TECHNICAL NOTES
Jul 15, 2004

Crumb Rubber-Bitumen Interactions: Diffusion of Bitumen into Rubber

Publication: Journal of Materials in Civil Engineering
Volume 16, Issue 4

Abstract

A method for reusing discarded tires is to process them into crumb-sized particles for use in flexible pavement applications by incorporating crumb rubber (known as crumb rubber modifier) into asphalt mixtures. Understanding of the interaction between rubber and bitumen is an important requirement. The work reported here is the development of a test method suitable for studying the diffusion of bitumen into rubber by determining the rate of bitumen ingression into the rubber (diffusion coefficient) and the solubility of bitumen (concentration at equilibrium or the solubility coefficient). The test method developed is extension of a method employed in adhesion science. The test method has been used to obtain diffusion data of various types of bitumen and two types of rubber from discarded tires to predict the variation of the concentration of bitumen in commercially produced particles of crumb rubber modifier. No such work has been reported in the literature before.

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References

Billiter, T. C., Davison, R. R., Glover, C. J., and Bullin, J. A. (1997). “Production of asphalt-rubber binders by high-cure conditions.” Transportation Research Record 1586, Transportation Research Board, Washington, D.C., 50–56.
Brewis, D. M., Comyn, J., and Tredwell, S. T.(1987). “Diffusion of water in some modified phenolic adhesives.” Int. J. Adhes. Adhesives, 7, 30–32.
Crank, J. (1975). The mathematics of diffusion, Oxford University Press, Oxford, U.K.
Frantzis, P.(1998). “Environmental attack on adhesive joints. Part III. Mechanisms of failure.” JSME Int. J., Ser. A. 41(3), 405–415.
Gledhill, R. A., Kinloch, A. J., and Shaw, S. J.(1980). “A model for predicting joint durability.” J. Adhes., 11, 3–15.
Oliver, J. W. H.(1982). “Optimising the improvements obtained by the digestion of comminuted scrap rubbers in paving asphalts.” Proc. Association of Asphalt Paving Technologists, 51, 169–184.

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Published In

Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 16Issue 4August 2004
Pages: 387 - 390

History

Received: Nov 5, 2002
Accepted: Sep 2, 2003
Published online: Jul 15, 2004
Published in print: Aug 2004

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Authors

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Panagiotis Frantzis
Research Associate, Dept. of Civil Engineering, Univ. of Liverpool, Liverpool, UK; mailing address: Eur. Ing. Dr. P. Frantzis, Composites Technology Consultant, No. 5, 25 Sefton Park Rd., Liverpool L8 3SL, UK).

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