Technical Papers
May 2, 2019

Ice Melting Kinetics in Sand–Water Mixtures Investigated by Neutron Radiography and Diffraction

Publication: Journal of Cold Regions Engineering
Volume 33, Issue 3

Abstract

A combination of thermal neutron radiography and time-of-flight neutron diffraction is applied to analyze ice melting kinetics in sand–heavy water mixtures. Two different temperature regimes are applied: (1) cooling down to 262 K followed by spontaneous melting at room temperature (neutron radiography) and (2) cooling down to 250 K followed by controlled linear heating (neutron diffraction). Coarse and fine quartz sand batches are tested with the diameter of grains within the range 630–1,250 and 100–630 m, respectively. The solid–liquid transition temperature is observed to be significantly higher for the tested mixtures than for the sample containing pure heavy water only. A similar increase in the melting point of the mixtures relative to pure heavy water was observed by both of the applied methods. The enhancement amounted to 3 and 6 K in the case of the coarse and fine-grained samples, respectively. Grain size–dependent change in heat transport through the volume of the tested sand–heavy water ice mixtures is suggested as the main physical process behind the observed effect.

Get full access to this article

View all available purchase options and get full access to this article.

Acknowledgments

The research discussed here was carried out with the kind support of the Czech Science Foundation (Grant No. 17-06759S).

