Resistance of Scoria-Based Blended Cement Concrete against Deterioration and Corrosion in Mixed Sulfate Environment
Publication: Journal of Materials in Civil Engineering
Volume 21, Issue 7
Abstract
The use of blended cements incorporating supplementary cementing materials and cements with low content is becoming common to prevent the deterioration of concrete structures subjected to aggressive environments. This paper presents the results of an investigation on the performance of finely ground volcanic scoria (VS)-based ASTM Type I and Type V (low ) blended cement concrete mixtures with varying immersion periods of up to in environments characterized by the presence of mixed magnesium–sodium sulfates. The concrete mixtures comprise a combination of two Portland cements (Types I and V) and two VS-based blended cements with two water-to-binder ratio of 0.35 and 0.45. Background experiments (in addition to strength and fresh properties) including X-ray diffraction (XRD), differential scanning calorimetry (DSC), mercury intrusion porosimetry (MIP), and rapid chloride permeability (RCP) were conducted on all concrete mixtures to determine phase composition, pozzolanic activity, porosity, and chloride ion resistance. Deterioration of concrete due to mixed sulfate attack and corrosion of reinforcing steel were evaluated by assessing concrete weight loss and measuring corrosion potentials and polarization resistance at periodic intervals throughout the immersion period of . Plain (Type I/V) cement concretes, irrespective of their content, performed better in terms of deterioration and corrosion resistance compared to Type I/V VS-based blended cement concrete mixtures in mixed sulfate environment.
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Acknowledgments
The writer is grateful to the Papua New Guinea (PNG) Halla Cement Factory, PNG Department of Works, Gazella Restoration Authority of Rabaul (PNG), and PNG Ready Mixed Concrete Co. Ltd. for their support.
References
Al-Amoudi, O. S. B. (1995). “Performance of 15 reinforced concrete mixtures in magnesium sulphate environments.” Constr. Build. Mater., 9(3), 149–158.
Al-Amoudi, O. S. B. (1998). “Sulfate attack and reinforcement corrosion in plain and blended cements exposed to sulfate environments.” Build. Environ., 33(1), 53–61.
Al-Amoudi, O. S. B. (2002). “Attack on plain and blended cements exposed to aggressive sulfate environments.” Cem. Concr. Compos., 24(3–4), 305–316.
Al-Amoudi, O. S. B., Abduljauwad, S. N., Rasheeduzzafar, F. A., and Maslehuddin, R. M. (1992). “Effect of chloride and sulfate contamination in soils on corrosion of steel and concrete.” Transportation Research Record. 1345, Transportation Research Board, Washington, D.C., 67–73.
Al-Amoudi, O. S. B., Maslehuddin, R. M., and Abduljauwad, S. N. (1994). “Influence of chloride ions on sulphate deterioration in plain and blended cements.” Mag. Concrete Res., 46(167), 113–123.
American Concrete Institute (ACI) Committee 201. (1991). “Proposed revision of: Guide to durable concrete.” ACI Mater. J., 88(2), 544–582.
Andrade, C., Castelo, V., Alonso, C., and Gonzalez, J. A. (1986). “The determination of corrosion rate of steel embedded in concrete by the polarization resistance and AC impedence methods.” Proc. ASTM STP 906, ASTM, Philadelphia, 43–63.
Bonen, D. A. (1993). “A microstructural study of the effect produced by magnesium sulfate on plain and silica fume–bearing Portland cement mortars.” Cem. Concr. Res., 23(3), 541–553.
Broomfield, J. P., Langford, P. E., and Ewins, A. J. (1990). “Corrosion rates of steel in concrete.” Proc., ASTM STP 1065, N. S. Berke, V. Chaker, and D. Whiting, eds., Philadelphia, 157.
Cohen, M. D., and Bentur, A. (1988). “Durability of Portland silica fume pastes in magnesium and sodium sulfate solutions.” ACI Mater. J., 85(3), 148–157.
Cohen, M. D., and Mather, B. (1991). “Sulphate attack on concrete—Research needs.” ACI Mater. J., 88(1), 62–69.
Frigione, G., and Sersale, R. (1989). “The action of some aggressive solutions on portland, pozzolanic and blast furnace slag cement mortars.” Cem. Concr. Res., 19(6), 885–893.
Gjorv, O. E., and Vennesland, O. (1979). “Diffusion of chloride ions from sea water concrete.” Cem. Concr. Res., 9(2), 229–238.
Hossain, K. M. A. (2004). “Properties of volcanic scoria based lightweight concrete.” Cem. Concr. Compos., 56(2), 111–120.
