Instability of Hydrocarbon Films over Mineral Surfaces: Microscale Experimental Studies
Publication: Journal of Environmental Engineering
Volume 129, Issue 12
Abstract
The fluid-mineral interaction defines the affinity of mineral surfaces for water in the presence of oil, determines wettability, affects interparticle forces, and controls the effectiveness of soil decontamination and oil recovery from reservoirs. This study involves the use of electrical impedance measurements and optical microscopy to determine the rupture time of thin oil films on mineral surfaces when water droplets are placed on the film. The results show that the time for film rupture depends on the mineral and the type of oil, it increases with the increase in oil viscosity, and it decreases in the presence of surfactants. The instability and rupture of the thin hydrocarbon films are analyzed taking into consideration surface forces and disjoining/conjoining pressure. These results are relevant to defining the ability of mineral surfaces to become wetted by water, leading to the displacement of organic films.
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Information & Authors
Information
Published In
Journal of Environmental Engineering
Volume 129 • Issue 12 • December 2003
Pages: 1120 - 1128
Copyright
Copyright © 2003 American Society of Civil Engineers.
History
Received: Jan 9, 2001
Accepted: Sep 23, 2002
Published online: Nov 14, 2003
Published in print: Dec 2003
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