TECHNICAL PAPERS
Nov 1, 2005

Nonlinear Behavior of Permeate Flux in Full-Scale Reverse Osmosis Processes

Publication: Journal of Environmental Engineering
Volume 131, Issue 11

Abstract

Permeate flux is a key design and operating parameter for the reverse osmosis (RO) process. It has been widely observed from laboratory studies that permeate flux is linearly related to transmembrane pressure, but it has been noted that such a simple linear relationship may not be strictly applicable to a typical full-scale RO process where a long membrane channel is employed. A pilot-scale RO system with a 4-m-long membrane channel was used in this study to investigate the behavior of permeate flux under various operating conditions. It was noted that the linear relationship between the average permeate flux and transmembrane pressure was only true when the RO system was operating at low transmembrane pressure or recovery. The average permeate flux deviated substantially from the linear relationship as the transmembrane pressure increased. It was speculated that thermodynamic equilibrium between the osmotic pressure in the membrane channel and the transmembrane pressure of the RO process might become the limiting factor of RO processes under certain circumstances.

Get full access to this article

View all available purchase options and get full access to this article.

Acknowledgments

The writers would like to thank the Singapore Millennium Foundation for providing a Ph.D. scholarship to K. G. Tay. This work was supported in part by the National University of Singapore (Project No. R-264-000-110-112). We are also grateful to Miss Serene Goh Sui Lin for her assistance in carrying out the experiments in her final year project during her attachment stint in our laboratory.

References

American Water Works Association (AWWA). (1998). “Reverse osmosis and nanofiltration.” American Water Works Association manual, AWWA, Denver.
American Water Works Association/Membrane Technology Research Committee (AWWA/MTRC) . (1998). “Committee Report: Membrane processes.” J. Am. Water Works Assoc., 90(6), 91–105.
Bremere, I., Kennedy, M., Stikker, A., and Schippers, J. (2001). “How water scarcity will affect the growth in the desalination market in the coming 25 years.” Desalination, 138, 7–15.
Dudley, L., Pisano, F. Vigo, and Fazel, M. (2000). “Optimizing membrane performance—Practical experiences.” Membr. Technol., 2000(121), 5–8.
Durham, B., Bourbigot, M. M., and Pankratz, T. (2002). “Membranes as pretreatment to desalination in wastewater reuse.” Membr. Technol., 2002(3), 8–12.
Koyuncu, I., Yazgan, M., Topacik, D., and Sarikaya, H. Z. (2001). “Evaluation of the low pressure RO and NF membranes for an alternative treatment of Buyukcekmece Lake.” Water Sci. Technol.: Water Supply, 1(1), 107–115.
Kurihara, M., Yamamura, H., Nakanishi, T., and Jinno, S. (2001). “Operation and reliability of very high-recovery seawater desalination technologies by brine conversion two-stage RO desalination system.” Desalination, 138, 191–199.
Lonsdale, H. K., Merten, U., and Riley, R. L. (1965). “Transport properties of cellulose acetate osmotic membranes.” J. Appl. Polym. Sci., 9(4), 1341–1362.
Mason, E. A., and Lonsdale, H. K. (1990). “Statistical-mechanical theory of membrane transport.” J. Membr. Sci., 51, 1–81.
Nemeth, J. E. (1998). “Innovative system designs to optimize performance of ultra-low pressure reverse osmosis membranes.” Desalination 118, 63–71.
Raab, T., and Samhaber, W. M. (2002). “New materials for high pressure reverse osmosis membranes.” Venice High Pressure Conf.
Rautenbach, R., Linn, T., and Eilers, L. (2000). “Treatment of severely contaminated waste water by a combination of RO, high-pressure RO and NF—Potential and limits of the process.” J. Membr. Sci., 174, 231–241.
Soltanieh M., and Gill, W. N. (1981). “Review of reverse osmosis membranes and transport models.” Chem. Eng. Commun., 12, 279–363.
Song, L., Hong, S., Hu, J. Y., Ong, S. L., and Ng, W. J. (2002). “Simulations of full-scale reverse osmosis membrane process.” J. Environ. Eng., 128(10), 960–966.
Taylor, J. S., and Jacobs, E. P. (1996). “Reverse osmosis and nanofiltration.” Water treatment: Membrane processes, American Water Work Association Research Foundation, McGraw-Hill, New York.
Van der Bruggen, B., and Vandecasteele, C. (2002). “Distillation versus membrane filtration: Overview of process evolutions in seawater desalination.” Desalination, 143, 207–218.
Van Gauwbergen, D., and Baeyens, J. (1998). “Modelling reverse osmosis by irreversible thermodynamics.” Sep. Purif. Technol., 13, 117–128.
Van Gauwbergen, D., and Baeyens, J. (1999). “Assessment of the design parameters for wastewater treatment by reverse osmosis.” Water Sci. Technol., 40(4–5), 269–276.
Wilf, M. (1997). “Design consequences of recent improvements in membrane performance.” Desalination, 113, 157–163.
Wilf, M., and Klinko, K. (2001). “Optimization of seawater RO systems designs.” Desalination, 138, 299–306.

Information & Authors

Information

Published In

Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 131Issue 11November 2005
Pages: 1481 - 1487

History

Received: Jul 28, 2003
Accepted: Mar 9, 2005
Published online: Nov 1, 2005
Published in print: Nov 2005

Permissions

Request permissions for this article.

Authors

Affiliations

Kwee Guan Tay
PhD Postgraduate, Dept. of Civil Engineering, National Univ. of Singapore, 10 Kent Ridge Crescent, Singapore 119260.
Lianfa Song
Associate Professor, Dept. of Civil Engineering, National Univ. of Singapore, 10 Kent Ridge Crescent, Singapore 119260.
S. L. Ong
Professor, Dept. of Civil Engineering, National Univ. of Singapore, 10 Kent Ridge Crescent, Singapore 119260.
W. J. Ng
Professor, Dept. of Civil Engineering, National Univ. of Singapore, 10 Kent Ridge Crescent, Singapore 119260.

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

Cited by

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share