Corrosion of Glasses and Expansion Mechanism of Concrete Containing Waste Glasses as Aggregates
Publication: Journal of Materials in Civil Engineering
Volume 21, Issue 10
Abstract
Expansion and cracking of portland cement concrete containing glass aggregates have been known for decades. Traditional alkali-silica reaction and expansion mechanisms are being used to explain the reaction and expansion mechanisms of cement concrete containing glass aggregates. This paper reviews glass chemistry, alkali-silica reaction mechanism, expansion of concrete containing glass aggregates, and microstructure of the interfacial transitional zone between cement paste and glass particles. Analysis of these published results indicates that the formation of expansive sodium-calcium silicate hydrate (N-C-S-H) gel around glass particles in concrete results from the dissolution and precipitation of soda-lime glass in high pH environments and not from the reaction between glass particles and the alkalis in cement. The corrosion of soda-lime glass and formation of N-C-S-H can happen when the pH of the pore solution is greater than 12 regardless of the presence of alkali ions. Thus, the expansion of concrete containing glass aggregates is different from that caused by traditional alkali-silica reaction. The presence of moisture and high pH are the two necessary conditions for concrete containing glass aggregates to expand.
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References
Bazant, Z. P., Zi, G., and Meyer, C. (2000). “Fracture mechanics of ASR in concretes with waste glass particles of different sizes.” J. Eng. Mech., 126(3), 226–232.
Beaudoin, J. J., and Brown, P. W. (1992). “The structure of hardened cement paste.” Proc., 9th Int. Congress on the Chemistry of Cement, Vol. 1, National Council for Cement and Building Materials, New Delhi, India, 485–525.
Berube, M. A., and Fournier, B. (2004). “Alkalis releasable by aggregates in concrete—Significance and test methods.” Proc., 12th Int. Conf. on Alkali-Aggregate Reaction in Concrete, International Academic Publishers, Beijing, 17–30.
Byars, E. A., Morales-Hernandez, B., and Zhu, H. Y. (2004). “Waste glass as concrete aggregate and pozzolan.” Concrete, 38(1), 41–44.
Chesner, W. H. (1992). “Waste glass and sludge for use in asphalt pavement.” Utilization of waste materials in civil engineering construction, H. Inyang and K. Bergeson, eds., ASCE, New York, 296–307.
Chesner, W. H., Collins, R. J. and MacKay, M. H. (1997). “User guidelines for waste and by-product materials in pavement construction.” FHWA-RD-97-148, U.S. DOT, Federal Highway Administration, Washington, D.C.
Diamond, S. (1989). “ASR—Another look at mechanisms.” Proc., 8th Int. Conf. on Alkali-Aggregate Reaction in Concrete, Elsevier Applied Science, Kyoto, Japan, 83–93.
Diamond, S. (2000). “Chemistry and other characteristics of ASR gels.” Proc., 11th Int. Conf. on Alkali-Aggregate Reaction in Concrete, Québec City, 31–40.
Din, Z. (1979). The physical chemistry of silicates, Chinese Construction Industry (in Chinese).
Etris, C. D. (1974). “Waste glass as coarse aggregate for concrete.” J. Test. Eval., 2(5), 344–350.
Figg, J. W. (1981). “Reaction between cement and artificial glass in concrete.” Proc., Conf. on Alkali-Aggregate Reaction in Concrete, National Building Research Institute, Cape Town, South Africa, 19.
Hansen, W. C. (1944). “Studies relating to the mechanism by which alkali-aggregate reaction produces expansion in concrete.” Proc. Am. Soc. Civ. Eng., 66, 1781–1811.
Jin, C., Meyer, C., and Baxter, S. (2000). “‘Glascrete’—Concrete with glass aggregate.” ACI Mater. J., 97, 208–213.
McLellan, G. W., and Shand, E. B. (1984). Glass engineering handbook, McGraw-Hill, New York.
Meyer, C., and Baxter, S. (1997). “Use of recycled glass for concrete masonry blocks.” Final Rep. No. 97-15, New York State Energy Research and Development Authority, Albany, New York.