References

Abraham, J. 2015. “Methane release from melting permafrost could trigger dangerous global warming.” The Guardian, October 13, 2015.
Anderson, D. M., and P. Hoekstra. 1965. “Migration of interlamellar water during freezing and thawing of Wyoming bentonite.” Soil Sci. Soc. Am. Proc. 29 (5): 498–504. https://doi.org/10.2136/sssaj1965.03615995002900050010x.
Anderson, D. M., and A. R. Tice. 1973. “The unfrozen interfacial phase in frozen soil water systems.” Ecol. Stud. 4 (1): 107–125. https://doi.org/10.1007/978-3-642-65523-4_12.
Anderson, I. S., R. L. McGreevy, and H. Z. Bilheux. 2009. Neutron imaging and applications: A reference for the imaging community. New York: Springer.
Beskow, G. 1935. Soil freezing and frost heaving. Stockholm, Sweden: SGU.
Bing, H., and W. Ma. 2011. “Laboratory investigation of the freezing point of saline soil.” Cold Reg. Sci. Technol. 67 (1–2): 79–88. https://doi.org/10.1016/j.coldregions.2011.02.008.
Bronfenbrener, L. 2009. “The modelling of the freezing process in fine-grained porous media: Application to the frost heave estimation.” Cold Reg. Sci. Technol. 56 (2–3): 120–134. https://doi.org/10.1016/j.coldregions.2008.11.004.
Bronfenbrener, L., and E. Korin. 2002. “Experimental studies of water crystallization in porous media.” Chem. Eng. Process. 41 (4): 357–363. https://doi.org/10.1016/S0255-2701(01)00156-8.
Dore, J., M. Dunn, and P. Chieux. 1987. “Neutron diffraction studies of ice nucleation in porous silica.” J. Phys. Colloques 48 (C1): C1-457–C1-463. https://doi.org/10.1051/jphyscol:1987163.
Goers, D., M. Holzapfel, W. Scheifele, E. Lehmann, P. Vontobel, and P. Novák. 2004. “In situ neutron radiography of lithium-ion batteries: The gas evolution on graphite electrodes during the charging.” J. Power Sour. 130 (1–2): 221–226. https://doi.org/10.1016/j.jpowsour.2003.11.065.
Guyman, G. L., R. L. Berg, and T. V. Hromadka. 1993. Mathematical model of frost heave and thaw settlement in pavements. Hanover, NH: USACE.
Justnes, H., K. Bryhn-Ingebrigtsen, and G. O. Rosvold. 1994. “Neutron radiography: An excellent method of measuring water penetration and moisture distribution in cementitious materials.” Adv. Cem. Res. 6 (22): 67–72. https://doi.org/10.1680/adcr.1994.6.22.67.
Kolaian, J. H., and P. F. Low. 1963. “Calorimetric determination of unfrozen water inmontmorillonite pastes.” Soil Sci. 95 (6): 376–384. https://doi.org/10.1097/00010694-196306000-00002.
Kozlenko, D. P., S. E. Kichanov, E. V. Lukin, A. V. Rutkauskas, A. V. Belushkin, G. D. Bokuchava, and B. N. Savenko. 2016. “Neutron radiography and tomography facility at IBR-2 reactor.” Phys. Part. Nucl. Lett. 13 (3): 346–351. https://doi.org/10.1134/S1547477116030146.
Kozlenko, D. P., S. E. Kichanov, E. V. Lukin, A. V. Rutkauskas, G. D. Bokuchava, B. N. Savenko, A. V. Pakhnevich, and A. Y. Rozanov. 2015. “Neutron radiography facility at IBR-2 high flux pulsed reactor: First results.” Phys. Procedia 69 (1): 87–91. https://doi.org/10.1016/j.phpro.2015.07.012.
Kozlenko, D. P., S. E. Kichanov, E. V. Lukin, and B. N. Savenko. 2018. “The DN-6 neutron diffractometer for high-pressure research at half a Megabar scale.” Crystals 8 (8): 331. https://doi.org/10.3390/cryst8080331.
Kozlowski, T. 2016. “A simple method of obtaining the soil freezing point depression, the unfrozen water content and the pore size distribution curves from the DSC peak maximum temperature.” Cold Reg. Sci. Technol. 122 (1): 18–25. https://doi.org/10.1016/j.coldregions.2015.10.009.
Kozlowski, T., and L. Walaszczyk. 2014. “Analyzing expanding clays by thermoporometry using a stochastic deconvolution of the DSC signal.” Clays Clay Miner. 62 (5): 386–402. https://doi.org/10.1346/CCMN.2014.0620503.
Kurylyk, B. L., and K. Watanabe. 2013. “The mathematical representation of freezing and thawing processes in variably-saturated, non-deformable soils.” Adv. Water Resour. 60 (1): 160–177. https://doi.org/10.1016/j.advwatres.2013.07.016.
Lehmann, E. H., A. Kaestner, C. Gruenzweig, D. Mannes, P. Vontobel, and S. Peetermans. 2014. “Materials research and non-destructive testing using neutron tomography methods.” Int. J. Mater. Res. 105 (7): 664–670. https://doi.org/10.3139/146.111053.
Li, J., Y. Luo, S. Natali, E. Schuur, J. Xia, E. Kowacyk, and Y. Wang. 2014. “Modeling permafrost thaw and ecosystem carbon cycle under annual and seasonal warming at an Arctic tundra site in Alaska.” J. Geophys. Res.: Biogeosci. 119 (6): 1129–1146. https://doi.org/10.1002/2013JG002569.
Lundin, L.-C. 1989. “Water and heat flows in frozen soils: Basic theory and operational modeling.” Ph.D. thesis, Dept. of Earth Sciences, Uppsala Univ.
Nakamura, M., K. Tamura, and S. Murakami. 1995. “Isotope effects on thermodynamic properties: Mixtures of x(D2OorH2O)+(1x)CH3CN at 298.15 K.” Thermochim. Acta 253 (1): 127–136. https://doi.org/10.1016/0040-6031(94)02086-4.
Perfect, E., C.-L. Cheng, M. Kang, H. Z. Bilheux, J. M. Lamanna, M. J. Gragg, and D. M. Wright. 2014. “Neutron imaging of hydrogen-rich fluids in geomaterials and engineered porous media: A review.” Earth-Sci. Rev. 129 (1): 120–135. https://doi.org/10.1016/j.earscirev.2013.11.012.
Pusch, R. 1979. “Unfrozen water as a function of clay microstructure.” Eng. Geol. 13 (1–4): 157–162. https://doi.org/10.1016/0013-7952(79)90028-0.
Rattanadecho, P. 2006. “Simulation of melting of ice in a porous media under multiple constant temperature heat sources using a combined transfinite interpolation and PDE methods.” Chem. Eng. Sci. 61 (14): 4571–4581. https://doi.org/10.1016/j.ces.2006.02.018.
Reichelt, J. M. A., and A. L. Rodgers. 1966. “Neutron diffraction by time-of-flight.” Nucl. Instrum. Methods 45 (2): 245–249. https://doi.org/10.1016/0029-554X(66)90295-3.
Rempel, A. W. 2010. “Frost heave.” J. Glaciol. 56 (200): 1122–1128.
Rodrıguez-Carvajal, J. 1993. “Recent advances in magnetic structure determination by neutron powder diffraction.” Phys. B 192 (1–2): 55–69. https://doi.org/10.1016/0921-4526(93)90108-I.
Romanelli, G., M. Ceriotti, D. E. Manolopoulos, C. Pantalei, R. Senesi, and C. Andreani. 2013. “Direct measurement of competing quantum effects on the kinetic energy of heavy water upon melting.” J. Phys. Chem. Lett. 4 (19): 3251–3256. https://doi.org/10.1021/jz401538r.
Schneider, C. A., W. S. Rasband, and K. W. Eliceiri. 2012. “NIH Image to ImageJ: 25 years of image analysis.” Nat. Methods 9 (7): 671–675. https://doi.org/10.1038/nmeth.2089.
Sears, V. F. 1992. “Neutron scattering lengths and cross sections.” Neutron News 3 (3): 26–37. https://doi.org/10.1080/10448639208218770.
Steckel, F., and S. Szapiro. 1963. “Physical properties of heavy oxygen water. Part 1: Density and thermal expansion.” Trans. Faraday Soc. 59 (1): 331–343. https://doi.org/10.1039/TF9635900331.
Tian, H., C. Wei, H. Wei, and J. Zhou. 2014. “Freezing and thawing characteristics of frozen soils: Bound water content and hysteresis phenomenon.” Cold Reg. Sci. Technol. 103 (1): 74–81. https://doi.org/10.1016/j.coldregions.2014.03.007.
Tice, A. R., J. L. Oliphant, Y. Nakano, and T. F. Jenkins. 1982. Relationship between the ice and unfrozen water phases in frozen soil as determined by pulsed nuclear magnetic resonance and physical desorption data. Hanover, NH: USACE.
Wagner, W., et al. 2000. “The IAPWS industrial formulation 1997 for the thermodynamic properties of water and steam.” ASME J. Eng. Gas Turbines Power 122 (1): 150–182. https://doi.org/10.1115/1.483186.
Wu, M., X. Tana, J. Huang, J. Wua, and P.-E. Jansson. 2015. “Solute and water effects on soil freezing characteristics based on laboratory experiments.” Cold Reg. Sci. Technol. 115 (1): 22–29. https://doi.org/10.1016/j.coldregions.2015.03.007.
Žák, A., M. Beneš, and T. H. Illangasekare. 2013. “Analysis of model of soil freezing and thawing.” Int. J. Appl. Math. 43 (3): 127–134.

