Recent Progress in the Modeling of Corrosion of Structural Steel Immersed in Seawaters
Publication: Journal of Infrastructure Systems
Volume 12, Issue 3
Abstract
For coastal infrastructure the long-term durability of new steel structures and the remaining life of existing steel structures is of central interest to their proper maintenance and asset management. This is particularly the case where protective measures such as paint coatings, galvanizing, or cathodic protection will become or are already ineffective or are nonexistent. Guidelines currently available for new design and for assessment are largely empirical and have a high degree of uncertainty. To address this recent research has produced better quality models for the progression of corrosion with time. These employ fundamental characteristics of steel corrosion as obtained from actual field observations and from laboratory-based electrochemical and other observations. The models are reviewed herein and an illustrative application to a typical infrastructure component is presented. It is shown that seawater temperature has an important influence on the rate of early corrosion and also has longer-term effects not predicted by short-term observations. Also, the influence on corrosion of small changes in metal composition and in water velocity, salinity, and pollution are described.
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Acknowledgment
The work reported herein is part of an ongoing project on structural reliability assessment of deteriorating structures supported by the Australian Research Council.
References
Blekkenhorst, F., Ferrari, G. M., van der Wekken, C. J., and IJsseling, F. P. (1986). “Development of high strength low alloy steels for marine applications. Part I: Results of long term exposure tests on commercially available and experimental steels.” Br. Corros. J., London, 21(3), 163–176.
Buzovkina, T. B., Aleksandrov, V. A., Loginov, V. B., Egorov, E. S., and Yurchenko, A. A. (1990). “Effect of the alkalinity of water and carbonates on the initial stages of steel corrosion in the Sea of Japan and the Black Sea.” Prot. Met., 26(4), 510–512.
Chernov, B. B., and Il'in, A. K. (1987). “Corrosion of metals in the tropical zone in the Indian Ocean.” Prot. Met., 23(1), 94–96.
Edyvean, R. G. J. (1990). “The effects of microbiologically generated hydrogen sulfide in marine corrosion.” Mar. Technol. Soc. J., 24(33) 5–9.
Evans, U. R., (1960). The corrosion and oxidation of metals: Scientific principles and practical applications, Edward Arnold, London.
Forgeson, B. W., Southwell, C. R., and Alexander, A. L. (1960). “Corrosion of metals in tropical environments. Part III: Underwater corrosion of ten structural steels.” Corrosion (Houston), 16(3), 87–96.
Hamilton, A. W. (1994). “Biocorrosion: The action of sulphate reducing bacteria.” Biochemistry of microbial degradation, C. Ratledge, ed., Kluwer Academic, Dordrecht, The Netherlands, 555–570.
Jeffrey, R., and Melchers, R. E. (2002). “Shape and size effects for marine immersion coupons.” Br. Corros. J., London, 37(2), 99–104.
Jones, D. (1996). Principles and prevention of corrosion, 2nd Ed., Prentice–Hall, Upper Saddle River, N.J.
LaQue, F. L. (1948). “Behavior of metals and alloys in sea water.” The corrosion handbook, H. H. Uhlig, ed., Wiley, New York, 391.
Lebedev, A. N., and Derbyshev, A. S. (1978). “Kinetics of carbon steelcorrosion in Caspian Seawaters and chloride solutions.” Prot. Met., 14(6), 575–577.
Little, B. J., Ray, R. I., and Pope, R. K. (2000). “Relationship between corrosion and the biological sulfur cycle: A review.” Corrosion (Houston), 56(4), 433–443.
Melchers, R. E. (2002). “Effect of temperature on the marine immersion corrosion of carbon steels.” Corrosion (Houston), 58(9), 768–782.
Melchers, R. E. (2003a). “A probabilistic model for marine corrosion of steel for structural reliability assessment.” J. Struct. Eng., 129(11), 1484–1493.
Melchers, R. E. (2003b). “Effect on marine immersion corrosion of carbon content of low alloy steels.” Corros. Sci., 45(11), 2609–2625.
Melchers, R. E. (2003c). “Mathematical modelling of the diffusion controlled phase in marine immersion corrosion of mild steel.” Corros. Sci., 45(5), 923–940.
Melchers, R. E. (2003d). “Modelling of marine immersion corrosion for copper-bearing steels.” Corros. Sci., 45(10), 2307–2323.
Melchers, R. E. (2003e). “Modeling of marine immersion corrosion for mild and low alloy steels. Part I: Phenomenological model.” Corrosion (Houston), 59(4), 319–334.
Melchers, R. E. (2003f). “Modeling of marine immersion corrosion for mild and low alloy steels. Part II: Uncertainty estimation.” Corrosion (Houston), 59(4), 335–344.
Melchers, R. E. (2003g). “Probabilistic models for corrosion in structural reliability assessment. Part I: Empirical models.” J. Offshore Mech. Arct. Eng., 125(4), 264–271.
Melchers, R. E. (2003h). “Probabilistic models for corrosion in structural reliability assessment. Part II: Models based on mechanics.” J. Offshore Mech. Arct. Eng., 125(4), 272–280.
Melchers, R. E. (2004). “Effect of small compositional changes on marine immersion corrosion of low alloy steel.” Corros. Sci., 46(7), 1669–1691.
Melchers, R. E., and Jeffrey, R. (2004). “Influence of water velocity on marine corrosion of mild steel.” Corrosion (Houston), 60(1), 84–94.
Melchers, R. E., and Jeffrey, R. (2005). “Early corrosion of mild steel in seawater.” Corros. Sci., 47(7), 1678–1693.
Melchers, R. E., and Wells, P. A. (2005). “Models for the anaerobic phases of marine immersion corrosion.” Corros. Sci., 48(7), 1791–1811.
Mercer, A. D., and Lumbard, E. A. (1995). “Corrosion of mild steel in water.” Br. Corros. J., London, 30(1), 43–55.
Peng, C.-G., and Park, J. K. (1994). “Principal factors affecting microbiologically influenced corrosion of carbon steel.” Corrosion (Houston), 50(9) 669–675.
Peterson, M. H. and Lennox, T. J., Jr. (1984). The effects of exposure conditions on the corrosion of mild steel, copper, and zinc in seawater. Materials Performance, 23(3), 15–18.
Peterson, M. H., and Waldron, L. J. (1961). “Investigation of mild steel corrosion rate in San Diego harbor.” Corrosion (Houston), 17(4), 112–114.
Phull, B. S., Pikul, S. J., and Kain, R. M. (1997). “Seawater corrosivity around the world—Results from five years of testing.” Corrosion testing in natural waters, STP 1300, R. M. Kain and W. T. Young, eds., Vol. 2, ASTM, Philadelphia.
Schultze, W. A., and van der Wekken, C J. (1976). “Influence of alloying elements on the marine corrosion of low alloy steels determined by statistical analysis of published literature data.” Br. Corros. J., London, 11(1), 18–24.
Southwell, C. R., Bultman, J. D., and Hummer, C. W. (1979). “Estimating service life of steel in seawater.” Seawater corrosion handbook, M. Schumacher, ed., Noyes Data Corp., Park Ridge, N.J., 374–387.
Svedrup, H. U., Johnson, M. W., and Fleming, R. H. (1942). The oceans: Their physics, chemistry and general biology, McGraw–Hill, New York.
Uhlig, H. H. (1963). Corrosion and corrosion control, Wiley, New York.
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© 2006 ASCE.
History
Received: Jun 11, 2004
Accepted: Apr 19, 2006
Published online: Sep 1, 2006
Published in print: Sep 2006
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