TECHNICAL PAPERS
Nov 1, 2004

Comparative Analysis of Chlorine Dioxide, Free Chlorine and Chloramines on Bacterial Water Quality in Model Distribution Systems

Publication: Journal of Environmental Engineering
Volume 130, Issue 11

Abstract

Drinking water utilities may be required to change disinfectant to improve water quality and meet more stringent disinfection regulations. This research was conducted to assess and compares chlorine dioxide to free chlorine and chloramines on bacterial water quality monitored within model distribution systems (i.e., annular reactors). Following colonization with nondisinfected water, annular reactors containing either polycarbonate or cast iron coupons were treated with free chlorine, chlorine dioxide or chloramines. Two disinfectant doses (low/high) were tested for each disinfectant. Under specific environmental conditions, bacterial inactivation varied as a function of the disinfectant type and dose, sample type (bulk water versus biofilm bacteria) and coupon material. The ranking by efficiency was as follows: chlorine dioxide > chlorine > chloramines. On preformed biofilms of 106-107cfu/cm2, the continuous application of a disinfectant led to a log removal of heterotrophic bacteria concentrations for suspended and biofilm bacteria ranging from 1.1 to 4.0, and from 0.2 to 2.5, respectively. Doubling the amount of disinfectant doses led to an additional log inactivation of 1–2.5 of heterotrophic bacteria levels. This study demonstrates that bacterial inactivation in distribution systems is governed by various inter-related parameters. The data indicate that chlorine dioxide represents a viable alternative for secondary disinfection in distribution systems.

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Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 130Issue 11November 2004
Pages: 1269 - 1279

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Published online: Nov 1, 2004
Published in print: Nov 2004

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Authors

Affiliations

G. A. Gagnon
Associate Professor, Dept. of Civil Engineering, Dalhousie Univ., Halifax, NS, Canada B3J 2X4.
K. C. O’Leary
Project Engineer, Cavanaugh Solutions, Winston-Salem, NC 27101.
C. J. Volk
President, Aqua Plus Services, Muncie, IN 47304.
C. Chauret
Associate Professor, Dept. of Biological and Physical Sciences, Indiana Univ. Kokomo, Kokomo, IN 460904-9003.
L. Stover
Research Associate, Dept. of Biological and Physical Sciences, Indiana Univ. Kokomo, Kokomo, IN 460904-9003.
R. C. Andrews
Professor, Dept. of Civil Engineering, Univ. of Toronto, Toronto, ON, Canada MIS 1A4.

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