TECHNICAL PAPERS
Nov 1, 2006

Methodological Aspects of Using Blast Furnace Slag for Wastewater Phosphorus Removal

Publication: Journal of Environmental Engineering
Volume 132, Issue 11

Abstract

Blast furnace (BF) slag is a by-product of steel plants. The objective of this study was to evaluate experimental methods to determine the phosphorus sorption capacity of BF slag. The handling of BF slag, before usage and clogging were also considered, as well as estimating the phosphorus retention capacity. Agitation and pilot-scale experiments were performed using both wastewater and phosphate solutions. This investigation showed that sorption capacities derived by wastewater experiments were considerably lower compared to those by phosphate solutions. Fresh BF slag briefly exposed to rainfall had a higher phosphorus sorption than weathered BF slag, indicating the importance of handling the slag carefully before usage. The risk for leakage of sulfuric compounds is considerable, especially during the initial operation phase of BF slag filters. Locations of BF slag filter beds for wastewater treatment must be carefully chosen from an environmental point of view.

Get full access to this article

View all available purchase options and get full access to this article.

Acknowledgments

This study was financed by “The Swedish Water and Wastewater Association,” and is hereby acknowledged. The information and delivery of blast furnace slag offered by Mr. Tore Sandström at SSAB, Luleå, was appreciated. Mrs. Lotta Lind at Merox, Oxelösund, is gratefully acknowledged for interesting discussions. The writers are especially thankful for all assistance during the experimental work offered by Ms. Kerstin Nordqvist and Mr. Roger Lindfors at Luleå University of Technology (LTU). Finally, Professor Jorgen Hanaeus at the Division of Sanitary Engineering, LTU, is particularly thanked for his academic support during this project.

