TECHNICAL PAPERS
Jul 1, 2007

Tropical Soils–Acid Mine Drainage Interactions: Breakthrough Curves and Some Transport Parameters

Publication: Journal of Environmental Engineering
Volume 133, Issue 7

Abstract

The interactions between acid mine drainage (AMD) and three tropical clayey soils have been studied through hydraulic conductivity and batch sorption/dissolution testing. After 19–24 pore volumes of AMD flow through the soils, the measured final hydraulic conductivity ranged between 1.1×1011 and 3.3×1011ms . The pH, electrical conductivity, and solute breakthrough curves obtained suggested the soils had low acid-buffering capacities. Also, several chemical species were released from the soils due to AMD attack of soil grains and mineral. The batch tests revealed high dissolution of species such as sodium, cobalt, and sulfate from the soils by AMD. The results also indicated dissolution of metals from soil constituents, desorption of chemical species, and transformation and dissolution of soil minerals due to AMD attack. The results of the study showed that, in general, the soils were not effective in attenuating contaminants present in the AMD. Thus, they may not be used alone to construct liners for acid-generating waste mine containment facilities.

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Acknowledgments

The information presented in this paper has been obtained as part of an ongoing study to evaluate tropical soils for lining waste containment facilities. The writers are grateful to the Canadian Commonwealth Scholarship and Fellowship Program and the Building and Road Research Institute, Ghana, for providing financial assistance to E. M. F. The study was also partly funded by the Discovery Grant awarded to E. K. Y. by the Natural Sciences and Engineering Research Council of Canada (NSERC).

References

Acquah, P. C. (1992). “Proposed guidelines for exploration, mining, and mineral processing.” Proc., Seminar on the Effect of Mining on Ghana’s Environment with Particular Reference to Proposed Mining Environmental Guidelines, Ghana Environmental Protection Agency Report, Accra, Ghana, 45–49.
Akosa, A. B., Adimado, A. A., Amegbey, N. A., Nignpense, B. E., Carboo, D., and Gyasi, S. (2002). Cyanide Investigation Committee Rep., Ministry of Environment and Science, Accra, Ghana.
Alpers, C. N., Blowes, D. W., Nordstrom, D. K., and Jambor, J. L. (1994). “Secondary minerals and acid mine-water chemistry.” The environmental chemistry of sulfide mine wastes, D. W. Blowes and J. L. Jambor, eds., Mineralogical Association of Canada, Waterloo, Ont., Canada, 247–270.
ASTM. (2002a). “Standard test method for distribution ratios by the short-term batch method. ASTM D 4319-1993 (2002).” 2002 Annual book of ASTM standards, West Conshohocken, Pa., 581–587.
ASTM. (2002b). Annual book of ASTM standards; Section 4: Construction—Soil and rock (I): D 420-D5779, Vol. 04.08, West Conshohocken, Pa.
Charman, J. H. (1995). “Laterite in road pavements.” CIRIA special publication 47, Construction Industry Research and Information Association, London.
Dreimanis, A. (1962). “Quantitative gasometric determination of calcite and dolomite by using Chittick apparatus.” J. Sediment. Petrol., 32(3), 520–529.
Frempong, E. M., and Yanful, E. K. (2006). “Chemical and mineralogical transformations in three tropical soils due to permeation with acid mine drainage.” Bull. Eng. Geol. Environ., 65(3), 353–271.
Gidigasu, M. D. (1976). “Laterite soil engineering: Pedogenesis and engineering principles.” Developments in geotechnical engineering, Vol. 9, Elsevier Scientific, New York.
Gray, N. F. (1997). “Environmental impact and remediation of acid mine drainage: A management problem.” Environ. Geol., 30(1/2), 358–361.
Griffin, R. A. et al. (1976). “Attenuation of pollutants in municipal landfill leachate by clay minerals: Part I. Column leaching and field verification.” Engineering geology note 78, Ilinois State Geological Survey, Urbana, Ill.
Grim, R. E. (1968). Clay mineralogy, 2nd Ed., McGraw-Hill, New York.
Jambor, J. L. (1994). “Mineralogy of sulfide-rich tailings and their oxidation products.” The environmental chemistry of sulfide mine wastes, D. W. Blowes and J. L. Jambor, eds., Mineralogical Association of Canada, Waterloo, Ont., Canada, 59–102.
Kashir, M., and Yanful, E. K. (1997). “A flow pump system for assessing clay barrier–permeant compatibility.” Geotech. Test. J., 20(2), 179–190.
Kashir, M., and Yanful, E. K. (2000). “Compatibility of slurry wall backfill soils with acid mine drainage.” Adv. Environ. Res., 4(3), 251–268.
Kashir, M., and Yanful, E. K. (2001). “Hydraulic conductivity of bentonite permeated with acid mine drainage.” Can. Geotech. J., 32(5), 1034–1048.
Kesse, G. O. (1985). The rock and mineral resources of Ghana, Balkema, Rotterdam, The Netherlands.
Levy, D. B., Custis, K. H., Casey, W. H., and Rock, P. A. (1997). “A comparison of metal attenuation in mine residue and overburden material from an abandoned copper mine.” Appl. Geochem., 12(2), 203–211.
Martin, R. T. (1955). “Glycol retention analysis.” Soil Sci. Soc. Am. Proc., 19(2), 160–164.
Mendoça, R. G. M., Barbosa, M. C., and Castro, F. J. C. O. (2002). “Evaluation of ions retention capacity of a residual soil of Rio de Janeiro, Brazil.” Proc. 4th Int. Congress on Environmental Geotechnics, G. De Mello and M. Almeida, eds., Vol. 1, Rio de Janeiro, Brazil, 439–446.
Smedley, P. L. (1996). “Arsenic in rural groundwater in Ghana.” J. African Earth Sci., Oxford, U.K., 22(4), 459–470.
Tsugawa, J. K., Boscov, M. E. G., Vello, K. L., and de Olivera, E. (2002). “Dissolution and reverse diffusion of metals in a compacted lateritic clay.” Proc., 4th Int. Congress on Environmental Geotechnics, Vol. 1, Rio de Janeiro, Brazil, 453–458.
Wissa, A. E. (1969). “Pore pressure measurement in saturated stiff soils.” J. Soil Mech. and Found. Div., 95(4), 1063–1073.
Yanful, E. K., Shikatani, K. S., and Quirt, D. H. (1995). “Hydraulic conductivity of natural soils permeated with acid mine drainage.” Can. Geotech. J., 32, 624–646.

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Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 133Issue 7July 2007
Pages: 733 - 741

History

Received: Aug 31, 2005
Accepted: Dec 5, 2006
Published online: Jul 1, 2007
Published in print: Jul 2007

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Eric M. Frempong, Ph.D., A.M.ASCE [email protected]
Senior Geotechnical Engineer, EBA Engineering, Inc., 4813 Seton Dr., Baltimore, MD 21215. E-mail: [email protected]
Ernest K. Yanful, Ph.D., A.M.ASCE [email protected]
Professor, Geotechnical Research Centre, Dept. of Civil and Environmental Engineering, The Univ. of Western Ontario, London ON, Canada N6A 5B9 (corresponding author). E-mail: [email protected]

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