Meyer, C., and Baxter, S. (1998). “Use of recycled glass and fly ash for precast concrete.” Rep. No. NYSERDA 98-18 (4292-IABR-IA-96), New York State Energy Research and Development Authority, Dept. of Civil Engrg. and Engrg. Mech., Columbia Univ., New York.
Meyer, C., Baxter, S., and Jin, W. (1996). “Alkali-aggregate reaction in concrete with waste glass as aggregate.” Proc., 4th Materials Engineering Conf.: Materials for the new millennium, ASCE, Reston, Va., 1388–1397.
Park, S.-B., and Lee, B. -C. (2004). “Studies on expansion properties in mortar containing waste glass and fibers.” Cem. Concr. Res., 34, 1145–1152.
Phillips, J. C., Cahn, D. S., and Keller, G. W. (1972). “Refuse glass aggregate in portland cement.” Proc., 5th Mineral Waste Utilization Symp., IIT Research Institute, Chicago, 385–390.
Pike, R. G., Hubbard, D., and Newman, E. S. (1960). “Binary silicate glasses in the study of alkali-aggregate reaction.” Highway Research Board Bulletin, 275, 39–44.
Pollery, C., Cramer, S. M., and De La Cruz, R. V. (1998). “Potential for using waste glass in portland cement concrete.” J. Mater. Civ. Eng., 10(4), 210–219.
Prezzi, M., Monteiro, P. J. M., and Sposito, G. (1997). “The alkali-silica reaction. Part I: Use of the double-layer theory to explain the behavior of reaction product gels.” ACI Mater. J., 94(1), 10–17.
Regourd-Moranville, M. (1989). “Products of reaction and petrographic examination.” Proc., 8th Int. Conf. on Alkali-Aggregate Reaction in Concrete, Elsevier Applied Science, Kyoto, Japan, 445–456.
Schmidt, A., and Saia, W. H. F. (1963). “Alkali-aggregate reaction tests on glass used for exposed aggregate wall panel work.” ACI Mater. J., 60, 1235–1236.
Shao, Y., Lefort, T., Moras, S., and Rodriguez, D. (2000). “Studies on concrete containing ground waste glasses.” Cem. Concr. Res., 30(1), 91–100.
Shayan, A., and Xu, A. (2004). “Value-added utilisation of waste glass in concrete.” Cem. Concr. Res., 34, 81–89.
Shi, C., and Day, R. L. (1996). “Selectivity of alkaline activators for the activation of slags. Cement.” Cem., Concr., Aggregates, 18(1), 8–14.
Shi, C., Wu, Y., Riefler, C., and Wang, H. (2005). “Characteristics and pozzolanic reactivity of glass powders.” Cem. Concr. Res., 35, 987–993.
Shi, C., Wu, Y., Shao, Y., and Riefler, C. (2004). “Alkali-aggregate reaction expansion of mortars containing glass powders.” Proc., 12th Int. Conf. on Alkali-Aggregate Reaction in Concrete, M. Tang and M. Deng, eds., International Academic Publishers, Beijing, 789–795.
Tang M., and Han, S. (1981). “Effect of on alkali-silica reaction.” J. Chin. Ceram. Soc., 9(2), 160–166.
Tang, M., Xu, Z., and Han, S. (1987). “Alkali-reactivity of glass aggregate.” Durability Build. Mater., 4(4), 377–385.
Topcu, I. B., and Canbaz, M. (2004). “Properties of concrete containing waste glass.” Cem. Concr. Res., 34, 267–274.
Zachariasen, W. H. (1932). “The atomic arrangement in glass.” J. Am. Chem. Soc., 54, 3841–3851.
Zhang, X., and Groves, G. W. (1990). “The Alkali-silica reaction in OPC/silica glass mortar with particular reference to pessimum effects.” Adv. Cem. Res., 3(9), 9–13.
Zhu, H., and Byars, E. A. (2004). “Alkali-silica reaction of recycled glass in concrete, alkali-aggregate reaction in concrete.” Proc., 12th Int. Conf. on Alkali-Aggregate Reaction in Concrete, International Academic Publishers, Beijing, 811–820.
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© 2009 ASCE.
History
Received: Dec 30, 2004
Accepted: Mar 26, 2009
Published online: Sep 15, 2009
Published in print: Oct 2009
Notes
Note. Associate Editor: Jason Weiss
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