Information & Authors

Information

Published In

Go to Journal of Cold Regions Engineering
Journal of Cold Regions Engineering
Volume 33Issue 3September 2019

History

Received: May 25, 2018
Accepted: Dec 4, 2018
Published online: May 2, 2019
Published in print: Sep 1, 2019
Discussion open until: Oct 2, 2019

Permissions

Request permissions for this article.

Authors

Affiliations

Associated Professor, Faculty of Nuclear Science and Physical Engineering, Czech Technical Univ. in Prague, Břehová 7, Prague 1 115 19, Czech Republic (corresponding author). ORCID: https://orcid.org/0000-0002-4051-7093. Email: [email protected]
Sergey E. Kichanov, Ph.D.
Frank Laboratory of Neutron Physics, Joint Institute for Nuclear Research, Dubna 141980, Russia.
Monika Kučeráková, Ph.D.
Faculty of Nuclear Science and Physical Engineering, Czech Technical Univ. in Prague, Břehová 7, Prague 1 115 19, Czech Republic.
Evgenyi V. Lukin, Ph.D.
Frank Laboratory of Neutron Physics, Joint Institute for Nuclear Research, Dubna 141980, Russia.
Stanislav Vratislav, Ph.D.
Professor, Faculty of Nuclear Science and Physical Engineering, Czech Technical Univ. in Prague, Břehová 7, Prague 1 115 19, Czech Republic.

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

Cited by

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share