TECHNICAL PAPERS
Aug 1, 1992

Rebar Corrosion in MgSO4 Solution

Publication: Journal of Materials in Civil Engineering
Volume 4, Issue 3

Abstract

Chloride ion attack is known to be the major cause of reinforcing steel corrosion in concrete. This study aims to demonstrate that not only chloride ions but also sulfate ions corrode the reinforcing steel embedded in concrete. Reinforced concrete specimens are prepared with different water‐cement ratios of 0.40, 0.55, and 0.70. A single piece of reinforcing steel is centrally embedded in the specimens at a clear concrete cover of 31 mm (1.25 in.). The reinforced concrete specimens are immersed in a 5% MgSO4 solution and subjected to corrosion monitoring for a period of 43 months. Half‐cell potential and linear polarization resistance techniques are used for corrosion monitoring. The test results indicate that the sulfate ions are corrosive to reinforcing steel, but their severity is less than that of chloride ions. The reduction in the alkalinity of concrete due to a reaction between sulfate salts and calcium hydroxide of the hydrated cement paste is believed to be responsible for the sulfate‐induced reinforcing steel corrosion.

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Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 4Issue 3August 1992
Pages: 292 - 299

History

Published online: Aug 1, 1992
Published in print: Aug 1992

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Authors

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Mohammad Shamim Khan, Member, ASCE
Doctoral Student, School of Civ. Engrg., Oklahoma State Univ., Stillwater, OK 74078‐0327
Abdul‐Hamid J. Al‐Tayyib
Mgr., Mater. and Building Tech. Program, Res. Inst., King Fahd Univ. of Petroleum and Minerals, Dhahran, Saudi Arabia

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