TECHNICAL PAPERS
Jul 15, 2004

Evaluation of Metal Attenuation through Paper Clay Utilized for Containment of Contaminated Groundwater

Publication: Journal of Environmental Engineering
Volume 130, Issue 8

Abstract

Paper clay has several properties that make its use in vertical barriers very promising. In this paper the characteristics of two paper sludges (which will also be referred to as paper clays) one from the Erving Paper Company and one from the International Paper Company are considered. To determine the feasibility of paper clay for heavy metal attenuation, batch tests, column tests, hydraulic conductivity tests, and pressure filtration tests were performed. Batch testing showed that the metal, the distribution coefficient (Kd) ranged from as low as 0.002 L/g for manganese to as high as 6.7 L/g for lead in International paper clay. In the Erving paper clay the Kd ranged from 0.007 L/g for manganese to 1.9 L/g for cadmium, while the International paper clay Kd ranged from 0.002 L/g for manganese to 6.7 L/g for lead. Chemisorption was established as the predominant metal binding mechanism in both clays with the only exceptions being manganese adsorption on International paper clay that indicated a constant partitioning, and copper and lead on Erving paper clay that indicated constant partitioning and cooperative adsorption, respectively. Both hydraulic conductivity and pressure filtration tests revealed permeabilities ranging from 10-5 to 10-7cm/s. Chloride testing showed that the coefficient of hydrodynamic dispersion (D) within paper clay is on the order of 10-7cm2/s.

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References

D’Applonia, D. J.(1980). “Soil–bentonite slurry trench cutoffs.” J. Geotech. Eng. Div., Am. Soc. Civ. Eng., 106(4), 399–417.
Davis, S. N., Thompson, G. M., Bentley, H. W., and Siles, G.(1980). “Groundwater tracers—A short review.” Ground Water, 18(1), 14–23.
Evans, J. C. (1991). “Geotechnics of hazardous waste control systems.” Foundation engineering handbook, H.-Y. Fang, ed., Van Nostrand Reinhold, New York.
Giles, C. H., MacEwan, T. H., Nakhwas, S. N., and Smith, D. (1960). “Studies in adsorption. Part XI. A system of classification of solution adsorption isotherms, and its use in diagnosis of adsorption mechanisms and in measurement of specific surface areas of solids.” J. Chem. Phys., 3973–3993.
Henry, L. B., Filz, G. M., and Davidson, R. R. (1998). “Formation and properties of bentonite filter cakes.” Filtration and drainage in geotechnical/geoenvironmental engineering, Geotechnical Special Publication No. 78, L. N. Reddi and M. V. S. Bonala, eds., ASCE, Reston, Va., 69–88.
Johnson, R. L., Cherry, J. A., and Pankow, J. F.(1989). “Diffusive contaminant transport in natural clay: A field example and implications for clay-lined waste disposal sites.” Environ. Sci. Technol., 23(3), 340–349.
Kemper, W. D., Maasland, D. E. L., and Porter, L. K.(1964). “Mobility of water adjacent to mineral surfaces.” Proc. Soil Sci. Soc. Am., 28(2), 164–167.
McBride, M. B. (1994). Environmental chemistry of soils, Oxford University Press, New York.
Moo-Young, H. K., Gallagher, M. J., Amadon, A., Polaski, J., and Wolfe, M. (2000). “Use of paper clay as a barrier for treatment of contaminated ground water.” Geotechnics of high water content materials, ASTM STP 1374, T. B. Edil and P. J. Fox, eds., American Society for Testing and Materials, West Conshohocken, Pa.
Moo-Young, H. K., and Zimmie, T.(1996). “Geotechnical properties of paper mill sludges for use in landfill covers.” J. Geotech. Eng., 122(9), 768–776.
Nash, J. K. T. L., and Jones, G. K. (1963). The support of trenches using fluid mud., Butterworths Scientific Publications, London.
Perkins, T. K., and Johnston, D. C.(1963). “A review of diffusion and dispersion in porous media.” Soc. Pet. Eng. J., 3(1), 70–84.
Quigley, R. M., and Rowe, R. K. (1986). “Leachate migration through clay below a domestic waste landfill, Sarnia, Ont., Canada: Chemical interpretation and modeling philosophies.” Hazardous and industrial solid waste testing and disposal, STP 933, D. Lorenz et al., eds., ASTM, Philadelphia, 93–103.
Robinson, R. A., and Stokes, R. H. (1959). Electrolyte solutions, 2nd Ed., Butterworths Scientific Publications, London.
Rowe, K. R., Quigley, R. M., and Booker, J. R. (1997). Clayey barrier systems for waste disposal facilities, E&FN SPON, London.
Roy, W. R., Krapac, I. G., Chou, S. F. J., and Griffin, R. A. (1991). “Batch-type procedures for estimating soil adsorption of chemicals.” EPA/530-SW-87-006-F, U.S. Environmental Protection Agency, Washington, D.C.
Ryan, C. R. (1987). “Vertical barriers in soil for pollution containment.”Geotechnical practice for waste disposal, ASCE, New York.
Shackleford, C. D., and Daniel, D. E.(1991a). “Diffusion in saturated soil. I: Background.” J. Geotech. Eng., 117(3), 467–484.
Shackleford, C. D., and Daniel, D. E.(1991b). “Diffusion in saturated soil. II: Results for compacted clay.” J. Geotech. Eng., 117(3), 485–506.
Sharma, H. D., and Lewis, S. P. (1994). Waste containment systems, waste stabilization, and landfills: design and evaluation, Wiley, New York.
van Genuchten, M. Th., and Alves, W. J. (1982). “Analytical solutions of the one-dimensional convective-dispersive solute transport equation.” Technical Bulletin No. 1661, U.S. Salinity Laboratory, U.S. Dept. of Agriculture, Riverside, Calif.
van Schaik, J. C., and Kemper, W. D.(1966). “Chloride diffusion in clay-water systems.” Proc. Soil Sci. Soc. Am., 30(1), 22–25.
Xanthakos, P. (1979). Slurry walls, McGraw-Hill, New York.

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Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 130Issue 8August 2004
Pages: 873 - 880

History

Received: Jun 18, 2003
Accepted: Jun 18, 2003
Published online: Jul 15, 2004
Published in print: Aug 2004

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Authors

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Charles Ochola
Dept. of Civil and Environmental Engineering, Lehigh Univ., Bethlehem, PA 18015.
Horace Moo-Young
Lehigh Univ., Bethlehem, PA 18015.

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