TECHNICAL PAPERS
Nov 15, 2004

Permeation of Organics through Linear Low Density Polyethylene Geomembranes under Mechanical Deformation

Publication: Journal of Environmental Engineering
Volume 130, Issue 12

Abstract

The effect of mechanical deformation on the permeation of methylene chloride (MEC), trichloroethylene (TCE) as well as mixtures thereof through linear low-density polyethylene (LLDPE) geomembranes was studied using a new experimental technique. A total of fifty experimental conditions involving five different deformations, five different concentrations and two types of LLDPE geomembranes were evaluated following a full factorial experimental design. Mixtures of TCE and MEC (0.66, 0.50, and 0.34 volumetric fraction) were tested through geomembranes elongated uniaxially (10% and 20%) as well as in the biaxial mode (10%×10%and20%×20%). The breakthrough times for the permeation of TCE and MEC decreased with elongation for both types of geomembranes. A reduction in breakthrough times between 38 and 45% was observed for the permeation of MEC and TCE though geomembranes elongated 20%×20% in the biaxial mode compared to the nonelongated specimens. Evidence of stress-enhanced transport was also observed as the steady-state permeation rates of MEC increased between 200 and 300% where geomembranes were elongated 20%×20% in the biaxial mode compared to the nonelongated samples. Enhanced transport of MEC was also noted during the permeation of the MEC–TCE mixtures.

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Information & Authors

Information

Published In

Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 130Issue 12December 2004
Pages: 1468 - 1474

History

Published online: Nov 15, 2004
Published in print: Dec 2004

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Authors

Affiliations

Juan Hinestroza
Fiber and Polymer Science Program, Dept. of Textile Engineering, Chemistry, and Science, North Carolina State Univ., Raleigh, NC 27695. E-mail: juan_[email protected]
Daniel De Kee
Professor and Associate Dean for Research and Graduate Studies, Dept. of Chemical Engineering, Tulane Univ. and Tulane Institute for Macromolecular Engineering and Science, New Orleans, LA 70118 (corresponding author). E-mail: [email protected]

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