TECHNICAL PAPERS
Aug 1, 2001

General Conservation Equation for Solute Transport in Heterogeneous Porous Media

Publication: Journal of Hydrologic Engineering
Volume 6, Issue 4

Abstract

In this study it is shown that in heterogeneous porous media all the ensemble average conservation equations, representing linear reactive and nonreactive transport at a spatial scale one step larger than the Darcy scale, are in the same operator equation form as given by (15) herein for vector cases and by (18) herein for scalar cases to exact second-order closure (they do not need information on third or higher moments or cumulants). This equation acts as a “master key” in that once one determines the particular form of the coefficient operator within a Darcy-scale transport equation, corresponding to a particular linear transport case, one can then write immediately the explicit ensemble average transport equation for this case for the spatial scale that is one-step larger than the Darcy scale. The aforementioned equations are in Eulerian-Lagrangian form since while the spatial coordinate xt is given by time t, the spatial coordinate xts is an unknown which is determined by the Lagrangian trajectories of the fluid motion during the time interval (ts, t). The exact formula for the determination of xts is provided. Along with general chemical heterogeneity, both hydraulic conductivity and porosity are taken as random fields.

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References

1.
Andricevic, R. ( 1995). “Comment on `Stochastic analysis of the transport of kinetically sorbing solutes in aquifers with randomly heterogeneous hydraulic conductivity,' by H. Quinodoz and A. Valocchi.” Water Resour. Res., 31(1), 237–243.
2.
Bear, J., and Verruijt, A. ( 1987). Modeling groundwater flow and pollution, Reidel, Boston.
3.
Berglund, S., and Cvetkovic, V. ( 1996). “Contaminant displacement in aquifers: Coupled effects of flow heterogeneity and nonlinear sorption.” Water Resour. Res., 32(1), 23–32.
4.
Cushman, J. H. ( 1991). “On diffusion in fractal porous media.” Water Resour. Res., 27, 643–644.
5.
Cushman, J. H., and Ginn, T. R. ( 1993). “On dispersion in fractal porous media.” Water Resour. Res., 29, 3513–3515.
6.
Cushman, J. H., and Ginn, T. R. ( 1999). “Reactive contaminant transport in the saturated zone.” Handbook of groundwater engineering, J. W. Delleur, ed., CRC, Boca Raton, Fla., 15-1–15-20.
7.
Cushman, J. H., Hu, B. X., and Deng, F.-W. ( 1996). “Comparison of Eulerian to Lagrangian expected spatial moments for transport in a heterogeneous porous medium with deterministic linear nonequilibrium sorption.” Chem. Engrg. Comm., 148–150, 5–21.
8.
Cvetkovic, V., and Dagan, G. ( 1996). “Reactive transport and immiscible flow in geological media. II. Applications.” Proc. Royal Soc., London, Series A, 452, 303–328.
9.
Dagan, G. ( 1984). “Solute transport in heterogeneous porous formations. J. Fluid Mech., London, 145, 151–177.
10.
Dagan, G. ( 1987). “Theory of solute transport by groundwater.” Ann. Rev. Fluid Mech., 19, 183–215.
11.
Dagan, G., Bellin, A., and Rubin, Y. ( 1996). “Lagrangian analysis of transport in heterogeneous formations under transient flow conditions.” Water Resour. Res., 32, 891–899.
12.
Dagan, G., and Cvetkovic, V. ( 1993). “Spatial moments of a kinetically sorbing solute plume in a heterogeneous aquifer.” Water Resour. Res., 29(12), 4053–4061.
13.
Feynman, R. P. ( 1951). “An operator calculus having applications in quantum electrodynamics.” Physical Rev., 84, 108–128.
14.
Freeze, R. A. ( 1975). “A stochastic-conceptual analysis of one-dimensional groundwater flow in nonuniform homogeneous media.” Water Resour. Res., 11, 725–741.
15.
