Fiber-Optic Chloride Sensor Development
Publication: Journal of Geotechnical Engineering
Volume 121, Issue 8
Abstract
Chloride in the form of salt water is a major contaminant of ground water, percolating through landfill liners and causing corrosion of steel. Four fiber-optic sensors capable of detecting chloride concentrations were developed. The most promising sensor detects chloride concentrations from 100 μg/mL to greater than 3,000 μg/mL. This sensor works when the chloride changes a reddish-brown silver chromate strip to white silver chloride. The color change causes the intensity of light propagating through the fiber to increase. The increase is monitored, and a calibration curve depicting light intensity versus chloride concentration results. The most promising sensor was multiplexed to determine the diffusion coefficients of chloride in a saturated sand column. The development, operation, and sensitivity of the sensors are described. Upon further development the sensor could be placed in the soil or in reinforced concrete for in situ monitoring of chloride. The sensor's advantages over electronic sensors include immunity to corrosion and electromagnetic interference, and the ability for multiplexing sensors onto a single fiber.
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References
1.
Berke, N. S., and Hicks, M. C. (1993). “Predicting chloride profiles in concrete.”Corrosion 93, Paper no. 341, Will Grace and Co-Conn., Cambridge, Mass.
2.
Desaulniers, D. E., Cherry, J. A., and Fritz, P. (1981). “Origin, age and movement of pore water in agrilaceous quantenary deposits at four sites in Southwestern Ontario.”J. Hydro., 50(1–3), 231–257.
3.
Freeman, T. M., and Seitz, W. R.(1981). “Oxygen probe bases on Tetrakis (alkylamino) ethylene chemiluminescence.”Anal. Chem., 53(1), 98–102.
4.
Kim, B. Y.(1989). “Multiplexing of fiber optic sensors.”Optic News, 15(11), 35–42.
5.
Seitz, W. R.(1988). “Chemical sensors based on immobilized indicators and fiber optics.”CRC Crit. Rev. Anal. Chem., 19, 135.
6.
Test method for electrical indication of concrete's ability to resist chloride ion penetration; C-1202. (1994). Vol. 4.02, ASTM, Philadelphia, Pa.
7.
Willard, H. H., Merritt, L. L., and Dean, J. A. (1974). Instrumental methods of analysis, Van Nostrand Co., New York, N.Y.
8.
Wolfbeis, O. S. (1989a). “Novel techniques and materials for fiber optic chemical sensing.”Optical Fiber Sensors: Proc., 6th Int. Conf., OFS, 89, Springer-Verlag, Berlin, Germany, 416–424.
9.
Wolfbeis, T.(1989b). “A fully reversible fiber optic lactate biosensor based on the intrinsic fluorescence of lactate mono-oxygenase.”Fresenius Z. Anal. Chem., Springer-Verlag, Berlin, Germany, 334(5), 427.
10.
Xi, H. (1993). “Fiber optic sodium chloride sensor,” MSc thesis, Florida Institute of Technology, Melbourne, Fla.
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Copyright © 1995 American Society of Civil Engineers.
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Published online: Aug 1, 1995
Published in print: Aug 1995
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