TECHNICAL PAPERS
Aug 1, 1994

Use of Gel‐Permeation Chromatography in Predicting Properties of Asphalt

Publication: Journal of Materials in Civil Engineering
Volume 6, Issue 3

Abstract

This paper examines the relationship between the gel permeation Chromatographic (GPC) profile and the physical properties of an asphalt cement. This problem was approached from a nontraditional perspective in that a regression‐based model for predicting GPC profiles from the physical properties of the asphalt was developed. Such a model provides an alternative way of investigating the relationship between a specific physical property and the GPC profiles of asphalts. The idea is to better understand how we can use GPC to characterize the behavior of asphalts. We used data for asphalts from a wide variety of sources in developing the regression model. The model was validated by using it to accurately predict the GPC profiles of 11 new asphalts [from the Strategic Highway Research Program (SHRP)]. The validation of the model shows that there is a strong relationship between GPC profiles and the physical properties of asphalts. This relationship is complex, however, the model clearly shows that the GPC profile is largely determined by the rheological type of the asphalt.

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References

1.
Christensen, D. W., and Anderson, D. A. (1992). “Interpretation of dynamic mechanical test data for paving grade asphalt.” Proc., Assoc. Asphalt Paving Technologists, Association of Asphalt Paving Technologists, 61.
2.
Duvall, J. J. (1993). “Size exclusion chromatography of asphalts using toluene as the mobile phase.” 72nd Annu. Meeting of Transp. Res. Board,” Transportation Research Board, Jan.
3.
Garrick, N. W., and Biskur, R. R. (1990). “A classification system for interpreting GPC profiles of asphalts.” Proc., Assoc. of Asphalt Paving Technologists, Association of Asphalt Paving Technologists, 59, 33–53.
4.
Garrick, N. W. (1992). “Modeling the effects of temperature and shear rate on the viscosity of asphalt cements.” Proc., Assoc. Asphalt Paving Technologists, Association of Asphalt Paving Technologists, 1–28.
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Glover, C. J., Bullin, J. A., Button, J. W., Davidson, R. R., Donaldson, G. R., and Hlavinka, M. W. (1987). “Characterization of asphalt using gel permeation chromatography and other methods.” Res. Rep. 419‐1F, Texas Transp. Inst., (May).
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Jennings, P. W., Pribanic, J. A., Dawson, K. R., Smith, J. A., Koontz, S., Spittler, T., and Shane, S. (1985). “Uses of high performance gel permeation chromatography for asphalt analysis.” 64th Meeting of TRB, Transportation Research Board, Washington, D.C.
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Jones, D. R. (1992). “An asphalt primer: Understanding how the origin and composition of paving‐grade asphalt cements affect their performance.” SHRP Asphalt Res. Program Tech. Memo #4. SHRP, Asphalt Res. Program.
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Price, R. P., and Burati, J. L. Jr. (1989). “A quantitative method using HP‐GPC to predict laboratory results of asphalt cement tests.” Proc. Assoc. Asphalt Paving Technologists, Association of Asphalt Paving Technologists, 58(Feb.), 182–219.

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Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 6Issue 3August 1994
Pages: 376 - 389

History

Received: Mar 2, 1993
Published online: Aug 1, 1994
Published in print: Aug 1994

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Authors

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Norman W. Garrick, Member, ASCE
Asst. Prof., Dept. of Civ. Engrg., Univ. of Connecticut, Storrs, CT 06269‐3037

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