Freyberg, D. L. ( 1986). “A natural gradient experiment on solute transport in a sand aquifer, 2. Spatial moments and the advection and dispersion of nonreactive tracers.” Water Resour. Res., 22, 2031–2046.
16.
Gardiner, C. W. ( 1985). Handbook of stochastic methods, Springer, New York.
17.
Gelhar, L. W., and Axness, C. L. ( 1983). “Three-dimensional stochastic analysis of macrodispersion in aquifers.” Water Resour. Res., 19, 161–180.
18.
Ginn, T. R., Simmons, C. S., and Wood, B. D. ( 1995). “Stochastic-convective transport with nonlinear reaction: Biodegradation and microbial growth.” Water Resour. Res., 31, 2689–2700.
19.
Graham, W., and McLaughlin, D. ( 1989a). “Stochatic analysis of nonstationary subsurface solute transport, 1. Unconditional moments.” Water Resour. Res., 25, 215–232.
20.
Graham, W., and McLaughlin, D. ( 1989b). “Stochastic analysis of nonstationary subsurface solute transport 2. Conditional moments.” Water Resour. Res., 25, 2331–2355.
21.
Hu, B. X., Deng, F. W., and Cushman, J. H. ( 1995). “Nonlocal reactive transport with physical and chemical heterogeneity; Linear nonequilibrium sorption with random Kd.” Water Resour. Res., 31(9), 2239–2252.
22.
Hu, B. X., Cushman, J. H., and Deng, F. W. ( 1997). “Nonlocal reactive transport with physical, chemical and biological heterogeneity.” Adv. in Water Resour., 20, 293–308.
23.
Kabala, Z. J., and Sposito, G. ( 1991). “A stochastic model of reactive solute transport with time-varying velocity in a heterogeneous aquifer.” Water Resour. Res., 27, 341–350.
24.
Kabala, Z. J., and Sposito, G. ( 1994). “Statistical moments of reactive solute concentration in a heterogeneous aquifer.” Water Resour. Res. 30, 759–768.
25.
Kapoor, V., and Gelhar, L. W. ( 1994). “Transport in three-dimensionally heterogeneous aquifers, 1. Dynamics of concentration fluctuations.” Water Resour. Res., 30, 1775–1788.
26.
Karakas, A., and Kavvas, M. L. (2000). “Conservation equations for ground-water velocity in general conditions.”J. Hydrologic Engrg., ASCE, 5(2), 206–216.
27.
Kavvas, M. L., and Karakas, A. ( 1996). “On the stochastic theory of solute transport by unsteady and steady groundwater flow in heterogeneous aquifers.” J. Hydrol., Amsterdam, 179, 321–351.
28.
Kavvas, M. L., and Wu, J.-L. ( 2000). “Conservation equations for solute transport by unsteady and steady flows in heterogeneous aquifers: the cumulant expansion/Lie operator methodology,” Stochastic methods in subsurface contaminant hydrology, R. S. Govindaraju, ed., ASCE.
29.
Kubo, R. ( 1962). “Generalized cumulant expansion method.” J. Phys. Soc. of Japan, 117, 1100–1120.
30.
Kubo, R. ( 1963). “Stochastic Liouville equations.” J. Math. Phys., 4(2), 174–183.
31.
Lapidus, L., and Amundson, N. R. ( 1952). “Mathematics of absorption in beds VI. The effect of longitudinal diffusion in ion exchange and chromatographic columns.” J. Phys. Chem., 56, 984–988.
32.
Miralles-Wilhelm, F., and Gelhar, L. W. ( 1996). “Stochastic analysis of sorption macrokinetics in heterogeneous aquifers.” Water Resour. Res., 32(6), 1541–1549.
33.
Miralles-Wilhelm, F., Gelhar, L. W., and Kapoor, V. ( 1997). “Stochastic analysis of oxygen-limited biodegradation in three-dimensionally heterogeneous aquifers.” Water Resour. Res., 33, 1251–1263.
34.
Neuman, S. P., and Zhang, Y.-K. ( 1990). “A quasilinear theory of non-Fickian and Fickian subsurface dispersion, 1. Theoretical analysis with application to isotropic media.” Water Resour. Res., 26, 887–902.
35.
Neuman, S. P. ( 1993). “Eulerian-Lagrangian theory of transport in space-time nonstationary velocity fields: Exact nonlocal formalism by conditional moments and weak approximation.” Water Resour. Res., 29, 633–645.
36.
Olver, P. J. ( 1993). Applications of Lie groups to differential equations, Springer, New York.
37.
