TECHNICAL PAPERS
Feb 1, 1991

Pb(II) Removal from Kaolinite by Electrokinetics

Publication: Journal of Geotechnical Engineering
Volume 117, Issue 2

Abstract

Electro‐osmosis tests are conducted on saturated kaolinite specimens loaded with Pb(II) to investigate the efficiency and energy requirements of the process in removing this heavy metal. Kaolinite specimens were loaded with 118 μg to 145 μg of Pb(II) per gram of dry soil, below the cation‐exchange capacity of the mineral. The test results pertaining to the flow and the associated electrochemistry (voltage, current, resistance, pH gradients, and conductivity) are presented. The flow in electro‐osmosis with open electrodes is time‐dependent, and it is strongly influenced by electrochemistry resulting from the pH gradients. The absorbed Pb(II) was removed 75‐95% by the process. The extent of removal is directly related to the pH gradients developed in the process. The total charge passed to remove Pb(II) varied between 1,400 and 2,000 amp‐hr per cubic meter of soil. The energy requirement for the removal of Pb(II) in these tests was less than 29 kWh‐60 kWh per cubic meter of soil processed.

Get full access to this article

View all available purchase options and get full access to this article.

References

1.
Acar, Y. B., Gale, R. J. (1986). “Decontamination of soils using electro‐osmosis.” Proposal submitted to the Board of Regents of the State of Louisiana, Louisiana State Univ., Baton Rouge, La.
2.
Acar, Y. B., Gale, R. J., Putnam, G., and Hamed, J. (1988). “Development of pH gradients in electrochemical processing of soils.” Annual Report, Board of Regents of Louisiana, Baton Rouge, La.
3.
Acar, Y. B., Gale, R. J., Putnam, G., and Hamed, J. (1989). “Electrochemical processing of soils: Its potential use in environmental geotechnology and significance of pH gradients.” 2nd Int. Symp. on Envir. Geotech. Shanghai, China, Envo Publishing, Bethlehem, Pa., 1, 25–38.
4.
Acar, Y. B., and Haider, L. (1990). “Transport of low‐concentration contaminants in saturated earthen barriers.” J. Geotech. Engrg., ASCE, 116(7), 1031–1052.
5.
Acar, Y. B., Gale, R. J., Putnam, G., Hamed, J., and Wong, R. (1990). “Electrochemical processing of soils: Theory of pH gradient development by diffusion and linear convection.” J. Envir. Sci. and Health, Part (a); Envir. Sci. and Engrg., 25(6).
6.
Acar, Y. B., Hamed, J., Gale, R. J., and Putnam, G. (1991). “Acid/base distributions in electro‐osmosis.” Transp. Res. Record, No. 1289.
7.
Amba, S. A., Chilingerian, G. V., and Beeson, C. M. (1964). “Use of direct electrical current for increasing the flow rate of reservoir fluids during petroleum recovery.” J. Canadian Petroleum Tech., 3(1), 8–14.
8.
Banerjee, S., and Mitchell, J. K. (1980). “In‐situ volume change properties by electro‐osmosis theory.” J. Geotech. Engrg. Div., ASCE, 106(4), 347–365.
9.
Bjerrum, L., Moum, J., and Eide, O. (1967). “Application of electroosmosis on a foundation problem in a Norwegian quick clay.” Géotechnique, London, England, 17(3), 214–235.
10.
Butterfield, R., and Johnston, I. W. (1980). “The influence of electro‐osmosis on metallic piles in clay.” Geotechnique, London, England, 30(1), 17–38.
11.
Casagrande, L. (1947). “The application of electro‐osmosis to practical problems in foundations and earthwork.” Technical Paper No. 30, Building Research, London, England.
12.
Casagrande, L. (1983). “Stabilization of soils by means of electro‐osmosis—state of the art.” J. Boston Society of Civ. Engr., ASCE, 69(2), 255–302.
13.
Chappell, B. A., and Burton, P. L. (1975). “Electro‐osmosis applied to unstable embankment.” J. Geotech. Engrg. Div., ASCE, 101(8), 733–740.
14.
Esrig, M. I., and Henkel, D. J. (1966). “The use of electrokinetics in the raising of submerged, partially buried metallic objects.” Research Project No. RR‐004‐01‐01, Department of the Navy, Washington, D.C.
15.
Esrig, M. I. (1967). “Application of electrokinetics in grouting.” Reprint No. 480: ASCE Natl. Meeting on Struct. Engrg., Seattle, Washington, ASCE, New York, N.Y.
16.
Esrig, M. I., and Gemeinhardt, J. P. (1968). “Electrokinetic stabilization of an illitic clay.” J. Soil Mech. and Found. Engrg. Div., ASCE, 93(3), 109–128.
17.
Gray, D. H. (1969). “Prevention of moisture rise in capillary systems by electrical short circuiting.” Nature, 223(5204), 371–374.
18.
Gray, D. H. (1970). “Electrochemical hardening of clay soils.” Géotechnique, London, England, 20(1), 81–93.
19.
Hamnet, R. (1980). “A study of the processes involved in the electro‐reclamation of contaminated soils,” thesis presented to the University of Manchester, at Manchester, England, in partial fulfillment of the requirements for the degree of Master of Science.
