Sediment Fingerprinting: Review of the Method and Future Improvements for Allocating Nonpoint Source Pollution
Publication: Journal of Environmental Engineering
Volume 135, Issue 7
Abstract
Sediment fingerprinting has been developed by researchers over the past three decades for watershed sediment transport research. Sediment fingerprinting is a method to allocate sediment nonpoint source pollutants in a watershed through the use of natural tracer technology with a combination of field data collection, laboratory analyses of sediments, and statistical modeling techniques. The method offers a valuable tool for total maximum daily load assessment to aid in developing efficient remediation strategies for pollution in watersheds. We review the methodological steps of sediment fingerprinting including classification of sediment sources in a watershed, identification of unique tracers for each sediment source, representation of sediment sources and sinks using field sampling, accounting for sediment and tracer fate during transport from source to sink, and utilization of an unmixing model to allocate sediment sources. This review places additional emphasis upon tracers used to discriminate sediment sources during past studies performed on different continents and across different physiogeographic regions. Review and analysis of tracer dependence upon watershed variables provides an additional resource for tracer selection to the community. Finally, future improvements needed for sediment fingerprinting are discussed in order to practically apply the technology for sediment nonpoint source pollution allocation within the context of total maximum daily load assessments.
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Acknowledgments
The writers would like to thank the Civil Engineering Department at the University of Kentucky for partial funding of the first author. This research was also funded, in part, by a Student Enhancement Award from the Department of the Interior, United States Geological Service and the University of Kentucky Research Foundation.
References
Ambers, R. K. R. (2001). “Relationships between clay mineralogy, hydrothermal metamorphism, and topography in a Western Cascades watershed, Oregon, USA.” Geomorphology, 38, 47–61.
Billheimer, D. (2001). “Compositional receptor modeling.” Environmetrics, 12, 451–467.
Birdsey, R. A. (1992). “Carbon storage and accumulation in the United States forest ecosystems.” WO-59, USDA Forest Service.
Birkeland, P. (1999). Soils and geomorphology, 3rd Ed., Oxford University Press, New York.
Blake, W. H., Wallbrink, P. J., Doerr, S. H., Shakesby, R. A., and Humphreys, G. S. (2006). “Magnetic enhancement in wildfire-affected soil and its potential for sediment-source ascription.” Earth Surf. Processes Landforms, 31, 249–264.
Blake, W. H., Walling, D. E., and He, Q. (2002). “Using cosmogenic beryllium-7 as a tracer in sediment budget investigations.” Appl. Sci. Res., 84A(2), 89–102.
Blesius, L., and Weirich, F. H. (1996). “Prediction of shallow landslides using GIS, geotechnical slope stability, and soil moisture models.” Program Abstracts: National Meeting of the Geological Society of America, Denver.
Brewer, M. J., Dunn, S. M., and Soulsby, C. (2002). “A Bayesian model for compositional data analysis.” Proc., Compstat, Berlin, 105–110.
Brigham, M. E., McCullough, C. J., and Wilkinson, P. (2001). “Analysis of suspended-sediment concentrations and radioisotope levels in the Wild Rice River Basin, Northwestern Minnesota, 1973–1998.” Water-Resources Investigations Rep. 01-4192, U.S. Department of the Interior, U.S. Geological Survey.
Brown, A. G. (1985). “The potential use of pollen in the identification of suspended sediment sources.” Earth Surf. Processes Landforms, 10, 27–32.
Buol, S. W., Hole, F. D., McCracken, R. J., and Southard, R. J. (1997). Soil genesis and classification, 4th Ed., Iowa State University Press.
Busacca, A. J., Cook, C. A., and Mulla, D. J. (1993). “Comparing landscape-scale estimation of soil erosion in the Palouse using Cs-137 and RUSLE.” J. Soil Water Conservat., 48(4), 361–367.
Carter, J., Owens, P. N., Walling, D. E., and Graham, J. L. L. (2003). “Fingerprinting suspended sediment sources in a large urban river system.” Sci. Total Environ., 314–316, 513–534.
