PRACTICE PERIODICAL ARTICLES
Jul 1, 2001

Measuring Phytoremediation Parameters for Volatile Organic Compounds: Focus on MTBE

Publication: Practice Periodical of Hazardous, Toxic, and Radioactive Waste Management
Volume 5, Issue 3

Abstract

Experimental techniques are described for conducting greenhouse tests to examine the pathways for phytoremediation of volatile organic compounds (VOCs), distinguishing between uptake of the VOC along with water transpired by living plants and the passive, physical process of volatilization. The experimental techniques were applied to assess the potential for phytoremediation of methyl-tertiary-butyl-ether (MTBE). Experimental data indicate that MTBE was readily taken up from water by hybrid poplar saplings, yielding 25% reduction in aqueous MTBE concentration and 30% reduction in MTBE mass over a 1-week period. These reductions in plant systems were significantly greater than in controls, indicating great potential for MTBE phytoremediation in the field. Engineering parameters for phytoremediation were determined from the experiments, yielding an MTBE transpiration stream concentration factor of 1 and a root concentration factor of 0.7–1.4. Mass balance studies showed good closure on MTBE mass balance, indicating no significant degradation of MTBE in the young poplar saplings used in this study. These results suggest that phytovolatilization may be the primary pathway for MTBE phytoremediation.

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References

1.
Briggs, G. G., Bromilow, R. H., and Evans, A. A. ( 1982). “Relationship between lipophobicity and root uptake and translocation of non-ionized chemicals by barley.” Pestic. Sci., 13, 495–504.
2.
Burken, J. G., and Schnoor, J. L. ( 1998). “Predictive relationships for uptake of organic contaminants by hybrid poplar trees.” Envir. Sci. and Technol., 32(21), 3379–3385.
3.
Howard, P. ( 1991). Handbook of environmental degradation rates, Lewis, Chelsea, Mich.
4.
Johnson, R., Pankow, J., Bender, D., Price, C., and Zogorski, J. ( 2000). “MTBE to what extent will past releases contaminate community water supply wells?” Envir. Sci. and Technol., 34(5), 1399– 1406.
5.
National Research Council (NRC). ( 1996). “Toxicological and performance aspects of oxygenated motor vehicles fuels.” National Academy Press, Washington, D.C.
6.
Newman, I., et al. ( 1999). “Remediation of trichloroethylene in an artificial aquifer with trees: A controlled field study.” Envir. Sci. and Technol., 33(13), 2257–2265.
7.
Pankow, J. F., Thompson, N. R., Johnson, R. L., Baehr, A. L., and Zogorski, J. S. ( 1997). “The urban atmosphere as a non-point source for the transport of MTBE and other volatile organic compounds (VOC's) to shallow groundwater.” Envir. Sci. and Technol., 31(10), 2821–2828.
8.
Ramsden, D. ( 2000). “MTBE bioremediation studies: Are we learning anything?” Soil Sediment and Groundwater, Special Issue on MTBE, 34–40.
9.
Rubin, F., and Ramaswami, A. ( 2001). “The potential for phytoremediation of MTBE.” Water Res., 35(5), 1348–1353.
10.
Schnoor, J. L., Licht, L. A., McCutcheon, S. C., Wolfe, N. L., and Carreira, L. H. ( 1995). “Phytoremediation of organic and nutrient contaminants.” Envir. Sci. and Technol., 29(7), 318A–323A.
11.
Schwarzenbach, R. P., Gschwend, P. M., and Imboden, D. M. ( 1993). Environmental organic chemistry, Wiley, New York.
12.
Suflita, J. M., and Mormile, M. R. ( 1993). “Anaerobic biodegradation of known and potential gasoline oxygenates in the terrestrial subsurface.” Envir. Sci. and Technol., 27, 976–978.
13.
Suthersan, S. S. ( 1997). Remediation engineering design concepts, CRC, Boca Raton, Fla.
14.
U.S. Environmental Protection Agency (USEPA). ( 1993). “Technical information review. Methyl tertiary butyl ether.” Case No. 1634-04-4, Office of Pollution Prevention and Toxics, Washington, D.C.
15.
U.S. Environmental Protection Agency (USEPA). ( 2000). “Introduction to phytoremediation.” EPA/600/R-99/107, Office of Research and Development, Cincinnati.

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Go to Practice Periodical of Hazardous, Toxic, and Radioactive Waste Management
Practice Periodical of Hazardous, Toxic, and Radioactive Waste Management
Volume 5Issue 3July 2001
Pages: 123 - 129

History

Received: Mar 22, 2001
Published online: Jul 1, 2001
Published in print: Jul 2001

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P.E.
Asst. Prof., PhD, Dept. of Civ. Engrg., Univ. of Colorado-Denver, Denver, CO 80217.
Doctoral Student, Dept. of Civ. Engrg., Univ. of Colorado-Denver, Denver, CO 80217.

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