20.
Jacobs, H. S., and Mortland, M. M. (1959). “Ion movement in Wyoming bentonite during electro‐osmosis.” Proc., of Soil Sci. Society, 23(2342), Lafayette, Ind.
21.
Khan, L. I., Pamukcu, S., and Kugelman, I. (1989). “Electro‐osmosis in fine‐grained soil.” 2nd Int. Symp. on Envir. Geotech., Shanghai, China, Envo Publishing, Bethlehem, Pa., 1, 39–47.
22.
Krizek, R. J., Gularte, F. B., and Hummel, P. B. (1976). “Stabilization of polluted dredgings by electro‐osmosis.” Preprint 2641: ASCE Natl. Water Resour. and Ocean Engrg. Convention, San Diego, Calif., ASCE, New York, N.Y.
23.
Lageman, R. (1989). “Theory and practice of electro‐reclamation.” NATO/CCMS Pilot Study: Demonstration of Remedial Action Technologies for Contaminated Land and Ground Water, NATO/CCMS, Copenhagen, Denmark.
24.
Lockhart, N. C. (1983). “Electroosmotic dewatering of clays: I, II and III.” Colloids and Surfaces, 6(3), 229–269.
25.
Mitchell, J. K. (1976). Fundamentals of Soil Behavior. John Wiley and Sons, New York, N.Y.
26.
Mitchell, J. K., and Wan, T.‐Y. (1977). “Electro‐osmotic consolidation—its effects on soft soils.” Proc. IXICSMFE, Tokyo, Japan, 1, 219–224.
27.
Mitchell, J. K., and Yeung, T.‐C. (1991). “Electro‐kinetic flow barriers in compacted clay.” Transp. Res. Records, No. 1289.
28.
Mitchell, J. K. (1986). “Potential uses of electro‐kinetics for hazardous waste site remediation.” Position paper, U.S. Envir. Protection Agency and University of Washington, Seattle, Wash.
29.
O'Bannon, C. E., Segall, B. A., and Matthias, J. S. (1976). “A laboratory study to determine the feasibility of electro‐osmotic dewatering of dredged material.” U.S. Corps of Engineers Report, Vicksburg, Miss.
30.
Putnam, G. (1988). “Development of pH gradients in electrochemical processing of kaolinite,” thesis presented to Louisiana State University, at Baton Rouge, La., in partial fulfillment of the requirements for the degree of Master of Science.
31.
Renauld, P. O., and Probstein, R. F. (1987). “Electro‐osmotic control of hazardous waste.” Physicochemical Hydrodynamics, 9(1/2), 345–360.
32.
Runnels, D. D., and Larson, J. L. (1986). “A laboratory study of electromigration as a possible field technique for the removal of contaminants from ground water.” Ground Water Monitoring Review, (Summer), 81–91.
33.
Segal, B. A., O'Bannon, C. E., and Matthias, J. A. (1980). “Electro‐osmosis chemistry and water quality.” J. Geotech. Engrg. Div., ASCE, 106(10), 1143–1147.
34.
Shmakin, B. M. (1985). “The method of partial extraction of metals in a constant current electrical field for geochemical exploration.” J. Geochem. Explor., 23(1), 27–33.
35.
Steude, J., Viani, S., and Baker, K. (1989). “Emerging technologies for the remediation of radioactive soils.” Tech. Report for the USEPA Office of Radiation Programs, Roy F. Weston, Inc., Walnut Creek, Calif.
36.
Thompson, R. P. (1971). “The effect of electro‐osmosis on the penetration and extraction resistance of model piles in clay,” thesis presented to the University of Southampton, at Southampton, England, in partial fulfillment of the requirements for the degree of Master of Science.
37.
Thompson, R. T. (1989). “The effect of secondary reactions on the electrokinetic treatment of a silty‐sand soil,” thesis presented to the University of Texas, at Austin, Tex., in partial fulfillment of the requirements for the degree of Master of Science.
38.
Wan, T. Y., and Mitchell, J. K. (1976). “Electro‐osmotic consolidation of soils.” J. Geotech. Engrg. Div., ASCE, 102(5), 473–491.
39.
Yukawa, H., Chigira, H., Hoshiro, T., and Iwata, M. (1971). “Fundamental study on electro‐osmotic filtration; effect of electric field on flow rate of permeation.” Journal of Chemical Engineering of Japan, Nagoya, Japan, 4, 370–376.

Information & Authors

Information

Published In

Go to Journal of Geotechnical Engineering
Journal of Geotechnical Engineering
Volume 117Issue 2February 1991
Pages: 241 - 271

History

Published online: Feb 1, 1991
Published in print: Feb 1, 1991

Permissions

Request permissions for this article.

Authors

Affiliations

Jihad Hamed
Grad. Res. Asst., Dept. of Civ. Engrg., Louisiana State Univ., Baton Rouge, LA 70803
Yalcin B. Acar, Member, ASCE
Assoc. Prof., Dept. of Civ. Engrg., Louisiana State Univ., Baton Rouge, LA
Robert J. Gale
Assoc. Prof., Dept. of Chemistry, Louisiana State Univ., Baton Rouge, LA

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

Cited by

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share