Chang, H. H. (1988). Fluvial processes in river engineering, Krieger Publishing Company, Malabar, Fla.
Claessens, L., Schoorl, J. M., and Veldkamp, A. (2006). “Modelling the location of shallow landslides and their effects on landscape dynamics in large watersheds: An application for northern New Zealand.” Geomorphology, 87(1–2), 16–27.
Collins, A. L., and Walling, D. E. (2002). “Selecting fingerprint properties for discriminating potential suspended sediment sources in river basins.” J. Hydrol., 261, 218–244.
Collins, A. L., Walling, D. E., and Leeks, G. J. L. (1997a). “Source type ascription for fluvial suspended sediment based on a quantitative composite fingerprinting technique.” Catena, 29, 1–27.
Collins, A. L., Walling, D. E., and Leeks, G. J. L. (1997b). “Use of the geochemical record preserved in floodplain deposits to reconstruct recent changes in river basin sediment sources.” Geomorphology, 19, 151–167.
Collins, A. L., Walling, D. E., and Leeks, G. J. L. (1998). “Use of composite fingerprints to determine the provenance of the contemporary suspended sediment load transported by rivers.” Earth Surf. Processes Landforms, 23, 31–52.
Collins, A. L., Walling, D. E., Sichingabula, H. M., and Leeks, G. J. L. (2001). “Suspended sediment source fingerprinting in a small tropical catchment and some management implications.” Applied Geography, 21, 387–412.
De Boer, D., and Crosby, G. (1995). “Evaluating the potential of SEM/EDS analysis for fingerprinting suspended sediment derived from two contrasting topsoils.” Catena, 24, 243–258.
De Miguel, E., Charlesworth, S., Ordonez, A., and Seijas, E. (2005). “Geochemical fingerprints and controls in the sediments of an urban river: River Manzanares, Madrid (Spain).” Sci. Total Environ., 340, 137–148.
Droppo, I. G., Nackaerts, K., Walling, D. E., and Williams, N. (2005). “Can flocs and water stable soil aggregates be differentiated within fluvial systems?” Catena, 60, 1–18.
Droppo, I. G., and Ongley, E. D. (1992). “The state of suspended sediment in the freshwater fluvial environment: A method of analysis.” Water Resour., 26(1), 65–72.
Federal Interagency Stream Restoration Working Group (FISRWG). (1998). Stream corridor restoration: Principles, processes, and practices, Federal Interagency Stream Restoration Working Group (FISRWG), GPO Item No. 0120-A; SuDocs No. A 57.6/2:EN 3/PT.653.
Fitzgerald, S. A., Klump, J. V., Swarzenski, P. W., MacKenzie, R. A., and Richards, K. D. (2001). “Beryllium-7 as a tracer of short-term sediment deposition and resuspension in the Fox River, Wisconsin.” Environ. Sci. Technol., 35(2), 300–305.
Fox, J. F. (2005). “Fingerprinting using biogeochemical tracers to investigate watershed processes.” Ph.D. thesis, University of Iowa, Iowa City, Iowa.
Fox, J. F., and Papanicolaou, A. N. (2007). “The use of carbon and nitrogen isotopes to study watershed erosion processes.” J. Am. Water Resour. Assoc., 43(4), 1047–1064.
Fox, J. F., and Papanicolaou, A. N. (2008a). “An un-mixing model to study watershed erosion processes.” Adv. Water Resour., 31(1), 96–108.
Fox, J. F., and Papanicolaou, A. N. (2008b). “Application of the spatial distribution of nitrogen stable isotopes for sediment tracing at the watershed scale.” J. Hydrol., 358, 46–55.
Franks, S. W., and Rowan, J. S. (2000). “Multi-parameter fingerprinting of sediment sources: Uncertainty estimation and tracer selection.” Computational methods in water resources XIII, Bentley et al., eds., Balkema, Rotterdam, 1067–1074.
Froehlich, W., and Walling, D. E. (2006). “The use of and to investigate sediment sources and overbank sedimentation rates in the Teesta River basin, Sikkim Himalaya, India.” Sediment dynamics and the hydromorphology of fluvial systems, International Association of Hydrological Sciences (IAHS) Publ., Wallingford, U.K., Vol. 306, 380–388.
