TECHNICAL PAPERS
Aug 1, 2006

Electrokinetic Nanoparticle Treatment of Hardened Cement Paste for Reduction of Permeability

Publication: Journal of Materials in Civil Engineering
Volume 18, Issue 4

Abstract

Colloidal nanoparticles were electrokinetically transported into hardened cement paste pores where they underwent chemical reactions resulting in reduced permeability. 20nm silica and 2nm alumina particles were combined with simulated pore fluids to assess precipitate production. One precipitate formed was C-S-H , the binder material native to Portland cement paste. Permeability tests were conducted to study the effect of these processes on hardened cement pastes of high water/cement ratio and of high and low alkali contents. It was observed that 5min treatments using 5V of potential applied over a span of 0.15m is sufficient to drive nanoparticles into the pore system, enabling them to react and produce precipitates. The coefficient of permeability for each paste was reduced by 1–3 orders of magnitude. These findings indicate that reactive nanoparticles can be electrokinetically inserted to reduce the permeability of hardened cement paste, even in the presence of an opposing hydraulic flow.

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References

Bakharev, T., Sanjayan, J., and Cheng, Y. (2000). “Effect of admixtures on properties of alkali-activated slag concrete.” Cem. Concr. Res., 30(9), 1367–1374.
Bazant, Z., Sener, S., and Kim, J. (1987). “Effect of cracking on drying permeability and diffusivity of concrete.” Technical Paper No. 84-M35, ACI Materials J., 84(5), 351–357.
Bockris, J. O. M., and Reddy, A. K. N. (1976). Modern electrochemistry, Vols. 1 and 2, Plenum, New York.
Brown, P. W., Shi, D., and Skalny, J. (1991). “Porosity/permeability relationships.” Materials science of concrete II, The American Ceramic Society, Westerville, Ohio, 83–109.
Burley, L. (1999). “The development of the strength index method and protocol for assessing the use of solid waste materials in concrete.” Ph.D. thesis, Univ. Illinois, Urbana-Champaign, Ill.
Carman, P. (1956). Flow of gases through porous media, Academic, New York.
Darcy, H. (1856). Determination of the law of the flow of water through sand, Les fontaines publiques de la ville de Dijon, Victor Dalmont, Paris, 590–594.
Deer, W., Howie, R., and Zussman, J. (1962). Rock forming minerals, Vol. 5, Longman, London.
Fan, Y., Yin, S., Wen, Z., and Zhong, J. (1999). “Activation of fly ash and its effects on cement properties.” Cem. Concr. Res., 29(4), 467–472.
Finney, D. (1998). Electro-osmosis dries wet areas, Cutting Edge, USA CERL, Champaign, Ill.
Garboczi, E. J. (1990). “Permeability, diffusivity, and microstructural parameters: A critical review.” Cem. Concr. Res., 20(4), 591–601.
Glasstone, S. (1946). Textbook of physical chemistry, 6th Ed., Van Nostrand, New York.
Gratwick, R. T. (1974). Dampness in buildings, Wiley, New York.
Hearn, N., Hooton, R. D., and Mills, R. H. (1994). “Pore structure and permeability.” STP 169C significance of tests and properties of concrete and concrete-making materials, Chap. 25, ASTM, West Conshohocken, Pa.
Hock, V., McInerney, M. K., and Kirstein, E. (1998). “Demonstration of electroosmotic pulse technology for groundwater intrusion control in concrete structures.” U.S. Army Facilities Engineering Applications Program, Champaign, Ill., Technical Rep. No. 98/86, 19.
Hooton, R. D. (1988). “Problems inherent in permeability measurement.” Proc., Engineering Foundation Conf. on Advances in Cement Manufacture and Use, Engineering Foundation, 143–155.
Hunter, R. J. (1992). Foundations in colloid science, Vol. 1, University Press, Belfast, Northern Ireland.
