Rebar Corrosion and Sulfate Resistance of Blast‐Furnace Slag Cement
Publication: Journal of Materials in Civil Engineering
Volume 6, Issue 2
Abstract
This study was designed to evaluate the relative corrosion and sulfate resistance of concrete made with portland cements containing 2%–14% without and with 50%, 60%, 70%, and 80% cement replacement by blast‐furnace slag (BFS). The results show that BFS blended‐cement concretes had a significantly superior corrosion‐resistance performance. The best corrosion protection was obtained with 50% BFS cement, which, depending on the content of the parent cement, showed a 3.82‐3.16 times better performance in terms of corrosion‐initiation time compared to the parent plain‐cement concrete. BFS blending was specially beneficial in improving the corrosion‐resistance performance of Type V low cements. Performance on exposure to sodium‐sulfate (N) solution, replacement level only at 70% and above, showed sulfate resistance to be better than that of the Type V sulfate‐resistant cement. BFS blending, even with high cement (9%, 11%, and 14%) at 70% and above‐replacement level, imparted a high degree of sulfate resistance. The cement with high ratio has a perceptible adverse‐interactive effect and causes sulfate deterioration even with sulfate‐resistant cements. In M‐N environment, due to the magnesium‐gypsum type of attack, the 60% BFS cement deteriorated even more severely than the plain Type V and Type I cements.
Get full access to this article
View all available purchase options and get full access to this article.
References
1.
Al‐Amoudi, O. S. B. (1992). “Studies on soil‐foundation interaction in the sabkha environment of eastern province of Saudi Arabia,” PhD thesis, King Fahd University of Petroleum and Minerals, Dhahran, Saudi Arabia.
2.
Bakker, R. F. M. (1983). “Permeability of blended cement concrete.” Fly Ash, Silica Fume, Slag, and Other Minerals By‐Products in Concrete, Rep. SP‐79, American Concrete Institute (ACI), Detroit, Mich., 589–605.
3.
Banden Bosch, V. D. (1982). “Performance of mortar specimens in chemical and accelerated marine exposure.” Perf. of Concrete, ACI Publ. SP‐65, American Concrete Institute, Detroit, Mich., 487–507.
4.
Beaton, J. L., Spellman, D. L., and Stratfull, R. F. (1967). “Corrosion of steel in continuously submerged reinforced concrete piling.” Hwy. Res. Rec. No. 204, Highway Research Board, Washington, D.C., 11–21.
5.
Bentur, A. (1976). “Effect of gypsum on the hydration and strength of pastes.” J. Am. Ceramic Soc., 59(5), 210–213.
6.
Canham, I., Page, C. L., and Nixon, P. J. (1987). “Aspects of the pore solution chemistry of blended cements related to the control of alkali silica reaction.” Cement and Concrete Res., 17(5), 839–844.
7.
Copeland, L. E., and Kantro, D. L. (1969). “Hydration of portland cement.” Proc., 5th Int. Symp. on the Chem. of Cement, Cement Assoc. of Japan, Tokyo, Japan, 2, 387–421.
8.
Ehtesham Hussain, S. (1991). “Mechanism of high durability performance of plain and blended cements,” PhD thesis, Dept. of Civ. Engrg., King Fahd University of Petroleum and Minerals, Dhahran, Saudi Arabia.
9.
Mehta, P. K. (1973). “Mechanism of expansion associated with ettringite formation.” Cement and Concrete Res., 3(1), 1–6.
10.
Radjy, F. (1973). “Discussion of ‘Identification of hydrated cement constitutes using a scanning electron microscope‐energy dispersive X‐ray spectrometer combination,’ by Sidney Diamond.” Cement and Concrete Res., 3(2), 219–221.
11.
Rasheeduzzafar (1992). “Influence of cement composition on concrete durability.” ACI Mat. J., 89(6), 574–586.
12.
Rasheeduzzafar, Al‐Saadoun, S. S., Al‐Gahtani, A. S., and Dakhil, F. H. (1990). “Effect of tricalcium aluminate content of cement on corrosion of reinforcing steel in concrete.” Cement and Concrete Res., 20(5), 723–738.
13.
Rasheeduzzafar, Dakhil, F. H., and Al‐Gahtani, A. S. (1985). “The deterioration of concrete structures in the Middle East.” Concrete Int., 7(9), 48–55.
14.
Rasheeduzzafar, Dakhil, F. H., Al‐Gahtani, A. S., Al‐Saadoun, S. S., and Bader, M. A. (1990). “Influence of cement composition on the corrosion of reinforcement and sulfate resistance of concrete.” ACI Mat. J., 87(2), 114–122.
15.
Rasheeduzzafar, Dakhil, F. H., Al‐Saadoun, S. S., and Al‐Gahtani, A. S. (1990). “Effect of cement composition on corrosion of reinforcing steel in concrete.” Corrosion of reinforcement in concrete, Elsevier Applied Science, London, England, 213–226.
16.
Rasheeduzzafar, Ehtesham Hussain, S., and Al‐Saadoun, S. S. (1991). “Effect of cement composition on chloride binding and corrosion of reinforcing steel in concrete.” Cement and Concrete Res., 21(5), 779–794.
17.
Rasheeduzzafar, Ehtesham Hussain, S., and Al‐Saadoun, S. S. (1992). “Effect of tricalcium aluminate content of cement on chloride binding and corrosion of reinforcing steel in concrete.” ACI Mat. J., 89(1), 3–12.
18.
Spellman, D. L., and Stratfull, R. F. (1969). “Chlorides and bridge deck deterioration.” Res. Rep. No. M & R 635116‐4, Div. of Hwy., California.
19.
Stucke, M. S., and Majumdar, A. J. (1976). “Composition of the gel phase in Portland cement paste.” Proc., Conf. Hydr. Cement Pastes: Their Structure and Properties, (Sheffield) Cement and Concrete Assoc., Wexham Springs, 31–45.
20.
Sutterheim, N. (1968). “Portland blast‐furnace slag cement—a case for separating grinding of slag.” Proc., 5th Int. Symp. on the Chem. of Cement, Tokyo, Japan, 270–276.
21.
Virmani, Y. P. (1982). “Cost effective rigid concrete construction and rehabilitation in adverse environments.” FCP Annu. Progress Rep., Federal Highway Administration, Washington, D.C., 68.
Information & Authors
Information
Published In
Copyright
Copyright © 1994 American Society of Civil Engineers.
History
Received: May 3, 1993
Published online: May 1, 1994
Published in print: May 1994
Authors
Metrics & Citations
Metrics
Citations
Download citation
If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.