Gelfand, A. E., and Smith, A. F. M. (1990). “Sampling-based approaches to calculating marginal densities.” J. Am. Stat. Assoc., 85, 399–409.
Gill, R. A., Polley, H. W., Johnson, H. B., Anderson, L. J., Maherali, H., and Jackson, R. B. (2002). “Nonlinear grassland responses to past and future atmospheric .” Nature (London), 417, 279–282.
Grimshaw, D. L., and Lewin, J. (1980). “Source identification for suspended sediments.” J. Hydrol., 47, 151–162.
Gruszowski, K. E., Foster, I. D. L., Lees, J. A., and Charlesworth, S. M. (2003). “Sediment sources and transport pathways in a rural catchment, Herefordshire, UK.” Hydrolog. Process., 17, 2665–2681.
Hasholt, B., Walling, D. E., and Owens, P. N. (2000). “Sedimentation in arctic proglacial lakes: Mittivakkat Glacier, south-east Greenland.” Hydrolog. Process., 14, 679–699.
Homann, P. S., Remillard, S. M., Harmon, M. E., and Bormann, B. T. (2004). “Carbon storage in coarse and fine fractions of Pacific northwest old-growth forest soils.” Soil Sci. Soc. Am. J., 68(6), 2023–2030.
Horowitz, A. J., and Elrick, K. A. (1987). “The relation of stream sediment surface area, grain size and composition to trace element chemistry.” Appl. Geochem., 2, 437–451.
Jenny, H. (1941). Factors of soil formation, McGraw-Hill, New York.
Kelley, D. W., and Nater, E. A. (2000). “Source apportionment of lake bed sediments to watersheds in an Upper Mississippi basin using a chemical mass balance method.” Catena, 41, 277–292.
Klages, M. G., and Hsieh, Y. P. (1975). “Suspended solids carried by the Gallatin River of southwestern Montana: II. Using mineralogy for inferring sources.” J. Environ. Qual., 4(1), 68–73.
Krause, A. K., Franks, S. W., Kalma, J. D., Loughran, R. J., and Rowan, J. S. (2003). “Multi-parameter fingerprinting of sediment deposition in a small gullied catchment in SE Australia.” Catena, 53, 327–348.
Krein, A., Petticrew, E., and Udelhoven, T. (2003). “The use of fine sediment fractal dimensions and colour to determine sediment sources in a small watershed.” Catena, 53, 165–179.
Lartiges, B. S., Deneux-Mustin, S., Villemin, G., Mustin, C., Barres, O., Chamerois, M., Gerard, B., and Babut, M. (2001). “Composition, structure, and size distribution of suspended particulates from the Rhine River.” Water Res., 35(3), 808–816.
Matisoff, G., Bonniwell, E. C., and Whiting, P. J. (2002). “Soil erosion and sediment sources in an Ohio watershed using beryllium-7, cesium-137, and lead-210.” J. Environ. Qual., 31(1), 54–61.
Matisoff, G., Wilson, C. G., and Whiting, J. (2005). “The ratio as an indicator of suspended sediment age or fraction new sediment in suspension.” Earth Surf. Processes Landforms, 30, 1191–1201.
Miller, J., Lord, M., Yurkovich, S., Mackin, G., and Kolenbrander, L. (2005). “Historical trends in sedimentation rates and sediment provenance, Fairfield Lake, western North Carolina.” J. Am. Water Resour. Assoc., 41(5), 1053–1075.
Minella, J. P. G., Merten, G. H., and Clarke, R. T. (2004). Identification of sediment sources in a small rural drainage basin, IAHS Pub., Wallingford, U.K., 288, 44–51.
Montgomery, J. A., Busacca, A. J., Frazier, B. E., and McCool, D. K. (1997). “Evaluating soil movement using cesium-137 and the revised universal soil loss equation.” Soil Sci. Soc. Am. J., 61(2), 571–579.
