Sci. Eng. China, 1(2), 240–245.
Ma, J. (1991). “Effectiveness and mechanisms of potassium permanganate removing and controlling organic pollutants in drinking water.” Ph.D. thesis, Harbin Institute of Architecture and Civil Engineering, Harbin, China.
Moyers, B., and Wu, J. S. (1985). “Removal of organic precursors by permanganate oxidation and alum coagulation.” Water Res., 19(3), 309–314.
Murray, J. W. (1974). “The surface chemistry of hydrous manganese dioxide.” J. Colloid Interface Sci., 46(3), 357–371.
State Environment Protection Bureau. (1997). Standard methods for water and wastewater analysis, 3rd Ed., China Environmental Science Press, Beijing.
Sun, L. H., Liu, R. P., Xia, S. J., Yang, Y. L., and Li, G. B. (2009). “Enhanced As(III) removal with permanganate oxidation, ferric chloride precipitation and sand filtration as pretreatment of ultra-filtration.” Desalination, 243(1-3), 122–131.
Xu, X. P., Li, H. B., Wang, W. H., and Gu, J. D. (2005). “Decolorization of dyes and textile wastewater by potassium permanganate.” Chemosphere, 59(6), 893–898.
Yang, M., Yu, J. W., Li, Z. L., Guo, Z. H., Burch, M., and Lin, T. F. (2008). “Taihu Lake not to blame for Wuxi’s woes.” Science, 319(5860), 158.
Zhang, L. Z., Ma, J., Li, X., and Wang, S. T. (2009). “Enhanced removal of organics by permanganate preoxidation using tannic acid as a model compound—Role of in situ formed manganese dioxide.” J. Environ. Sci. (China), 21(7), 872–876.
Zhang, X. J., Zhang, Y., Wang, H., Zhang, S. X., and Jia, R. B. (2007). “Emergent drinking water treatment for taste and odor control in Wuxi City water pollution incident.” Water Wastewater Eng., 33(9), 7–12 (in Chinese).

Information & Authors

Information

Published In

Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 137Issue 6June 2011
Pages: 481 - 486

History

Received: Apr 20, 2010
Accepted: Dec 16, 2010
Published online: Dec 18, 2010
Published in print: Jun 1, 2011

Permissions

Request permissions for this article.

Authors

Affiliations

Ruiping Liu
Associate Professor, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, P.R. China; formerly, Graduate Student, School of Municipal and Environmental Engineering, Harbin Institute of Technology, Harbin, P.R. China.
Lihua Sun
Graduate Student, School of Municipal and Environmental Engineering, Harbin Institute of Technology, Harbin 150090, P.R. China.
Ran Ju
Graduate Student, School of Municipal and Environmental Engineering, Harbin Institute of Technology, Harbin 150090, P.R. China.
Hongjie Wang
Graduate Student, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, P.R. China.
Huijuan Liu [email protected]
Professor, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, P.R. China (corresponding author). E-mail: [email protected]
Junnong Gu
Senior Engineer, Center of Water Quality Examination and Monitoring, Beijing Waterworks Group, Beijing 100031, P.R. China.
Guibai Li
Professor, School of Municipal and Environmental Engineering, Harbin Institute of Technology, Harbin 150090, P.R. China.

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

Cited by

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share