Hossain, K. M. A. (2005). “Chloride induced corrosion of reinforcement in volcanic ash and pumice based blended concrete.” Cem. Concr. Compos., 27(3), 381–390.
Hossain, K. M. A. (2006). “Blended cement and lightweight concrete using scoria: mix design, strength, durability and heat insulation characteristics.” Int. J. of Physical Sciences (IJPS), 1(1), 5–16.
Irassar, E. F., González, M., and Rahhal, V. (2000). “Sulphate resistance of Type V cements with limestone filler and natural pozzolana.” Cem. Concr. Compos., 22(5), 361–368.
Kalousek, G. L., Porter, L. C., and Benton, E. J. (1972). “Concrete for long-time service in sulfate environment.” Cem. Concr. Res., 2(1), 79–89.
Kostmatka, S. H., Kerkhoff, B., Panarese, W. C., Macleod, N. F., and McGrath, R. J. (2002). “Design and control of concrete mixtures.” Engineering Bulletin 101, 7th Canadian Ed., Cement Association of Canada, Ottawa.
Lawrence, C. D. (1990). “Sulphate attack on concrete.” Mag. Concrete Res., 42(153), 249–264.
Mangat, P. S., and El-Khatib, J. M. (1992). “Influence of initial curing on sulphate resistance of blended cement concrete.” Cem. Concr. Res., 22(6), 1089–1100.
Mather, M. (1968). “Field and laboratory studies of the sulphate resistance of concrete.” Performance of concrete, E. G. Swenson, ed., University of Toronto Press, Toronto, 66–76.
Mehta, P. K. (1973). “Mechanisms of expansion associated with ettringite formation.” Cem. Concr. Res., 3(1), 1–6.
Mehta, P. K. (1981). “Effect of cement composition on corrosion of reinforcing steel in concrete: Chloride corrosion of steel in concrete.” ASTM STP 629, Philadelphia, 12–19.
Mehta, P. K. (1993). “Sulfate attack on concrete: A critical review.” Materials science of concrete, Vol. III, American Ceramic Society, Westerville, Ohio, 105–130.
Montemor, M. F., Simoes, A. M. P., and Salta, M. M. (2000). “Effect of fly ash on concrete reinforcement corrosion studied by EIS.” Cem. Concr. Compos., 22(2), 175–185.
Neville, A. (1969). “Behaviour of concrete in saturated and weak solutions of magnesium sulphate or calcium chloride.” J. Mater., 4(4), 781–816.
Neville, A. (2004). “The confused world of sulfate attack on concrete.” Cem. Concr. Res., 34(8), 1275–1296.
Rasheeduzzafar, Al-Amoudi, O. S. B., Abduljauwad, S. N., and Maslehuddin, M. (1994). “Magnesium–sodium sulfate attack in plain and blended cements.” J. Mater. Civ. Eng., 6(2), 201–222.
Rasheeduzzafar, Al-Gahtani, A. S., Al-Saadoun, S. S., and Bader, M. A. (1990). “Influence of cement composition on the corrosion of reinforcement and sulfate resistance of concrete.” ACI Mater. J., 87(2), 114–122.
Santhanam, M., Cohen, M. D., and Olek, J. (2003). “Effects of gypsum formation on the performance of cement mortars during external sulfate attack.” Cem. Concr. Res., 33(3), 325–332.
Taylor, H. F. W. (1999). “Discussion on ‘Sulfate attack mechanisms.’” Materials science of concrete, Special Vol., American Ceramic Society, Ohio, 33–34.
Tian, B., and Cohen, M. D. (2000). “Does gypsum formation during sulfate attack on concrete lead to expansion?” Cem. Concr. Res., 30(1), 117–123.
Washburn, E. W. (1921). “Note on a method of determining the distribution of pore sizes in a porous materials.” Proc. Natl. Acad. Sci. U.S.A., 7, 115–116.
Wong, G., and Poole, T. (1987). “Effect of pozzolans and slags on the sulfate resistance of hydraulic cement mortars.” Concrete durability, ACI SP-100, ACI, Detroit, 100–109.
Young, J. F., Mindess, S., Gray, R. J., and Bentur, A. (1998). The science and technology of civil engineering materials, Prentice-Hall, Upper Saddle River, N.J.
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© 2009 ASCE.
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Received: Oct 17, 2006
Accepted: Jan 22, 2009
Published online: Jun 15, 2009
Published in print: Jul 2009
Notes
Note. Associate Editor: Zhishen Wu
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