TECHNICAL NOTES
Oct 15, 2009

Characterization of Calcium Carbonate, Calcium Oxide, and Calcium Hydroxide as Starting Point to the Improvement of Lime for Their Use in Construction

Publication: Journal of Materials in Civil Engineering
Volume 21, Issue 11

Abstract

In this paper a complete characterization of lime cycle transitions is described. CaCO3 was collected from a Mexican mine and was processed to obtain Ca(OH)2 through CaO. When the calcium hydroxide interacted with the CO2 in the air forming CaCO3 , the lime cycle was completed. Crystal structure and spectroscopy characterization was carried out to get the knowledge of lime cycle CaCO3CaOCa(OH)2CaCO3 deeply. The changes in the crystalline structures were described using X-ray diffraction by powder to accomplish phase identification. Scanning electron microscopy was done to examine the morphology, topology, crystal structure, and crystalline growth habit. Dynamic light scattering was used to determine the particle-size distribution of Ca(OH)2 . Fourier-transform infrared was done to identify molecules and atomic bonds. Finally, inductively coupled plasma-mass spectrometry was done to get quantitative analyses. These results are a contribution to the restoration and construction industry fields, as well as a starting point to new possible applications of lime in current engineering.

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Acknowledgments

This work was developed with the generous collaboration of several people and organizations, technical support—Carolina Muñoz, Alicia del Real, Ofelia Pérez, Genoveva Hernandez—along with the support of CoSDAC-SEP (Project No. UNSPECIFIED022.09-P03), and FIFI-UAQ to whom we express our sincere gratefulness.

References

Boynton, R. S. (1980). Chemistry and technology of lime and limestone, Wiley, New York.
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Galván-Ruiz, M., Baños, L., and Rodríguez-García, M. E. (2007). Lime characterization as a food additive.” Sens. & Instrumen. Food Qual., 1, 169–175.
Galván-Ruiz, M., Velázquez-Castillo, R., Pérez-Lara, M., Arjona, J. L., Baños, L., and Rodríguez-García, M. E. (2009). “Chemical and physical characterization of stuccos from a Mexican colonial building: El Museo del Calendario of Querétaro.” Archaeometry, Published Online: Feb. 2, 2009.
Hill, N., Holmes, S., and Mather, D. (1992). Lime and other alternative cements, Intermediate Technology Publications, U.K.
Holmes, S., and Wingate, M. (2003). Building with lime, ITDG Publishing, U.K.
Park, J., Min, D., and Song, H. (2002). “Structural investigation of CaO–Al2O3 and CaO–Al2O3–CaF2 slags via Fourier transform infrared spectra.” ISIJ Int., 42(1), 38–43.

Information & Authors

Information

Published In

Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 21Issue 11November 2009
Pages: 694 - 698

History

Received: Mar 19, 2007
Accepted: Apr 21, 2009
Published online: Oct 15, 2009
Published in print: Nov 2009

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Notes

Note. Associate Editor: Carl Liu

Authors

Affiliations

Miguel Galván-Ruiz [email protected]
Associate Professor, División de investigación y Posgrado, Facultad de Ingeniería, Universidad Autónoma de Querétaro, Centro Universitario Cerro de las Campanas s/n 76010, Querétaro, Mexico. E-mail: [email protected]
Juan Hernández [email protected]
Associate Professor, CETIS 105-SEP, carr. a Tlacote s/n, Querétaro, Qro. 76148, Mexico. E-mail: [email protected]
Leticia Baños [email protected]
Associate Researcher, Instituto de Investigaciones en Materiales, Universidad Nacional Autónoma de México, Ciudad Universitaria, C.P. 04510, Mexico. E-mail: [email protected]
Joaquín Noriega-Montes [email protected]
Associate Professor, División de Investigación y Posgrado, Facultad de Ingeniería, Universidad Autónoma de Querétaro, Centro Universitario Cerro de las Campanas s/n 76010, Querétaro, Mexico. E-mail: [email protected]
Mario E. Rodríguez-García [email protected]
Professor, Departamento de Nanotecnología, Centro de Física Aplicada y Tecnología Avanzada, Universidad Nacional Autónoma de México Campus Juriquilla, Querétaro, A. P. 1-1010, C.P. 76000, Mexico (corresponding author). E-mail: [email protected]

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