Kasselouri, V., Kouloumbi, N., and Thomopoulos, Th. (2001). “Performance of silica fume-calcium hydroxide mixture as a repair material.” Cem. Concr. Compos., 23(1), 103–110.
Lim, C., Gowripalan, N., and Sirivivatnanon, V. (2000). “Microcracking and chloride permeability of concrete under uniaxial compression.” Cem. Concr. Compos., 22(5), 353–360.
Ludirdja, D., Berger, R. L., and Young, J. F. (1989). “Simple method for measuring water permeability of concrete.” ACI Mater. J., 86(5), 433–439.
Marchand, J., Maltais, Y., Samson, E., Johansen, V., and Hazrati, K. (1998). “Modeling ionic interaction mechanisms in cement-based materials—An overview.” Proc., Sidney Diamond Symp., American Ceramic Society, Honolulu, 143–159.
Mindess, S., Young, J. F., and Darwin, D. (2003). Concrete, 2nd Ed., Prentice-Hall, Pearson, Upper Saddle River, N.J.
Otsuki, N., Hisada, M., Ryu, J., and Banshoya, E. (1999). “Rehabilitation of concrete cracks by electrodeposition.” Concr. Int., 21(3), 58–63.
Paya, J., Borrachero, M., Monzo, J., Peris-Mora, E., and Amahjour, F. (2001). “Enhanced conductivity measurement techniques of evaluation of fly ash pozzolanic activity.” Cem. Concr. Res., 31(1), 41–49.
Poon, C., Kou, S., Lam, L., and Lin, Z. (2001). “Activation of fly ash/cement systems using calcium sulfate anhydrite (CaSO4) .” Cem. Concr. Res., 31(6), 873–881.
Powers, T. C. (1960). “Physical properties of cement paste.” Proc., 4th Int. Symp. on the Chemistry of Cement, Vol. 2, Washington, D.C., Paper V-1, 577–613.
Ryu, J., and Otsuki, N. (2002). “Crack closure of reinforced concrete by electrodeposition technique.” Cem. Concr. Res., 32(1), 159–164.
Samaha, H. R., and Hover, K. C. (1992). “Influence of microcracking on the mass transport properties of concrete.” ACI Mater. J., 89(4), 416–424.
Sanchez de Rojas, M., and Frias, J. (1999). “Influence of the microsilica state on pozzolonic reaction rate.” Cem. Concr. Res., 29(6), 945–949.
Shaw, D. J. (1992). Introduction to colloid and surface chemistry, 4th Ed., Reed, Cornwall, U.K.
Shi, C., and Day, R. (2000). “Pozzolanic reaction in the presence of chemical activators. II: Reaction products and mechanism.” Cem. Concr. Res., 30(4), 607–613.
Taylor, H. F. W. (1997). Cement chemistry, 2nd Ed., Thomas Telford, London.
Uchikawa, H. (1986). “Effect of blending components on hydration and structure formation.” Theme III-Blended and Special Cements, 8th Int. Congress on the Chemistry of Cement, Vol. 1, Rio de Janeiro, Brazil, 249–280.
Vandex. (1983). “Water proofing systems.” Vandex product brochure, Stamford, Conn.
Xypex. (1983). “Concrete waterproofing by crystallization.” Data sheet 005, Richmond, B.C., Canada.
Zhang, T., Shang, S., Yin, F., Aishah, A., Salmiah, A., and Ooi, T. (2001). “Adsorptive behavior of surfactants on surface of Portland cement.” Cem. Concr. Res., 31(7), 1009–1015.

Information & Authors

Information

Published In

Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 18Issue 4August 2006
Pages: 554 - 560

History

Received: Aug 3, 2004
Accepted: Apr 19, 2005
Published online: Aug 1, 2006
Published in print: Aug 2006

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Notes

Note. Associate Editor: Hilary I. Inyang

Authors

Affiliations

Henry E. Cardenas
Assistant Professor of Mechanical Engineering, Louisiana Tech Univ., 238 Bogard Hall, 600 W. Arizona St., Ruston, LA 71272.
Leslie J. Struble
Associate Professor of Civil Engineering, Univ. of Illinois at Urbana-Champaign, 2129d Newmark Civil Engineering Laboratory, 205 North Matthews, Urbana, IL 61801.

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