References

Agyei, N. M., Strydom, C. A., and Potgieter, J. H. (2002). “The removal of phosphate ions from aqueous solution by fly ash, slag, ordinary Portland cement and related blends.” Cem. Concr. Res., 32(12), 1889–1897.
Brooks, A. S., Rozenwald, M. N., Geohring, L. D., Lion, L. W., and Steenhuis, T. S. (2000). “Phosphorus removal by wollastonite: A constructed wetland substrate.” Ecol. Eng., 15(1–2), 121–132.
Cameron, K., Madramootoo, C, Crolla, A., and Kinsley, C. (2003). “Pollutant removal from municipal sewage lagoon effluents with a free-surface wetland.” Water Res., 37(12), 2803–2812.
Drizo, A., Comeau, Y., Forget, C, and Chapuis, R. P. (2002). “Phosphorus saturation potential: A parameter for estimating the longevity of constructed wetland systems.” Environ. Sci. Technol., 36(21), 4642–4648.
Drizo, A., Frost, C. A., Grace, J., and Smith, K. A. (1999). “Physico-chemical screening of phosphate removing substrates for use in constructed wetland systems.” Water Res., 33(17), 3595–3602.
Droste, R. L. (1997). Theory and practise of water and wastewater treatment, Wiley New York.
Grüneberg, B., and Kern, J. (2001). “Phosphorus retention capacity of iron-ore and blast furnace slag in subsurface flow constructed wetlands.” Water Sci. Technol., 44(11–12), 69–75.
Hill, C. M., Duxbury, J., Geohring, L., and Peck, T. (2000). “Designing constructed wetlands to remove phosphorus from barnyard runoff: A comparison of four alternative substrates.” J. Environ. Sci. Health, Part A: Toxic/Hazard. Subst. Environ. Eng., 35(8), 1357–1375.
Hylander, L. D., Kietlińska, A., Renman, G., and Simán, G. (2006). “Phosphorus retention in filter materials for wastewater treatment and its subsequent suitability for plant production.” Bioresour. Technol. (in press).
Jenkins, D., Ferguson, F., and Menar, A. B. (1971). “Chemical processes for phosphate removal.” Water Res., 5(7), 369–389.
Johansson, J., and Gustafsson, J. P. (2000). “Phosphate removal using blast furnace slags and opoka-mechanisms.” Water Res., 34(1), 259–265.
Johansson, L. (1998). “Phosphorus sorption to filter substrates—potential benefits for onsite wastewater treatment,” Doctoral thesis TRITA-AMI PHD 1024, Dept. of Civil and Environmental Engineering., Royal Institute of Technology, Stockholm, Sweden.
Johansson, L. (1999). “Industrial by-products and natural substrata as phosphorus sorbents.” Environ. Technol., 20(3), 309–316.
Kadlec, R. H., and Knight, R. L. (1996). Treatment wetlands, Lewis, Boca Raton, Fla.
Kanschat, A. (1996). “Blast furnace slag in road construction.” Master's thesis 1996:162E, Dept. of Civil and Environmental Engineering, Luleå Univ. of Technology, Luleå, Sweden (in Swedish).
Khelifi, O., Kozukia, K., Murakamia, H., Kurataa, K., and Nishiokab, M. (2002). “Nutrients adsorption from seawater by new porous carrier made from zeolitized fly ash and slag.” Mar. Pollution Bull., 45(1–12), 311–315.
Korkusuz, E. A., Beklioğlu, M., and Demirer, G. N. (2005). “Comparison of the treatment performances of blast furnace slag-based and gravel-based vertical flow wetlands operated identically for domestic wastewater treatment in Turkey.” Ecol. Eng., 24, 187–200.
Lee, S. H., Vigneswaran, S., and Moon, H. (1997). “Adsorption of phosphorus in saturated slag media columns.” Sep. Purif. Technol., 12(2), 109–118.
Lindgren, Å. (1992). “Laboratory investigations of blast furnace slag.” Rep. No. 1992:09T, Dept. of Civil and Environmental Engineering, Luleå Univ. of Technology, Luleå, Sweden (in Swedish).
Lindgren, Å. (1998). “Road construction materials as a source of pollutants” Doctoral thesis 1998:05, Dept. of Civil and Environmental Engineering, Luleå Univ. of Technology, Luleå, Sweden.
Mann, R. A., and Bavor, H. J. (1993). “Phosphorus removal in constructed wetlands using gravel and industrial waste substrata.” Water Sci. Technol., 27(1), 107–113.
Metcalf and Eddy Inc. (1991). Wastewater engineering—treatment, disposal and reuse, 3rd Ed., McGraw-Hill, Singapore.
Oguz, E. (2004). “Removal of phosphate from aqueous solution with blast furnace slag.” J. Hazard. Mater. B114, 131–137.
Ramakrishna, K. R., and Viraraghavan, T. (1997). “Use of slag for dye removal.” Waste Manage., 17(8), 483–488.
Roseth, R. (2000). “Shell sand: A new filter medium for constructed wetlands and wastewater treatment.” J. Environ. Sci. Health, Part A: Toxic/Hazard. Subst. Environ. Eng., 35(8), 1335–1355.
Sakadevan, K., and Bavor, H. J. (1998). “Phosphate adsorption characteristics of soils, slags, and zeolite to be used as substrates in constructed wetlands systems.” Water Res., 32(2), 393–399.
Sedlak, R. (1991). Phosphorus and nitrogen removal from municipal wastewater: Principles and practice, Lewis, Chelsea.
Snoeyink, V. L., and Jenkins, D. (1980). Water chemistry, Wiley, New York.
Stark, T. (2004). “Reactive filter materials for removal of phosphorus in small scale wastewater treatment plants.” Master thesis UPTEC W 04 023, Dept. of Earth Sciences, Uppsala Univ., Uppsala, Sweden (in Swedish).
Statistics Sweden (SCB). (2004). “Discharges to water and sludge production in 2002”. Rep. No. Mi 22 SM 0401, Stockholm, Sweden (in Swedish).
Sunahara, H., Wei, M. X., and Kayama, M. (1987). “Phosphate removal by column packed blast-furnace slag. I. Fundamental research by synthetic wastewater.” Environ. Technol. Lett., 8(11), 589–598.
Swedish Environmental Protection Agency (SEPA). (1991). “Treatment of wastewater—Infiltration units for more than 25 people.” Rep. No Allmänna Råd 91:2, Solna, Sweden (in Swedish).
Swedish Environmental Protection Agency (SEPA). (2003). “No eutrophication.” Rep. No 5319, Stockholm, Sweden (in Swedish).
Tossavainen, M., and Forssberg, E. (2000). “Leaching behaviour of rock material and slag used in road construction—A mineralogical interpretation.” Steel Res., 71(11), 442–448.
Yamada, H., Kayama, M., Saito, K., and Hara, M. (1986). “Fundamental research on phosphate removal by using slag.” Water Res., 20(5), 547–557.
Zhu, T., Maehlum, T., Jenssen, P. D., and Krogstad, T. (2003). “Phosphorus sorption characteristics of light-weight aggregate.” Water Sci. Technol., 48(5), 93–100.

Information & Authors

Information

Published In

Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 132Issue 11November 2006
Pages: 1431 - 1438

History

Received: May 31, 2005
Accepted: Apr 10, 2006
Published online: Nov 1, 2006
Published in print: Nov 2006

Permissions

Request permissions for this article.

Authors

Affiliations

Annelie Hedström
Licentiate in Engineering, Dept. of Civil and Environmental Engineering, Luleå Univ. of Technology, SE-971 87, Luleå, Sweden. E-mail: [email protected]
Lea Rastas
Dept. of Civil and Environmental Engineering, Luleå Univ. of Technology, SE-971 87, Luleå, Sweden (corresponding author). E-mail: [email protected]

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

Cited by

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share