Morris, G. L., and Fan, J. (1997). Reservoir sedimentation handbook, McGraw-Hill, New York.
Motha, J. A., Wallbrink, P. J., Hairsine, P. B., and Grayson, R. B. (2002). “Tracer properties of eroded sediment and source material.” Hydrolog. Process., 16, 1983–2000.
Motha, J. A., Wallbrink, P. J., Hairsine, P. B., and Grayson, R. B. (2003). “Determining the sources of suspended sediment in a forested catchment in southeastern Australia.” Water Resour. Res., 39(3), 1056.
Motha, J. A., Wallbrink, P. J., Hairsine, P. B., and Grayson, R. B. (2004). “Unsealed roads as suspended sediment sources in an agricultural catchment in south-eastern Australia.” J. Hydrol., 286, 1–18.
Nagle, G. N., Lassoie, J. P., Fahey, T. J., and McIntyre, S. C. (2000). “The use of caesium-137 to estimate agricultural erosion on steep slopes in a tropical watershed.” Hydrolog. Process., 14, 957–969.
Ney, R. A., Schnoor, J. L., and Mancuso, M. A. (2002). “A methodology to estimate carbon storage and flux in forestland using existing forest and soils databases.” Environ. Monit. Assess., 78(3), 291–307.
Oldfield, F., Maher, B. A., Donoghue, J., and Pierce, J. (1985). “Particle-size related, mineral magnetic source sediment linkages in the Rhode River catchment, Maryland, USA.” J. Geol. Soc. (London), 142, 1035–1046.
Olley, J., and Caitcheon, G. (2000). “Major element chemistry of sediments from the Darling-Barwon River and its tributaries: Implications for sediment and phosphorous sources.” Hydrolog. Process., 14, 1159–1175.
Owens, P. N., and Walling, D. E. (2002). “Changes in sediment sources and floodplain deposition rates in the catchment of the River Tweed, Scotland, over the last : The impact of climate and land use change.” Earth Surf. Processes Landforms, 27, 402–423.
Palmer, C. J. (2003). “Techniques to measure and strategies to monitor forest soil carbon.” The potential of U.S. forest soils to sequester carbon and mitigate the greenhouse effect, J. Kimble, L. S. Heath, R. A. Birdsey, and R. Lal, eds., CRC, Boca Raton, Fla., 385–394.
Papanicolaou, A. N., Fox, J. F., and Marshall, J. (2003). “Soil fingerprinting in the Palouse Basin, USA using stable carbon and nitrogen isotopes.” Int. J. Sediment Res., 18(2), 291–297.
Parton, W. J., Schimel, D. S., Cole, C. V., and Ojima, D. S. (1987). “Analysis of factors controlling soil organic levels of grasslands in the Great Plains.” Soil Sci. Soc. Am. J., 51, 1173–1179.
Peart, M. R. (1993). “Using sediment properties as natural tracers for sediment source: Two case studies from Hong Kong.” Tracers in hydrology, IAHS Publ., Wallingford, U.K., 215, 313–317.
Phillips, J. M., Russell, M. A., and Walling, D. E. (2000). “Time-integrated sampling of fluvial suspended sediment: A simple methodolgy for small watersheds.” Hydrolog. Process., 14, 2589–2602.
Porto, P., Walling, D. E., and Callegari, G. (2005). “Investigating sediment sources within a small catchment in southern Italy.” Sediment Budgets I, IAHS Publ., Wallingford, U.K., 291, 113–122.
Russell, M. A., Walling, D. E., and Hodgkinson, R. A. (2001). “Suspended sediment sources in two small lowland catchments in the UK.” J. Hydrol., 252, 1–24.
Schimmack, W., Auerswald, K., and Bunzl, K. (2001). “Can replace as an erosion tracer in agricultural landscapes contaminated with Chernobyl fallout?” J. Environ. Radioact., 53, 41–57.
Slattery, M. C., Burt, T. P., and Walden, J. (1995). “The application of mineral magnetic measurements to quantify within-storm variations in suspended sediment sources.” Tracer technologies for hydrological systems, IAHS Publ., Wallingford, U.K., Vol. 229, 143–151.