Quinodoz, H., and Valocchi, A. ( 1993). “Stochastic analysis of the transport of kinetically sorbing solutes in aquifers with randomly heterogeneous hydraulic conductivity.” Water Resour. Res., 29(9), 3227–3240.
38.
Rajaram, H. ( 1997). “Time and scale dependent effective retardation factors in heterogeneous aquifers.” Adv. in Water Resour., 20(4), 217–228.
39.
Rajaram, H., and Gelhar, L. W. ( 1993). “Plume scale-dependent dispersion in heterogeneous aquifers, 1. Lagrangian analysis in a stratified aquifer.” Water Resour. Res., 29, 3249–3260.
40.
Rubin, Y. ( 1991a). “Transport in heterogeneous porous media: Prediction and uncertainty.” Water Resour. Res., 27, 1723–1738.
41.
Rubin, Y. ( 1991b). “The spatial and temporal moments of tracer concentration in disordered porous media.” Water Resour. Res., 27, 2845–2854.
42.
Serrano, S. ( 1988a). “General solution to random advective-dispersive transport equation in porous media, 1. Stochasticity in the sources and in the boundaries.” Stochastic Hydrol. and Hydr., 2, 79–98.
43.
Serrano, S. ( 1988b). “General solution to random advective-dispersive transport equation in porous media, 2. Stochasticity in the parameters.” Stochastic Hydrol. and Hydr., 2, 99–112.
44.
Serrano, S. ( 1992). “The form of the dispersion equation under recharge and variable velocity, and its analytical solution.” Water Resour. Res., 28, 1801–1808.
45.
Serre, J.-P. ( 1965). Lie Algebras and Lie Groups, W. A. Benjamin, London.
46.
Simmons, C. S. ( 1982). “A stochastic-convective transport representation of dispersion in one-dimensional porous media systems.” Water Resour. Res., 18, 1193–1214.
47.
Simmons, C. S., Ginn, T. R., and Wood, B. D. ( 1995). “Stochastic-convective transport with nonlinear reaction: mathematical framework.” Water Resour. Res., 31, 2674–2688.
48.
Sposito, G., and Barry, D. A. ( 1987). “On the Dagan model of solute transport in groundwater: Foundational aspects.” Water Resour. Res., 23, 1867–1875.
49.
Sudicky, E. A. ( 1986). “A natural gradient experiment on solute transport in a sand aquifer: Spatial variability of hydraulic conductivity and its role in the dispersion process.” Water Resour. Res., 22, 2069–2082.
50.
Valiantzas, J., and Thirriot, C. ( 1990a). “Transport in heterogeneous porous formations, 1. Time-dependent convective dispersion.” J. Hydrol., Amsterdam, 118, 311–328.
51.
Valiantzas, J., and Thirriot, C. ( 1990b). “Transport in heterogeneous porous formations, 2. Time-dependent double dispersion.” J. Hydrol., Amsterdam, 329–342.
52.
Van Kampen, N. G. ( 1974). “A cumulant expansion for stochastic linear differential equations. II.” Physia, 74, 239–247.
53.
Van Kampen, N. G. ( 1976). “Stochastic differential equations.” Phys. Rep., 24, 171–228.
54.
Wood, B. D. ( 1998). “A connection between the Lagrangian stochastic-convective and cumulant expansion approaches for describing solute transport in heterogeneous porous media.” Adv. in Water Resour., 22, 319–332.
55.
Wood, B. D., and Kavvas, M. L. ( 1999). “Ensemble-averaged equations for reactive transport in porous media under unsteady flow conditions.” Water Resour. Res., 35, 2053–2068.
56.
Woodbury, A. D., and Sudicky, E. A. ( 1991). “The geostatistical characteristics of the Borden Aquifer.” Water Resour. Res., 27, 533–546.

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Go to Journal of Hydrologic Engineering
Journal of Hydrologic Engineering
Volume 6Issue 4August 2001
Pages: 341 - 350

History

Received: Sep 13, 1999
Published online: Aug 1, 2001
Published in print: Aug 2001

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Authors

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M. Levent Kavvas
Prof., Hydrologic Res. Lab., Dept. of Civ. and Envir. Engrg., Univ. of California, Davis, CA 95616.

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