TECHNICAL PAPERS
May 1, 1999

Sulfate Attack on Cement-Stabilized Sand

Publication: Journal of Geotechnical and Geoenvironmental Engineering
Volume 125, Issue 5

Abstract

A 3.5-km (2.2 mi) section of a road in Georgia developed unexpected transverse bumps within 6 months after construction. The source of the bumps appeared to be expansion within the cement-stabilized base course. Laboratory examination of samples from areas showing distress revealed the presence of ettringite, a calcium sulfoaluminate the formation of which can be accompanied by severe expansion. This expansive material was the probable cause of the volume changes causing the transverse bumps. The calcium and alumina needed to form ettringite were available from the portland cement and the stabilized soil's clay minerals. The source of the sulfur was identified as the well water that was mixed with the cement-stabilized base. Sulfate attack of cement-stabilized soils is a relatively infrequent problem, but it is highly destructive when it occurs. Currently, there are no firm criteria for identifying when sulfate attack of a cement-stabilized soil is a potential problem nor are there established methods of preventing the attack.

Get full access to this article

View all available purchase options and get full access to this article.

References

1.
Corps of Engineers. ( 1949). “Method of test for determination of sulfate ion in soil and water.” Handbook for concrete and cement. CRD-C 403, U.S. Army Engineer Waterways Experiment Station, Vicksburg, Miss.
2.
DePuy, G. W. ( 1994). “Chemical resistance of concrete.” Significance of tests and properties of concrete and concrete-making materials, ASTM 169C, P. Klieger and J. Lamond, eds., ASTM, West Conshohocken, Pa., 263–281.
3.
Dunlap, W. A., Epps, J. A., Biswas, B. R., and Gallaway, B. M. ( 1975). “United States Air Force soil stabilization index system: A validation.” Rep. No. AFWL-TR-73-150, Air Force Weapons Laboratory, Kirtland Air Force Base, New Mexico.
4.
“Guide to durable concrete.” (1998). ACI 201.2R-92, ACI manual of concrete practice, Vol. 1, American Concrete Institute, Detroit.
5.
Hunter, D. (1988). “Lime-induced heave in sulfate-bearing clay soils.”J. Geotech. Engrg., ASCE, 114(2), 150–167.
6.
Hunter, D. ( 1989). “The geochemistry of lime-induced heave in sulfate bearing clay soils,” PhD dissertation, University of Nevada, Reno, Nev.
7.
McCallister L. D., and Tidwell, L. ( 1997). “Double lime treatment to minimize sulfate-lime induced heave in expansive clays.” Draft Tech. Rep., U.S. Army Engineers, Waterways Experiment Station, Vicksburg, Miss.
8.
Mehta, P. K., and Klein, A. ( 1966). “Investigation on the hydration products in the system 4CaO⋅3Al2O3⋅SO3-CaSO4-CaO-H2O.” Hwy. Res. Board Spec. Rep. No. 90, National Research Council, Washington, D.C. 328–352.
9.
Mitchell, J. K. (1986). “Practical problems from surprising soil behavior.”J. Geotech. Engrg., ASCE, 112(3), 259–289.
10.
Mitchell, J. K. ( 1993). Fundamentals of soil behavior, 2nd ed., Wiley Intescience, New York.
11.
Mitchell, J. K., and Dermatas, D. ( 1992). “Clay soil heave caused by lime-sulfate reactions.” Innovations and uses for lime. STP 1135, D. C. Hoffman and D. D. Stanley, eds., ASTM West Conshohocken, Pa., 41–64.
12.
Neville, A. M. ( 1981). Properties of concrete. Pitman Books, London.
13.
Perrin, L. . ( 1992). “Expansion of lime-treated clays containing sulfates.” Proc., 7th Int. Conf. on Expansive Soils, Vol. 1, ASCE Expansive Soils Research Council, New York, 409–414.
14.
Petry, T. M. ( 1994). “Studies of factors causing and influencing localized heave of lime treated clay soils (sulfate induced heave).” Contract Rep., U.S. Army Engineers, Waterways Experiment Station, Vicksburg, Miss.
15.
Petry, T. M., and Little, D. N. ( 1992). “Update on sulfate induced heave in lime and portland cement treated clays: Determination of potentially problematic sulfate levels.” Transp. Res. Rec., No. 1362, Transportation Research Board, Washington, D.C., 51–55.
16.
Rollings, M. P. and Rollings, R. S. ( 1996). Geotechnical materials in construction. McGraw-Hill, New York.
17.
Sherwood, P. T. ( 1962). “Effect of sulfates on cement and lime-stabilized soils.” Hwy. Res. Board Bull. 353, National Research Council, Washington, D. C.
18.
Snedker, E. A., and Temporal, J. ( 1990). “M 40 Motorway Bunbury IV Contract—lime stabilization.” J. Inst. of Hwy. and Transp., London, 37(12), 7–8.
19.
“State-of-the-art report on soil cement.” (1998). ACI 230-1R-90 (reapproved 1997), ACI manual of concrete practice, Vol. 1, American Concrete Institute, Detroit.
20.
Terzaghi, K. ( 1958). “Design and performance of the Sasamua Dam,” Proc. Inst. Civ. Engrs., London, 9, 269–394.
21.
Thomas, M. D. A., Kettle, R. J., and Morton, J. A. ( 1989). “Expansion of cement stabilized minestone due to oxidation of pyrite.” Transp. Res. Rec. No. 1219, National Research Council, Washington, D.C.
22.
The World Almanac and Book of Facts . (1994). Funk and Wagnalls, Mahwah, N.J.

Information & Authors

Information

Published In

Go to Journal of Geotechnical and Geoenvironmental Engineering
Journal of Geotechnical and Geoenvironmental Engineering
Volume 125Issue 5May 1999
Pages: 364 - 372

History

Received: Jun 12, 1997
Published online: May 1, 1999
Published in print: May 1999

Permissions

Request permissions for this article.

Authors

Affiliations

Member, ASCE,
Member, ASCE
Res. Civ. Engr., U.S. Army Engineer Waterways Experiment Station, 3909 Halls Ferry Rd., Vicksburg, MS 39180.
Res. Petrographer (retired), U.S. Army Engineer Waterways Experiment Station, 3909 Halls Ferry Rd., Vicksburg, MS.
Res. Civ. Engr., U.S. Army Engineer Waterways Experiment Station, 3909 Halls Ferry Rd., Vicksburg, MS.

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

Cited by

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share