TECHNICAL PAPERS
Jun 1, 2008

Effect of ClO2 Pretreatment on Subsequent Water Treatment Processes

Publication: Journal of Environmental Engineering
Volume 134, Issue 6

Abstract

The effect of chlorine dioxide (ClO2) pretreatment on subsequent treatment processes (coagulation, flocculation, sedimentation, filtration, and ozonation) was studied at pilot-scale at the Upper San Leandro Water Treatment Plant near Oakland, Calif. Potential impacts of ClO2 on the distribution system were also studied at bench scale using simulated distribution system (SDS) tests. Pilot trials were conducted with one train operating without ClO2 pretreatment (Train 1) and the other with a ClO2 dose of between 0.6 and 1.0mgL (Train 2). Comparison between Trains 1 and 2 showed that ClO2 pretreatment resulted in a 0.1–0.2 NTU decrease in settled water turbidity when compared to no pretreatment. ClO2 pretreatment also resulted in a small (0.01cm1) decrease in ultraviolet absorbance at 254nm . Following sedimentation, about 60% of the applied ClO2 formed chlorite (ClO2) , with 10–20% forming chlorate (ClO3) . Ozonation immediately converted all residual ClO2 and ClO2 to ClO3 . There was no significant difference in the performance of the filters between the two trains in terms of headloss, particle count, and turbidity. Bench-scale SDS tests indicated that chlorine dioxide preoxidation did not affect subsequent chloramine stability or concentrations of trihalomethanes, haloacetic acids, or adsorbable organic halides in the distribution system.

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Acknowledgments

This work was funded as part of American Water Works Association Research Foundation (AwwaRF) Project No. 2843. AwwaRF is the joint owner of the technical information upon which this manuscript is based. The writers thank the AwwaRF for its financial, technical, and administrative assistance in funding and managing the project through which this information was discovered. The comments and views detailed herein may not necessarily reflect the views of the AWWA Research Foundation, its officers, directors, affiliates, or agents.

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Information & Authors

Information

Published In

Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 134Issue 6June 2008
Pages: 478 - 485

History

Received: Jun 2, 2006
Accepted: Oct 18, 2007
Published online: Jun 1, 2008
Published in print: Jun 2008

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Authors

Affiliations

M. Zamir B. Alam
Research Fellow, Dept. Civil Engineering, Univ. of Toronto, 35 St. George St., Toronto ON, Canada M5S 1A4.
Raymond E. Cantwell
Ph.D. Candidate, Dept. Civil Engineering, Univ. of Toronto, 35 St. George St., Toronto ON, Canada M5S 1A4.
Ron Hofmann
Assistant Professor, Dept. Civil Engineering, Univ. of Toronto, 35 St. George St., Toronto ON, Canada M5S 1A4 (corresponding author). E-mail: [email protected]
Robert C. Andrews
Professor, Dept. Civil Engineering, Univ. of Toronto, 35 St. George St., Toronto ON, Canada M5S 1A4.
Jennie L. Rand
Assistant Professor, Ivan Curry School of Engineering, Acadia Univ., Wolfville NS, Canada B4P 2R6.
Graham A. Gagnon
Associate Professor, Dept. Civil Engineering, Dalhousie University, 1360 Barrington St., Halifax, NS B3J 2X4.
Monique VanderMarck
Water Treatment Superintendent, East Bay Municipal Utility District, Oakland, CA 94623.
Erin Moffat
Research Assistant, Dept. Civil Engineering, Univ. of Waterloo, 200 University Ave. W., Waterloo ON, Canada N2L 3G1.
Susan A. Andrews
Associate Professor, Dept. Civil Engineering, Univ. of Waterloo, 200 University Ave. W., Waterloo ON, Canada N2L 3G1.

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