TECHNICAL PAPERS
May 21, 2010

Modeling VOC Emissions in the High-Purity Oxygen Activated Sludge Process

Publication: Journal of Environmental Engineering
Volume 136, Issue 11

Abstract

Mass balances for volatile organic compounds (VOCs) were added to a structured mathematical model of the high-purity oxygen activated sludge (HPO-AS) process. The model was sized to correspond to two large existing HPO-AS treatment plants. The stripping of ten different VOCs was modeled and compared to stripping from conventional air activated sludge process. The results show that the covered aeration tanks can reduce stripping by more than 90%, depending on the specific VOC. If biodegradation is considered, the HPO-AS process degrades more than the conventional process due to the higher liquid-phase concentrations that result because of reduced stripping. The increase in biodegradation depends on the VOCs degradability but should increase to nearly 100% for highly volatile but biodegradable VOCs.

Get full access to this article

View all available purchase options and get full access to this article.

References

ASCE. (2006). “Measurement of oxygen transfer in clean water.” ASCE 2-06, New York.
Barton, D. A. (1987). “Intermedia transport of organic compounds in biological wastewater treatment processes.” Environ. Prog., 6(4), 246–256.
Blackburn, J. W. (1987). “Prediction of organic chemical fates in biological treatment systems.” Environ. Prog., 6(4), 217–223.
Busby, J. B., and Andrews, J. F. (1975). “Dynamic modeling and control strategies for the activated sludge process.” J. Water Pollut. Control Fed., 47(5), 1055–1080.
Clifft, R. C. (1980). “A dynamic model for predicting oxygen utilization in activated sludge processes.” Ph.D. thesis, Univ. of Houston, Houston, Tex.
Doyle, M. L., Boyle, W. C., Rooney, T., and Huibregtse, G. L. (1983). “Pilot-Plant determination of oxygen transfer in fine bubble aeration.” J. Water Pollut. Control Fed., 55(12), 1435–1440.
Gujer, W., Henze, M., Mino, T., and van Loosdrecht, M. (1999). “Activated sludge model No. 3.” Water Sci. Technol., 39(1), 183–193.
Gurol, M. D., and Nekouinaini, S. (1985). “Effect of organic substances on mass transfer in bubble aeration.” J. Water Pollut. Control Fed., 57(3), 235–240.
Hsieh, C. C. (1991). “Estimating volatilization rate and gas/liquid mass transfer coefficients in aeration systems.” Ph.D. thesis, Univ. of California, Los Angeles, Calif.
Hsieh, C.- C., Babcock, Jr., R. W., and Stenstrom, M. K. (1993b). “Estimating emissions of 20 VOCs: Diffused aeration.” J. Environ. Eng., 119(6), 1099–1118.
Hsieh, C.- C., Ro, K. S., and Stenstrom, M. K. (1993a).“Estimating emissions of 20 VOCs: Surface aeration.” J. Environ. Eng., 119(6), 1077–1098.
Libra, J. A. (1991). “Volatilization of organic compounds in an aerated stirred tank reactor.” Ph.D. thesis, Univ. of California, Los Angeles, Calif.
Mackay, D., and Yeun, A. T. K. (1983). “Mass transfer coefficient correlations for volatilization of organic solutes from water.” Environ. Sci. Technol., 17(4), 211–217.
McDonald, H. S., Nicholson, C. C., and Dezham, P. (1991). “Case studies of POTW air toxic emission tests and a proposed emission control strategy.” Proc., 1991 Speciality Conf., Environmental Engineering Div., ASCE, ASCE, Reston, Va., 425–430.
Metcalf and Eddy, Inc. (2003). Wastewater engineering: Treatment, disposal, and reuse, 4th Ed., McGraw-Hill, New York.
Mills, W. B., and Haith, D. A. (1985). “A screening procedure for toxic and conventional pollutants in surface and groundwater-Part I.” EPA-600/6-85/002a, U.S. Environmental Protection Agency, Athens, Ga.
Mueller, J. A., and Di Toro, D. M. (1991). “Multicomponent adsorption of volatile organic chemicals from air stripper offgas.” 64th WPCF Annual Conf., Alexandria, Va.
Namkung, E., and Rittmann, B. E. (1987). “Estimating volatile organic compound emissions from publicly owned treatment works.” J. Water Pollut. Control Fed., 59(7), 670–678.
Parker, W. J., Thompson, D. J., Bell, J. P., and Melcer, H. (1993). “Fate of volatile organic compounds in municipal activated sludge plants.” Water Environ. Res., 65(1), 58–65.
Roberts, P. V., Munz, C., and Dandliker, P. (1984). “Modeling volatile organic solute removal by surface and bubble aeration.” J. Water Pollut. Control Fed., 56(2), 157–163.
Stenstrom, M. K., and Andrews, J. F. (1979). “Real-Time control of activated sludge process.” J. Environ. Eng. Div., 105(2), 245–260.
Stenstrom, M. K., and Gilbert, R. G. (1981). “Effects of alpha, beta and theta factor upon the design, specification and operation of aeration systems.” Water Res., 15(6), 643–654.
Stenstrom, M. K., Kido, W., Shanks, R. F., and Mulkerin, M. (1989). “Estimating oxygen-transfer capacity of a full-scale pure oxygen activated-sludge plant.” J. Water Pollut. Control Fed., 61(2), 208–220.
Tata, P., Witherspoon, J., and Lue-Hing, C. (2003). VOC Emissions from wastewater treatment plants: Characterization, control and compliance, CRC, Boca Raton, Fla.
Tzeng, C. -J. (1992). “Advanced dynamic modeling of the high purity oxygen activated sludge process.” Ph.D. thesis, Univ. of California, Los Angeles, Calif.
Tzeng, C. -J., Iranpour, R., and Stenstrom, M. K. (2003). “Modeling and control of oxygen transfer in high purity oxygen activated sludge process.” J. Environ. Eng., 129(5), 402–411.
Yuan, W. B. W., Okrent, D., and Stenstrom, M. K. (1993). “Model calibration for the high-purity oxygen activated sludge process—Algorithm development and evaluation.” Water Sci. Technol., 28(11–12), 163–171.

Information & Authors

Information

Published In

Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 136Issue 11November 2010
Pages: 1189 - 1196

History

Received: Mar 31, 2009
Accepted: May 20, 2010
Published online: May 21, 2010
Published in print: Nov 2010

Permissions

Request permissions for this article.

Authors

Affiliations

Pan Jiang
Ph.D. Candidate, Dept. of Civil and Environmental Engineering, Univ. of California, Los Angeles, Los Angeles, CA 90095-1598.
Chwen-Jeng Tzeng
Technical Manager, CECI Engineering Consultants, Inc., Taipei, Taiwan.
Chu-Chin Hsieh
Professor, Dept. of Environmental and Safety Engineering, National Yunlin Univ., Yunlin, Taiwan.
Michael K. Stenstrom, F.ASCE
Professor, Dept. of Civil and Environmental Engineering, Univ. of California, Los Angeles, Los Angeles, CA 90095-1598 (corresponding author).

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

Cited by

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share