Experimental Studies on Ettringite-Induced Heaving in Soils
Publication: Journal of Geotechnical and Geoenvironmental Engineering
Volume 131, Issue 3
Abstract
Sulfate-induced heaving in soils is primarily attributed to ettringite formation from the reactions between calcium of a lime or cement stabilizer, reactive alumina in soils, and sulfates in soils. Ettringite formation and subsequent heaving in soils are complex topics that are not well understood. This research is an attempt to advance the state of the knowledge on these topics. Ettringite was successfully synthesized in the laboratory by simulating conditions close to those in chemically treated sulfate-bearing soils. Soils spiked and compacted with the synthesized ettringite did not undergo heaving in one-dimensional free swell tests. However, heaving was observed when ettringite was formed inside the lime-treated soil specimen by including ionic reactions. Mineralogical studies including x-ray diffraction and scanning electron microscope studies were used to evaluate the presence of ettringite. Experimental investigations showed that the ettringite or sulfate-induced heaving was higher in clays than in sands under similar chemistry and environmental conditions. This is attributed to the void sizes of soil types and crystalline ettringite formation in the voids. Also, the effects of soil type, lime and sulfate amounts on this type of heaving, and hypothesized threshold levels of chemical ions to form ettringite mineral in treated soils, are addressed.
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Acknowledgments
The contents of this paper reflect the views of the writers, who are responsible for the facts and accuracy of the data presented. They would like to acknowledge the National Science Foundation (Program Director: Dr. Richard J. Fragaszy) for supporting this research under NSF Grant No. 0100255. The writers would also like to acknowledge the Civil and Environmental Engineering Department of UT Arlington for providing student support to this research and acknowledge both the Materials Science Department of UTA and the Chemistry Department of Southern Methodist University (SMU) for providing SEM and XRD equipment access to the present research.
References
Burkart, B., Goss, C. G., and Kern, P. J. (1999). “The role of gypsum in production of sulfate-induced deformation of lime-stabilized soils.” Environ. Eng. Geosci., 5(2), 173–187.
Chen, F. H. (1988). Foundations on expansive soils, 2nd ed., Elsevier, New York.
Chomtid, S. (2000). “Laboratory evaluation of sulfate heaving mechanisms in artificial illite soil and natural soil.” MS thesis, Univ. of Texas at Arlington, Arlington, Tex.
Dermatas, D. (1995). “Ettringite-induced swelling in soils: State-of-the-art.” Appl. Mech. Rev., 48(10), 659–673.
Hausmann, M. R. (1990). Engineering principles of ground modification, McGraw–Hill, New York.
Hunter, D. (1988). “Lime-induced heave in sulfate-bearing clay soils.” J. Geotech. Eng., 114(2), 150–167.
Jonathan, L. W., Griffin, P. V. C., Andrew, W., and Roger, D. (1999). “Design and synthesis of macrocyclic ligands for specific interaction with crystalline ettringite and demonstration of a viable mechanism for the setting of cement.” J. Chem. Soc., Perkin Trans. 2, 10, 1973–1981.
Joint Committee on Powder Diffraction Standards (JCPDS). (1998). International Centre for Diffraction Data, Publication DBM-1-23, Philadelphia.
Kota, P., Hazlett, D., and Perrin, L. (1996). “Sulfate-bearing soils: Problems with calcium based stabilizers.” Transportation Research Record. 1546, National Research Council, Washington, D.C. 62–69.
Kujala, K., and Nieminen, P. (1983). “On the reactions of clays stabilized with gypsum lime.” Proc., 8th European Conf. on Soil Mechanics and Foundation Engineering, 2, 929–932.
Lindsay, W. L. (2001). Chemical equilibria in soils, Wiley, New York.
McCallister, L. D., and Tidwell, L. (1994). “Double treatment to minimize sulfate-lime-induced heave in expansive clays.” Final report, United States Military Academy, West Point, N.Y.
Mitchell, J. K. (1986). “Practical problems from surprising soil behavior.” J. Geotech. Eng., 112(3), 255–289.
Mitchell, J. K., and Dermatas, D. (1992). “Clay soil heave caused by lime-sulfate reactions.” ASTM STP 1135, Innovations and Uses for Lime, Philadelphia.
Nelson, J. D., and Miller, D. J. (1992). Expansive soils: Problems and practice in foundation and pavement engineering, Wiley, N.Y.
Odler, I., and Abdul, M. (1984). “Possibilities of quantitative determination of the Aft—(ettringite) and AFm—(monosulphate) phases in hydrated cement pastes.” Cem. Concr. Res., 14(1), 133–141.
Perrin, L. L. (1992). “Expansion of lime-treated clays containing sulfates.” Proc., 7th Int. Conf. on Expansive Soils.
Petry, M. T. (1994). “Studies of factors causing and influencing localized heave of lime-treated clay soils (sulfate-induced heave).” Final Report, Univ. of Texas at Arlington, Arlington, Tex.
Puppala, A. J., Hanchanloet, S., Jadeja, M., and Burkart, B. (1999). “Evaluation of sulfate-induced heave by mineralogical and swell tests.” Proc., 9th Pan-American Conf. on Soil Mechanics and Geotechnical Engineering.
Puppala, A. J., Wattanasanticharoen, E., Intharasombat, N., and Hoyos, L. R. (2003). “Studies to understand soil compositional and environmental variables on sulfate heave problems.” Proc., Soil Rock America, 12th Pan American Conf. on Soil Mechanics and Geotechnical Engineering.
Rollings, M. P., and Rollings, R. S. (2003). “Sulfate attack on bound bases.” Proc., Transportation Research Board Annual Meeting, (CD-ROM) Washington, D.C.
Rollings, R. S., Burkes, J. P., and Rollings, M. P. (1999). “Sulfate attack on cement-stabilized sand.” J. Geotech. Geoenviron. Eng., 125(5), 364–372.
Schoute, E. (1999). “Chemical stabilization of soft clays.” MS thesis, Center of Engineering Geology, No. 188, Delft Univ.
Shizong, L., Yanrog, W., and Chen, L. (1995). “Investigation on the formation of ettringite in the presence of BaO.” Cem. Concr. Res., 25(7), 1417–1422.
Struble, L. J., and Brown, P. W. (1984). “An evaluation of ettringite and related compounds for use in solar energy storage.” Progress Report, NBSIR 84-2942, National Bureau of Standards, Gaithersburg, Md.
Vempati, R. K., and Cocke, D. L. (1994). “Application of atomic force microscopy to soil minerals.” Proc., 15th Int. Soil Science Congress.
Vempati, R. K., Chintala, A. K., Mollah, M. Y. A., and Cocke, D. L. (1996). “Stabilization and solidification of toxic wastes using coke and coal combustion by-products.” Waste Manage., 15, 433–440.
Viyanant, C. (2000). “Laboratory evaluation of sulfate heaving mechanisms in artificial kaolinite soil.” M.S. thesis, Univ. of Texas at Arlington, Arlington, Tex.
Wang, L. (2002). “Cementitious stabilization of soils in the presence of sulfate.” PhD thesis, Louisiana State Univ., La.
Wild, S., Kinuthia, J. M., Jones, G. I., and Higgins, D. D. (1998). “Suppression of swelling associated with ettringite formation in lime stabilized sulfate bearing soils by partial substitution of lime with ground granulated blast furnace slag.” Eng. Geol. (Amsterdam), 51, 257–277.
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© 2005 ASCE.
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Received: Aug 1, 2003
Accepted: Jul 23, 2004
Published online: Mar 1, 2005
Published in print: Mar 2005
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