TECHNICAL PAPERS
Dec 1, 2006

Concentration–Duration–Frequency Curves for pH in a Stream in the Great Smoky Mountains

Publication: Journal of Environmental Engineering
Volume 132, Issue 12

Abstract

Multiparameter monitors (sondes) were installed at four sites in a stream in the Great Smoky Mountains National Park. These sondes recorded pH, turbidity, and other parameters every 15min . The data were analyzed to determine the time-connected duration of excursions below various pH levels (pH 4.5, 5.0, 5.5, 6.0, and 6.5). The durations for excursions below each pH level were assigned probability quantiles and plotted. This created a concentration–duration–frequency curve similar to precipitation intensity–duration–frequency curves. The pH excursion events appear to follow a Poisson arrival process and were fitted to a corresponding exponential distribution. The mean event duration for each pH level is the fitting parameter, μ , for the exponential distribution, and μ followed an exponential trend with pH. The characteristics of the concentration–duration–frequency family of curves capture the information contained in the original data and potentially allow comparisons with toxicity data as well as a temporal and spatial comparison.

Get full access to this article

View all available purchase options and get full access to this article.

Acknowledgments

This work was partially supported by a National Park Service Cooperative Agreement Grant No. UNSPECIFIED1443-CA-5460-98-006 (Amendment 10). The assistance and counsel of Stephen Moore and Matt Kulp of the GRSM were greatly appreciated.

References

Anderson, D. R., Sweeny, D. J., and Williams, T. A. (1993). Statistics for business and economics, West Publishing Company, Minneapolis.
Bobba, A. G., Lam, D. C. L., Booty, W. G., Jefries, D. S., and Thomas, R. L. (1990). “Stochastic analysis of acid shocks generated by mixed hydrological processes.” Water, Air, Soil Pollut., 53, 239–250.
Chin, D. A. (2000). Water-resources engineering, Prentice-Hall, Englewood Cliffs, N.J.
Clair, T. A., Bobba, A. G., and Miller, K. (2001). “Yearly changes in the seasonal frequency and duration of short-term acid pulses in some Nova Scotia, Canada streams.” Environ. Geol., 40(4–5), 582–591.
Cramer, H., and Leadbetter, M. R. (1967). Stationary and related stochastic processes, Wiley, New York.
Gaboury, D. R., Driscoll, E. D., and Sartor, J. D. (1987). “A probabalistic methodology for estimating water quality effects from highway stormwater runoff.” Sci. Total Environ., 59, 447–456.
Greb, S. R., and Graczyk, D. J. (1995). “Frequency-duration analysis of dissolved-oxygen concentrations in two southwestern Wisconsin streams.” Water Resour. Bull., 31(3), 431–438.
Huckabee, J. W., Goodyear, C. P., and Jones, R. D. (1975). “Acid rock in the Great Smokies: Unanticipated impact on aquatic biota of road construction in regions of sulfide mineralization.” Trans. Am Fish. Soc., 104(4), 677–684.
MacAvoy, S. E., and Bulger, A. J. (1995). “Survival of brook trout (Salvelinus fontinalis) embryos and fry in streams of different acid sensitivity in Shenandoah National Park, USA.” Water, Air, Soil Pollut., 85, 445–450.
Neal, C., Robson, A., Reynolds, B., and Jenkins, A. (1992). “Prediction of future short-term stream chemistry—a modeling approach.” J. Hydrol., 130, 87–103.
Newcombe, C. P. (2003). “Impact assessment model for clear water fishes exposed to excessively cloudy water.” J. Am. Water Resour. Assoc., 39(3), 529–544.
Robinson, R. B., Roby, J. C., Buchanan, J. R., Barnett, T. W., and Moore, S. E. (2004a). “Storm event monitoring in the Great Smoky Mountains National Park.” Proc., ASCE EWRI 2004 World Water and Environmental Resources Congress, ASCE, Reston, Va.
Robinson, R. B., Wood, M. S., Smoot, J. L., and Moore, S. E. (2004b). “Parametric modeling of water quality and sampling strategy in a high-altitude Appalachian stream.” J. Hydrol., 287, 62–73.
Rousseau, D., Verdonck, F., Moerman, O., Carrette, R., Thoeye, C., Meirlaen, J, and Vanrolleghem, P. A. (2001). “Development of a risk assessment based technique for design/retrofitting of WWTPs.” Water Sci. Technol., 43(7), 287–294.
Shubzda, J., Lindberg, S. E., Garten, C. T., and Nodvin, S. C. (1995). “Elevational trends in the fluxes of sulphur and nitrogen in throughfall in the southern Appalachian Mountains: Some surprising results.” Water, Air, Soil Pollut., 8, 2265–2270.
Todorovic, P. (1978). “Stochastic models of floods.” Water Resour. Res., 14(2), 345–356.

Information & Authors

Information

Published In

Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 132Issue 12December 2006
Pages: 1600 - 1605

History

Received: Oct 18, 2005
Accepted: Feb 10, 2006
Published online: Dec 1, 2006
Published in print: Dec 2006

Permissions

Request permissions for this article.

Authors

Affiliations

R. Bruce Robinson [email protected]
Armour T. Granger Professor of Civil and Environmental Engineering, Dept. of Civil and Environmental Engineering, 223 Perkins Hall, Univ. of Tennessee, Knoxville, TN 37996-2010 (corresponding author). E-mail: [email protected]
J. Chadwick Roby
Graduate Research Assistant, Dept. of Civil and Environmental Engineering, 223 Perkins Hall, The Univ. of Tennessee, Knoxville, TN 37996.

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

Cited by

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share