TECHNICAL PAPERS
Nov 15, 2004

Accelerated Weathering of Natural Fiber-Filled Polyethylene Composites

Publication: Journal of Materials in Civil Engineering
Volume 16, Issue 6

Abstract

The resistance of natural fiber-filled high-density polyethylene composite specimens to ultraviolet- (UV) and moisture-induced degradation was evaluated by measuring changes to flexural properties. High-density polyethylene (HDPE) served as the polymer matrix for four formulations: two formulations without fiber filler and two formulations one containing wood flour and the other containing kenaf fiber, each added at 50% by weight. Specimens were exposed for 4,000 h to UV radiation and moisture cycling in a laboratory weathering device to simulate the effects of exposure to sunlight and rain. Modulus of elasticity and modulus of rupture were measured prior to and after specific exposure periods. The flexural modulus and strength decreased significantly with increasing exposure for both natural fiber-filled HDPEs, but these composites still outperformed composites without filler. To explore a practical means to predict the changes in flexural properties to observed physical changes, a two-layer elementary mechanics model consisting of a degraded surface layer and an unaffected core layer was considered. The model was only partially successful—it provided reasonable predictions of flexural strength but did not accurately predict modulus of elasticity.

Get full access to this article

View all available purchase options and get full access to this article.

References

1.
American Society for Testing and Materials (ASTM. ( 1996). “Standard test method for the flexural properties of unreinforced and reinforced plastics and electrical insulation materials.” D790-96a, West Conshohocken, Pa.
2.
Ashbee, K.H. G. ( 1993). Fundamental principals of fiber reinforced composites, Technomic, Lancaster, Pa.
3.
Dash, B., Rana, A., Mishra, H., Nayak, S., and Tripathy, S. (2000). “Novel low-cost jute-polyester composites. III. Weathering and thermal behavior.” J. Appl. Polym. Sci., 78, 1671–1679.
4.
Davis, A., and Sims, D. ( 1983). Weathering of polymers, Applied Science, London.
5.
Eckert, C. ( 2000). “Opportunities for natural fibers in plastic composites.” Proc., Progress in Woodfibre-Plastic Composite Conf., Univ. of Toronto, Toronto.
6.
Evans P. D., Thay P. D., and Schmatzl K. J. (1996). “Degradation of wood surfaces during natural weathering. Effects on lignin and cellulose and on the adhesion of acrylic latex primers.” Wood Sci. Technol., 30, 411–422.
7.
Falk, R., Felton, C., and Lundin, T. ( 2000a). “The effects of weathering on the color loss of natural fiber/thermoplastic composites.” Proc., 3rd Int. Symp. on Natural Polymers and Composites, ISNaPol, Sāo Pedro, Brazil, 382–385.
8.
Falk, R., Lundin, T., and Felton, C. ( 2000b). “The effects of weathering on wood-thermoplastic composites intended for outdoor applications.” Proc., 2nd Annual Conf. on Durability and Disaster Migration in Wood-Frame Housing, Forest Products Society, Madison, Wis., 175–179.
9.
Furneaux G., Ledbury K., and Davis A. (1981). “Photooxidation of thick polymer samples. Part I. The variation of photooxidation with depth in naturally and artificially weathered low density polyethylene.” Polym. Degrad. Stab. 3, 431–442.
10.
Gillen, K. T., Clough, R. L., and Dhooge, N. J. (1986). “Density profiling of polymers.” Polymer, 27, 225–232.
11.
Hoekstra, H. ( 1997). “The mechanical behavior of UV-degraded HDPE: Consequences for designers,” PhD thesis, Delft Univ. of Technology, Delft, The Netherlands.
12.
Hon, D. ( 2001). “Weathering and photochemistry of wood.” Wood Cell. Chem., 513–546.
13.
International Conference of Building Officials (ICBO. ( 1997). “Acceptance criteria for special roofing systems.” AC07, Whittier, Calif.
14.
Kiguchi, M., Kataoka, Y., Kaneiwa, H., Akita, K., and Evans, P. ( 2000). “Photostabilization of woodfiber-plastic composites by chemical modification of woodfibre.” Proc., 5th Pacific Rim Bio-Based Composites Symp., Canberra, Australia.
15.
Lu, J., Wu, Q., and McNabb, H. (2000). “Chemical coupling in wood fiber and polymer composites: A review of coupling agents and treatments. “Wood Fiber Sci. 32(1), 88–104.
16.
Lundin, T. ( 2002). “Effect of accelerated weathering on the physical and mechanical properties of natural fiber thermoplastic composites.” MS thesis, Univ. of Wisconsin-Madison, Madison, Wis.
17.
Matuana, L., Kamdem, D., and Zhang, J. (2001). “Photoaging and stabilization of rigid PVC/wood-fiber composites.” J. Appl. Polym. Sci., 80, 1943–1950.
18.
Murphy, J. ( 1992). “Characterization of nonlinear materials by laboratory curve fitting technique.” Internal Rep. Prepared for the USDA Forest Service, Forest Products Laboratory, Madison, Wis.
19.
Osswald, T., and Menges, G. ( 1995). Materials science of polymers for engineers, Hanser/Gardner, Cincinnati.
20.
Powell, J. (1996). “The recycled plastic lumber industry: Moving toward adulthood,” Resour. Recycl., 15(2), 20–29.
21.
Rowell, R., et al. ( 1998). “Recent advances in agro-fiber/thermoplastic composites.” Proc., 2nd Int. Symp. on Natural Polymers and Composites, Atibaia, Sāo Pedro, Brazil, 11–20.
22.
Schoolenberg, G. E., and Vink, P. (1991). “Ultra-violet degradation of polypropylene. 1. Degradation profile and thickness of the embrittled surface layer.” Polymer, 32(3), 432–437.

Information & Authors

Information

Published In

Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 16Issue 6December 2004
Pages: 547 - 555

History

Published online: Nov 15, 2004
Published in print: Dec 2004

Permissions

Request permissions for this article.

Authors

Affiliations

Thomas Lundin
Structural Designer, Stantec Consulting, 6980 Sierra Center Pkwy., Suite 100, Reno, NV 89511; formerly, Graduate Research Assistant.
Steven M. Cramer
Professor, Dept. of Civil and Environmental Engineering, Univ. of Wisconsin-Madison, 1415 Engineering Dr., Madison, WI 53706.
Robert H. Falk
Research Engineer, USDA Forest Service, Forest Products Laboratory, One Gifford Pinchot Dr., Madison, WI 53705.
Colin Felton
Technical Manager, Teel-Global Resource Technologies LLC, 426 Hitchcock St., Baraboo, WI 53913.

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

Cited by

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share