Impact of Reaction Conditions on Genesis during Permanganate Oxidation
Publication: Journal of Environmental Engineering
Volume 130, Issue 5
Abstract
To enhance the understanding of the behavior and effects of the precipitation of particles in the subsurface generated during in situ chemical oxidation (ISCO) using permanganate, laboratory batch experiments were completed to examine the influence that varied reaction matrix conditions have on the generation and properties of manganese oxides. The conditions examined include organic material type and concentration, permanganate concentration, pH, and the presence of calcium (as a representative divalent cation) in solution. Experimental studies included: (1) spectrophotometric examination of permanganate depletion and manganese oxides generation over time during reactions with trichloroethene; (2) scanning electron microscopy analyses of manganese particle morphology; (3) particle size distribution (filtration) characterization studies; and (4) optical particle sizing and numeration studies. Bench-scale, batch experiments were conducted to focus on fundamental chemical properties affecting particle development under varied potential environmental conditions. The amount of manganese oxides particles that develop, grow, and potentially settle as a result of permanganate ISCO of organic contaminants is a function of the particle size and concentration, the time allowed for particle development, and the impact of matrix conditions on the ability of particles to agglomerate.
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References
American Public Health Association (APHA). (1998). Standard methods for the examination of water and wastewater. 20th Ed., L. S. Clesceri, A. E. Greenberg, and R. R. Trussell, eds., APHA-AWWA-WPCF, Washington, D.C.
Chandrakanth, M. S., and Amy, G. L.(1996). “Effects of ozone on the colloidal stability and aggregation of particles coated with natural organic matter.” Environ. Sci. Technol., 30(2), 431–442.
Crimi, M. L. (2002). “Particle genesis and effects on metals in the subsurface during in situ chemical oxidation using permanganate.” PhD dissertation, Colorado School of Mines, Golden, Colo.
Doona, C. J., and Schneider, F. W.(1993). “Identification of colloidal Mn(IV) in permanganate oscillating reactions.” J. Am. Chem. Soc., 115, 9683–9686.
Fu, G., Allen, H. E., and Cowan, C. E.(1991). “Adsorption of cadmium and copper by manganese oxide.” Soil Sci., 152(2), 72–81.
Huang, K. H., Hoag, G. E., Chheda, P., Woody, B. A., and Dobbs, G. M.(1999). “Kinetic study of oxidation of trichloroethylene by potassium permanganate.” Environ. Eng. Sci., 16(4), 265–274.
Insausti, M. J., Mata-Perez, F., and Alvarez-Macho, P.(1992). “Permanganate oxidation of glycine: Influence of amino acid on colloidal manganese dioxide.” Int. J. Chem. Kinet., 24(5), 411–419.
Insausti, M. J., Mata-Perez, F., and Alvarez-Macho, P.(1993). “UV-VIS spectrophotometric study and dynamic analysis of the colloidal product of permanganate oxidation of α-amino acids.” React. Kinet. Catal. Lett., 51(1), 51–59.
McKenzie, R. M. (1977). “Manganese oxides and hydroxides.” Minerals in soil environments, J. B. Dixon and S. B. Weed, eds., Soil Society of America, Madison, Wis., 181–193.
Morgan, J. J., and Stumm, W.(1964). “Colloid-chemical properties of manganese dioxide.” J. Colloid Sci., 19, 347–359.
Perez-Benito, J. F., and Arias, C.(1991). “A kinetic study of the permanganate oxidation of triethylamine. Catalysis by soluble colloids.” Int. J. Chem. Kinet., 23, 717–732.
Perez-Benito, J. F., and Arias, C.(1992a). “A kinetic study of the reaction between soluble (colloidal) manganese dioxide and formic acid.” J. Colloid Interface Sci., 149(1), 92–97.
Perez-Benito, J. F., and Arias, C.(1992b). “Occurrence of colloidal manganese dioxide in permanganate reactions.” J. Colloid Interface Sci., 152(1), 70–84.
Perez-Benito, J. F., Arias, C., and Brillas, E.(1990). “A kinetic study of the autocatalytic permanganate oxidation of formic acid.” Int. J. Chem. Kinet., 22, 261–287.
Perez-Benito, J. F., Brillas, E., and Pouplana, R.(1989). “Identification of a soluble form of colloidal manganese (IV).” Inorg. Chem., 28, 390–392.
Siegrist, R. L., Urynowicz, M. A., Crimi, M. L., and Lowe, K. S.(2002). “Genesis and effects of particles produced during in situ chemical oxidation using permanganate.” J. Environ. Eng., 128(11), 1068–1079.
Siegrist, R. L., Urynowicz, M. A., West, O. R., Crimi, M. L., and Lowe, K. S. (2001). Principles and practices of in situ chemical oxidation using permanganate, Battelle, Columbus, Ohio.
Struse, A. M., Siegrist, R. L., Dawson, H. E., and Urynowicz, M. A.(2002). “Diffusive transport of permanganate during in situ oxidation.” J. Environ. Eng., 128(4), 327–334.
Urynowicz, M. A. (2000). “Dense non-aqueous phase trichloroethene degradation with permanganate ion.” PhD dissertation, Colorado School of Mines, Golden, Colo.
U.S. Environmental Protection Agency (1998). “In situ remediation technology: In situ chemical oxidation.” EPA 542-R-98-008, Office of Solid Waste and Emergency Response, Washington, D.C.
West, O. R., Cline, S. R., Holden, W. L., Gardner, F. G., Schlosser, B. M., Thate, J. E., Pickering, D. A., and Houk, T. C. (1998a). “A full-scale field demonstration of in situ chemical oxidation through recirculation at the X-701B site.” Rep. No. ORNL.TM-13556, Oak Ridge National Laboratory, Oak Ridge, Tenn.
West, O. R., Cline, S. R., Siegrist, R. L., Houk, T. C., Holden, W. L., Gardner, F. G., and Schlossner, R. M. (1998b). “A field-scale test of in situ chemical oxidation through recirculation.” Proc., Spectrum ’98 Int. Conf. on Nuclear and Hazardous Waste Management, Denver, 1051–1057.
Yan, Y., and Schwartz, F. W. (1996). “In-situ oxidative dechlorination of trichloroethylene by potassium permanganate.” 3rd Int. Conf. on AOTs, Cincinnati.
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Copyright © 2004 American Society of Civil Engineers.
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Received: Sep 18, 2002
Accepted: Mar 26, 2003
Published online: Apr 15, 2004
Published in print: May 2004
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