TECHNICAL PAPERS
Aug 1, 2007

Characterization of Aggregate Surface Energy Using the Universal Sorption Device

Publication: Journal of Materials in Civil Engineering
Volume 19, Issue 8

Abstract

Moisture damage in asphalt concrete pavements is a major cause for high maintenance costs of state and federal highways. Moisture damage in asphalt concrete is largely due to loss of adhesion between bitumen and aggregate, and loss of cohesive strength in the mastic (bitumen and mineral filler). Surface energy components of bitumen and aggregate are used to calculate their interfacial bond strength and effectively quantify moisture susceptibility of asphalt concrete mixes. This technology has several advantages over conventional mechanical tests currently being used to identify moisture susceptible mixes. However, accurate surface energy characterization of bitumen and aggregate is the key element to calculate interfacial bond strengths. This paper presents development of a sorption based method to measure specific surface area and surface energy components of aggregate. Measured surface energy components and precision statements are presented for five aggregates. The paper also illustrates application of bond strengths calculated from surface energy components of aggregate and bitumen in the selection process of compatible pairs of aggregate and bitumen to produce a durable mix.

Get full access to this article

View all available purchase options and get full access to this article.

References

Adamson, A. W., and Gast, A. P. (1997). Physical chemistry of surfaces, Wiley, New York.
Bhasin, A. (2006). “Development of methods to quantify bitumen-aggregate adhesion and loss of adhesion due to water.” Ph.D. dissertation at Texas A&M Univ., College Station, Tex.
Bhasin, A., Chowdhury, A., and Button, J. W. (2004). “Evaluation of selected laboratory procedures and development of databases for HMA.” Final Rep. No. FHWA/TX-05/0-4203-1, Texas Transportation Institute.
Bilinski, B., and Chibowski, E. (1983). “The determination of the dispersion and polar free energy of quartz by the elution gaschromatography method.” Powder Technol., 35(1), 39–45.
Bilinski, B., and Holysz, L. (1999). “Some theoretical and experimental limitations in the determination of surface free energy of siliceous solids.” Powder Technol., 102(2), 120–126.
Chen, C. H., and Dural, N. H. (2002). “Chloroform adsorption on soil.” J. Chem. Eng. Data, 47(5), 1110–1115.
Cheng, D. (2002). “Surface free energy of asphalt-aggregate systems and performance analysis of asphalt concrete based on surface free energy.” Ph.D. dissertation at Texas A&M Univ., College Station, Tex.
Della Volpe, C., and Siboni, S. (1997). “Some reflections on acid-base solid surface free energy theories.” J. Colloid Interface Sci., 195(1), 121–136.
Della Volpe, C., and Siboni, S. (2000). “Acid base surface free energies of solids and the definition of scales in the Good van Oss Chaudhury theory.” J. Adhes. Sci. Technol., 14(2), 235–272.
Douillard, J. M., Zoungrana, T., and Partyka, S. (1995). “Surface Gibbs free energy of minerals: Some values.” J. Pet. Sci. Eng., 14(1), 51–57.
Gregg, S. J., and Sing, K. S. W. (1967). Adsorption, surface area and porosity, Academic, New York.
Harkins, W. D., and Jura, G. A. (1944). “A vapor adsorption method for the determination of the area of a solid without the assumption of a molecular area, and the areas occupied by nitrogen.” J. Am. Chem. Soc., 66(8), 1366–1373.
Jura, G., and Harkins, W. D. (1944). “Surfaces of solids XI. Determination of the decrease of free surface energy of a solid by an adsorbed film.” J. Am. Chem. Soc., 66(8), 1356–1361.
Kim, Y. R., and Little, D. N. (2003). “Development of specification type tests to assess damage and healing properties of bitumens and mastics.” FHWA/473630, Federal Highway Administration, Washington, D.C.
Ku, H. (1966). “Notes on the use of propagation of error formulas.” J. Res. Natl. Bur. Stand., Sect. C, 70C(4), 263–273.
Li, W. (2002). “Evaluation of the surface energy of aggregate using the cahn balance.” Final Rep. Cahn Balance Thermogravimetry Gas Adsorption Experiments, Chemical Engineering Dept., Texas A&M Univ., College Station, Tex.
Little, D. N., and Bhasin, A. (2006). “Using surface energy measurements to select materials for asphalt pavements.” NCHRP Project No. 9-37, Draft Final Report (submitted to NCHRP), Texas Transportation Institute, College Station, Tex.
Little, D. N., Bhasin, A., and Hefer, A. W. (2004). “Using surface energy measurements to select materials for asphalt pavements.” NCHRP Project No. 9-37, July Quarterly Report, Texas Transportation Institute, College Station, Tex.
Majidzadra, K., and Brovold, F. N. (1968). “State of the art: Effect of water on bitumen-aggregate mixtures.” Special Rep., Highway Research Board, Washington, D.C.
McClellan, A. L., and Harnsberger, H. F. (1967). “Cross-sectional areas of molecules adsorbed on solid surfaces.” J. Colloid Interface Sci., 23, 577–599.
Pitzer, K. S., and Brewer, L. (1961). Thermodynamics, McGraw-Hill, New York.
Press, W. H., Flannery, B. P., Teukolsky, S. A., and Vetterling, W. T. (1982). Numerical recipes, Cambridge University Press, Cambridge, Mass., 19–57 and 498–520.
Van Oss, C. J., Good, R. J., and Chaudhury, M. K. (1988). “Additive and nonadditive surface tension components and interpretation of contact angles.” Langmuir, 4(4), 884–891.
Western Research Institute. (2001). “Fundamental properties of asphalts and modified asphalts. Volume I: Interpretive report.” FHWA-RD-99–212, Federal Highway Administration, Washington, D.C.

Information & Authors

Information

Published In

Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 19Issue 8August 2007
Pages: 634 - 641

History

Received: Sep 21, 2005
Accepted: Mar 14, 2006
Published online: Aug 1, 2007
Published in print: Aug 2007

Permissions

Request permissions for this article.

Notes

Note. Associate Editor: Shin-Che Huang

Authors

Affiliations

Amit Bhasin [email protected]
Graduate Research Assistant, Dept. of Civil Engineering, Texas A&M Univ., College Station, TX 77843-3135. E-mail: [email protected]
Dallas N. Little [email protected]
P.E.
Professor, Dept. of Civil Engineering, Texas A&M University, College Station, TX 77843-3135. E-mail: [email protected]

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

Cited by

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share