Tensile Characteristics of Palladium Exposed to Hydrogen (Deuterium)
Publication: Journal of Energy Engineering
Volume 126, Issue 3
Abstract
The effects of hydrogen (protium) or deuterium absorption/desorption cycling on the strength and hardness of well-annealed palladium have been evaluated in this study. The results indicate that absorption followed by complete desorption of hydrogen or deuterium increases the strength and hardness characteristics of the palladium matrix while decreasing the metal's ductility. Increasing the amount of hydrogen or deuterium during absorption leads to more pronounced effects on the strength, hardness, and ductility of palladium. The effects of hydrogen absorption/desorption are more pronounced than those of deuterium absorption/desorption. The observed results have been explained in terms of the generation of dislocations during hydrogen or deuterium cycling.
Get full access to this article
View all available purchase options and get full access to this article.
References
1.
Flanagan, T., and Park, C. ( 1988). “Hydrogen Storage Materials.” Chapter 12, Materials Science Forum, R. Barnes, ed., Trans Tech Publications, Aedermannsdorf, Switzerland, 297–305.
2.
Goltsov, V. ( 1981). “The phenomenon of controllable hydrogen phase naklep and the prospects for its use in metal science and engineering.” Mat. Sci. Engrg., 49, 109–125.
3.
Goltsov, V., Dekanenko, V., and Vlasenko, N. ( 1990). “Hydrogen treatment of niobium: Strength and structural changes.” Mat. Sci. Engrg., A129, 239–247.
4.
Goltsov, V., Kirillov, V., Gorban, S., Karnaukh, O., Volynskaya, V., and Tikhonov, N. ( 1983). “Influence of annealing temperature on changes in the properties of hydrogen-phase hardened palladium in a state of hydride embrittlement.” Phys. Met. Mettall., 55, 113–117.
5.
Goods, S., and Guthrie, S. ( 1992). “Mechanical properties of palladium and palladium hydride.” Scripta Metall. Mat., 26, 561–565.
6.
Hasegawa, H., and Nakajima, K. ( 1979). “Effect of hydrogen on the mechanical properties of Pd.” J. Phys. F: Met. Phys., 9, 1035–1046.
7.
Lewis, F. ( 1967). The palladium hydrogen system, Academic, New York.
8.
Mueller, W., Blackledge, J., and Libowitz, G., eds. ( 1968). Metal hydrides, Academic, New York.
9.
Shenk, J., Moss, A., Jonsen, D., Nesbit, S., Rebeiz, K., and Craft, A. ( 1994). “Influence of hydrogen and long-range order on the tensile and fatigue characteristics of Pd3Mn.” J. Mat. Sci. Letters, 13, 496–499.
Information & Authors
Information
Published In
History
Received: Dec 1, 1998
Published online: Dec 1, 2000
Published in print: Dec 2000
Authors
Metrics & Citations
Metrics
Citations
Download citation
If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.