Soil Survey Division Staff. (1993). Soil survey manual, Soil Conservation Service Handbook 18, United States Department of Agriculture (USDA), Washington, D.C.
Song, W., Liu, P., Yang, M., and Xue, Y. (2003). “Using REE tracers to measure sheet erosion changing to rill erosion.” J. Rare Earths, 21(5), 587–590.
Soulsby, C., Petrya, J., Brewerb, M. J., Dunnc, S. M., Otta, B., and Malcolma, I. A. (2003). “Identifying and assessing uncertainty in hydrological pathways: A novel approach to end member mixing in a Scottish agricultural catchment.” J. Hydrol., 274, 109–128.
Spiro, T. G., and Stigliani, W. M. (2003). Chemistry of the environment, Prentice-Hall, Upper Saddle River, N.J.
United States Environmental Protection Agency (USEPA), Office of Science and Technology. (2004). “The incidence and severity of sediment contamination in surface waters of the United States.” EPA 823-R-04-007, Washington, D.C.
United States Environmental Protection Agency (USEPA), Office of Water. (2007). “National water quality inventory,” Report to Congress 2002 Reporting Cycle, EPA 841-R-07-001, Washington, D.C.
VandenBygaart, A. J., and Protz, R. (2001). “Bomb-fallout as a marker of geomorphic stability in dune sands and soils, Pinery Provincial Park, Ontario, Canada.” Earth Surf. Processes Landforms, 26, 689–700.
Vigiak, O., Sterk, G., Romanowicz, R. J., and Beven, K. J. (2006). “A semi-empirical model to assess uncertainty of spatial patterns of erosion.” Catena, 66(3), 198–210.
Wallbrink, P. J., Murray, A. S., and Olley, J. M. (1999). “Relating suspended sediment to its original soil depth using fallout radionuclides.” Soil Sci. Soc. Am. J., 63(2), 369–378.
Wallbrink, P. J., Murray, A. S., Olley, J. M., and Olive, L. J. (1998). “Determining sources and transit times of suspended sediment in the Murrumbidgee River, New South Wales, Australia, using fallout and .” Water Resour. Res., 34(4), 879–887.
Walling, D. E. (2005). “Tracing suspended sediment sources in catchments and river systems.” Sci. Total Environ., 344, 159–184.
Walling, D. E., and Amos, C. M. (1999). “Source, storage, and mobilisation of fine sediment in a chalk stream system.” Hydrolog. Process., 13, 323–340.
Walling, D. E., Collins, A. L., Sichingabula, H. M., and Leeks, G. J. L. (2001). “Integrated assessment of catchment suspended sediment budgets: A Zambian example.” Land Degrad. Dev., 12, 387–415.
Wischmeier, W. H., and Smith, D. D. (1978). “Predicting rainfall erosion losses: A guide to conservation planning.” United States Department of Agriculture (USDA), agriculture handbook, No. 537, U.S. Government Printing Office, Washington, D.C.
Worner, U., Zimmermann-Timm, H., and Kausch, H. (2002). “Aggregate associated bacteria and heterotrophic flagellates in the River Elbe—Their relative significance along the longitudinal profile from .” International Review of Hydrobiology, 87(2), 255–266.
Yoneyama, T. (1996). “Characterization of natural 15N abundance of soils.” Mass spectrometry of soils, T. W. Boutton and S. I. Yamasaki, eds., Marcel Dekker, New York, 205–224.
Yu, L., and Oldfield, F. (1989). “A multivariate mixing model for identifying sediment source from magnetic measurements.” Quater. Res., 32, 168–181.
Zhang, X., Wen, Z., Feng, M., Yang, Q., and Zheng, J. (2007). “Application of fingerprinting technique to interpreting sediment production records from reservoir deposits in a small catchment of the Hilly Loess Plateau, China.” Sci. China, Ser. D: Earth Sci., 50(2), 254–260.
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Received: Nov 1, 2007
Accepted: Dec 29, 2008
Published online: Jun 15, 2009
Published in print: Jul 2009
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